废玻璃粉在碱-硅反应减缓中的作用:通过化学成分动力学改变玻璃混凝土的耐久性

IF 5.5 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Maryam Basil Ishaq, Ahmed Salih Mohammed, Azad A. Mohammed
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引用次数: 0

摘要

碱-二氧化硅反应对混凝土结构的耐久性提出了重大挑战,主要是由于碱性孔隙溶液与骨料中的活性二氧化硅之间的反应,产生吸湿凝胶,导致裂缝和混凝土在存在水分的情况下劣化。选择废玻璃粉是因为其高硅含量,火山灰反应性和与碱结合的潜力,可以减轻asr引起的膨胀。此外,它的使用通过减少水泥消耗和重新利用工业废物来促进可持续性,与绿色建筑的原则保持一致。以最佳剂量利用废料可提供具有平衡耐久性和性能的可持续混凝土。本研究建立了碱-硅反应(ASR)预测模型。根据玻璃与水泥的化学成分,以及w/b、水泥、细骨料、玻璃置换、浸泡时间等其他输入参数,对废玻璃替代水泥改性混凝土进行膨胀,如线性、纯二次、M5P-tree模型。结果表明,加入玻璃粉可以有效地降低膨胀(%),并通过膨胀时间优化技术确定最佳剂量。对比评估显示,虽然玻璃粉在较低剂量下可显著缓解ASR,但粉煤灰在所有替代水平上都表现出优越的长期性能,特别是在NaOH溶液中浸泡28天后。此外,渣在高剂量下具有竞争力,表明其在ASR降低方面的潜在效用。较高的SiO2/CaO比导致ASR膨胀减小,特别是随着GP(%)的增加和固化时间的延长。更高的GP(%)也会导致更高的ASR膨胀,在3天后,普通砂浆的ASR膨胀率从0.05%上升到0.2%,GP为40%。相比之下,当SiO2/CaO比为0.3时,GP为0%的普通砂浆棒在3天后ASR膨胀最小,为0.03%,28天后ASR膨胀率上升至0.18%,说明在碱性溶液中浸泡时间起关键作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The role of waste glass powder in alkali-silica reaction mitigation: Transforming glasscrete durability through chemical composition dynamics

The role of waste glass powder in alkali-silica reaction mitigation: Transforming glasscrete durability through chemical composition dynamics
The alkali-silica reaction poses a significant challenge to the durability of concrete structures, primarily due to the reaction between alkaline pore solutions and reactive silica in aggregate, generating hygroscopic gel that leads to cracks and concrete deterioration in the presence of moisture. Waste glass powder is selected due to its high silica content, pozzolanic reactivity, and potential to bind alkalis, which can mitigate ASR-induced expansion. Additionally, its use promotes sustainability by reducing cement consumption and repurposing industrial waste, aligning with the principles of green construction. Utilizing waste materials in optimal dosage offers sustainable concrete with balanced durability and performance. In this study, models were generated to predict alkali-silica reaction (ASR). Expansion for concrete modified with waste glass as cement replacement, such as linear, pure quadratic, and M5P-tree models based on the chemical composition of glass and cement, and other input parameters such as w/b, cement, fine aggregate, glass replacement, and immersion time. The findings indicate that incorporating glass powder effectively reduces expansion (%), with optimal dosages identified through the expansion-time optimizing technique. Comparative assessments reveal that while glass powder demonstrates notable ASR mitigation at lower dosages, fly ash exhibits superior long-term performance across all replacement levels, particularly after 28 days of immersion in NaOH solution. Additionally, slag performs competitively at higher dosages, indicating its potential utility in ASR reduction. Higher SiO2/CaO ratios lead to reduced ASR expansion, particularly with increased GP (%) and more extended curing periods. Higher GP (%) also results in higher ASR expansion, rising from 0.05 % in plain mortar to 0.2 % with 40 % GP after 3 days. In contrast, plain mortar bars with 0 % GP at a SiO2/CaO ratio of 0.3 show minimal ASR expansion of 0.03 % after 3 days, rising to 0.18 % after 28 days, indicating the critical role of immersion time in alkaline solutions.
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来源期刊
Sustainable Chemistry and Pharmacy
Sustainable Chemistry and Pharmacy Environmental Science-Pollution
CiteScore
8.20
自引率
6.70%
发文量
274
审稿时长
37 days
期刊介绍: Sustainable Chemistry and Pharmacy publishes research that is related to chemistry, pharmacy and sustainability science in a forward oriented manner. It provides a unique forum for the publication of innovative research on the intersection and overlap of chemistry and pharmacy on the one hand and sustainability on the other hand. This includes contributions related to increasing sustainability of chemistry and pharmaceutical science and industries itself as well as their products in relation to the contribution of these to sustainability itself. As an interdisciplinary and transdisciplinary journal it addresses all sustainability related issues along the life cycle of chemical and pharmaceutical products form resource related topics until the end of life of products. This includes not only natural science based approaches and issues but also from humanities, social science and economics as far as they are dealing with sustainability related to chemistry and pharmacy. Sustainable Chemistry and Pharmacy aims at bridging between disciplines as well as developing and developed countries.
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