Kun Cao , Zhenhai Yang , Meng Wang , Yu Liang , Jiao Liu , Yining Bao , Yuqi Zhang , Luolei Shi , Guoyang Cao , Xiaofeng Li , Linling Qin
{"title":"高效背接触隧道氧化物钝化接触太阳能电池的物理机制和设计策略","authors":"Kun Cao , Zhenhai Yang , Meng Wang , Yu Liang , Jiao Liu , Yining Bao , Yuqi Zhang , Luolei Shi , Guoyang Cao , Xiaofeng Li , Linling Qin","doi":"10.1016/j.solmat.2025.113656","DOIUrl":null,"url":null,"abstract":"<div><div>Back contact-based tunnel oxide passivating contact (TBC) solar cells (SCs) represent one of the significant research focuses for future development in the photovoltaic industry, owing to their advantages of high-efficiency potential and compatibility with large-scale mass production lines. However, the current efficiency of TBC SCs has not yet reached the expected level due to a lack of clear understanding of the working mechanisms and high-efficiency technological pathways. Here, we clarify the physical mechanisms and propose detailed strategies for designing high-efficiency TBC SCs through a comprehensive simulation study. The simulation results indicate that high-efficiency TBC SCs require extended carrier lifetimes, improved front-surface passivation, and minimized interface recombination in the <em>p</em>-region. Additionally, we also point out that the optimized cell size should balance carrier transport and recombination losses. Specifically, for small-<em>pitch</em> devices, reducing the fill size ratio of the <em>p</em>-type contact proves advantageous, whereas for large-<em>pitch</em> devices, a relatively larger fill size ratio of the <em>p</em>-type contact region is required. Moreover, based on the current passivation contact quality and device integration level, an efficiency of up to 28% is anticipated. This study reveals the working mechanism of the device in detail, providing a reference for the preparation of high-efficiency TBC SCs.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"289 ","pages":"Article 113656"},"PeriodicalIF":6.3000,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Physical mechanisms and design strategies for high-efficiency back contact tunnel oxide passivating contact solar cells\",\"authors\":\"Kun Cao , Zhenhai Yang , Meng Wang , Yu Liang , Jiao Liu , Yining Bao , Yuqi Zhang , Luolei Shi , Guoyang Cao , Xiaofeng Li , Linling Qin\",\"doi\":\"10.1016/j.solmat.2025.113656\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Back contact-based tunnel oxide passivating contact (TBC) solar cells (SCs) represent one of the significant research focuses for future development in the photovoltaic industry, owing to their advantages of high-efficiency potential and compatibility with large-scale mass production lines. However, the current efficiency of TBC SCs has not yet reached the expected level due to a lack of clear understanding of the working mechanisms and high-efficiency technological pathways. Here, we clarify the physical mechanisms and propose detailed strategies for designing high-efficiency TBC SCs through a comprehensive simulation study. The simulation results indicate that high-efficiency TBC SCs require extended carrier lifetimes, improved front-surface passivation, and minimized interface recombination in the <em>p</em>-region. Additionally, we also point out that the optimized cell size should balance carrier transport and recombination losses. Specifically, for small-<em>pitch</em> devices, reducing the fill size ratio of the <em>p</em>-type contact proves advantageous, whereas for large-<em>pitch</em> devices, a relatively larger fill size ratio of the <em>p</em>-type contact region is required. Moreover, based on the current passivation contact quality and device integration level, an efficiency of up to 28% is anticipated. This study reveals the working mechanism of the device in detail, providing a reference for the preparation of high-efficiency TBC SCs.</div></div>\",\"PeriodicalId\":429,\"journal\":{\"name\":\"Solar Energy Materials and Solar Cells\",\"volume\":\"289 \",\"pages\":\"Article 113656\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-04-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solar Energy Materials and Solar Cells\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927024825002570\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024825002570","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Physical mechanisms and design strategies for high-efficiency back contact tunnel oxide passivating contact solar cells
Back contact-based tunnel oxide passivating contact (TBC) solar cells (SCs) represent one of the significant research focuses for future development in the photovoltaic industry, owing to their advantages of high-efficiency potential and compatibility with large-scale mass production lines. However, the current efficiency of TBC SCs has not yet reached the expected level due to a lack of clear understanding of the working mechanisms and high-efficiency technological pathways. Here, we clarify the physical mechanisms and propose detailed strategies for designing high-efficiency TBC SCs through a comprehensive simulation study. The simulation results indicate that high-efficiency TBC SCs require extended carrier lifetimes, improved front-surface passivation, and minimized interface recombination in the p-region. Additionally, we also point out that the optimized cell size should balance carrier transport and recombination losses. Specifically, for small-pitch devices, reducing the fill size ratio of the p-type contact proves advantageous, whereas for large-pitch devices, a relatively larger fill size ratio of the p-type contact region is required. Moreover, based on the current passivation contact quality and device integration level, an efficiency of up to 28% is anticipated. This study reveals the working mechanism of the device in detail, providing a reference for the preparation of high-efficiency TBC SCs.
期刊介绍:
Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.