封面专题：[MnFe(CO)10]+的分离和表征：三维二金属十羰基系列中的缺失环节（化学）。欧元。j . 23/2025)

IF 3.9 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - A European Journal Pub Date : 2025-04-22 DOI:10.1002/chem.202582302

Malte Sellin, Hendrik Koger, Tobias A. Engesser, Jörg Grunenberg, Ingo Krossing

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引用次数: 0

摘要

配合物[CrMn(CO)10]−和[MnFe(CO)10]+的分子结构完成了从[Cr2(CO)10]2−到[Fe2(CO)10]2+的二金属十羰基系列。在我们对雾海之上的漫游者号的解释中，一位化学家徒步穿越了二金属-十羰基的景观，发现了雾中隐藏的异双核复合物。雾气也突出了共价键和路易斯对键之间的朦胧边界，光线被华丽地洒在上面。在背景中，标题化合物的振动山脉显示出它的高峰。更多信息可以在I. Krossing及其同事的研究文章中找到（DOI: 10.1002/chem.202500489）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: Isolation and Characterization of [MnFe(CO)10]+: The Missing Link in the 3 d Dimetal Decacarbonyl Series (Chem. Eur. J. 23/2025)

查看原文本刊更多论文

Cover Feature: Isolation and Characterization of [MnFe(CO)10]+: The Missing Link in the 3 d Dimetal Decacarbonyl Series (Chem. Eur. J. 23/2025)

The molecular structures of the complexes [CrMn(CO)₁₀]⁻ and [MnFe(CO)₁₀]⁺ complete the series of dimetal decacarbonyls reaching from [Cr₂(CO)₁₀]²⁻ to [Fe₂(CO)₁₀]²⁺. In our interpretation of the Wanderer above the Sea of Fog, a chemist is hiking through the dimetal-decacarbonyl landscape, discovering the hidden heterodinuclear complexes in the fog. The fog also highlights the misty borderline situation between covalent and Lewis-pair bonding, onto which light is ornately shed. In the background, the vibrational mountain range of the title compound shows its peaks. More information can be found in the Research Article by I. Krossing and co-workers (DOI: 10.1002/chem.202500489).

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来源期刊

Chemistry - A European Journal 化学-化学综合

CiteScore

7.90

自引率

4.70%

发文量

1808

审稿时长

1.8 months

期刊介绍： Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields. Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world. All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times. The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems. Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.