Sein Lee, Yoonseo Jang, Wooho Ham, Jonghyun Bae, Kyunghwan Kim, Jeong-Min Park, Junseo Lee, Min-Kyu Song, Dohwan Jung, Prakash R. Sultane, Jae-Hoon Han, Christopher W. Bielawski, Jungwoo Oh, Jang-Yeon Kwon
{"title":"原子层沉积生长HfO2/BeO异质介质的高性能氧化薄膜晶体管","authors":"Sein Lee, Yoonseo Jang, Wooho Ham, Jonghyun Bae, Kyunghwan Kim, Jeong-Min Park, Junseo Lee, Min-Kyu Song, Dohwan Jung, Prakash R. Sultane, Jae-Hoon Han, Christopher W. Bielawski, Jungwoo Oh, Jang-Yeon Kwon","doi":"10.1021/acs.nanolett.5c00552","DOIUrl":null,"url":null,"abstract":"Atomic layer deposition-grown beryllium oxide (BeO) is gaining attention as a dielectric material that can minimize device power consumption because of its high dielectric constant, high thermal conductivity, and low leakage current enabled by its wide bandgap energy. In this study, the impact of BeO dielectrics on InSnZnO (ITZO) thin-film transistors (TFTs) was investigated, revealing that adding a hafnium dioxide (HfO<sub>2</sub>) layer can enhance electrical performance and bias stress reliability. Time-of-flight secondary-ion mass spectrometry and X-ray photoelectron spectroscopy confirmed that the single-BeO dielectric-based ITZO TFTs exhibited a low mobility of 27.6 cm<sup>2</sup>/V·s due to Be migration and demonstrated abnormal threshold voltage (<i>V</i><sub>TH</sub>) shifts under bias stress. Conversely, the HfO<sub>2</sub> 20 nm/BeO hetero-dielectric ITZO TFTs exhibited a high mobility of 76.6 cm<sup>2</sup>/V·s and enhanced abnormal <i>V</i><sub>TH</sub> shift characteristics. Therefore, these results demonstrate that our high-performance HfO<sub>2</sub>/BeO hetero-dielectric-based ITZO TFTs could be utilized in back-end-of-line devices for monolithic three-dimensional memory technologies.","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"653 1","pages":""},"PeriodicalIF":9.6000,"publicationDate":"2025-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High-Performance Oxide Thin-Film Transistors with Atomic Layer Deposition-Grown HfO2/BeO Hetero-Dielectric\",\"authors\":\"Sein Lee, Yoonseo Jang, Wooho Ham, Jonghyun Bae, Kyunghwan Kim, Jeong-Min Park, Junseo Lee, Min-Kyu Song, Dohwan Jung, Prakash R. Sultane, Jae-Hoon Han, Christopher W. Bielawski, Jungwoo Oh, Jang-Yeon Kwon\",\"doi\":\"10.1021/acs.nanolett.5c00552\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Atomic layer deposition-grown beryllium oxide (BeO) is gaining attention as a dielectric material that can minimize device power consumption because of its high dielectric constant, high thermal conductivity, and low leakage current enabled by its wide bandgap energy. In this study, the impact of BeO dielectrics on InSnZnO (ITZO) thin-film transistors (TFTs) was investigated, revealing that adding a hafnium dioxide (HfO<sub>2</sub>) layer can enhance electrical performance and bias stress reliability. Time-of-flight secondary-ion mass spectrometry and X-ray photoelectron spectroscopy confirmed that the single-BeO dielectric-based ITZO TFTs exhibited a low mobility of 27.6 cm<sup>2</sup>/V·s due to Be migration and demonstrated abnormal threshold voltage (<i>V</i><sub>TH</sub>) shifts under bias stress. Conversely, the HfO<sub>2</sub> 20 nm/BeO hetero-dielectric ITZO TFTs exhibited a high mobility of 76.6 cm<sup>2</sup>/V·s and enhanced abnormal <i>V</i><sub>TH</sub> shift characteristics. Therefore, these results demonstrate that our high-performance HfO<sub>2</sub>/BeO hetero-dielectric-based ITZO TFTs could be utilized in back-end-of-line devices for monolithic three-dimensional memory technologies.\",\"PeriodicalId\":53,\"journal\":{\"name\":\"Nano Letters\",\"volume\":\"653 1\",\"pages\":\"\"},\"PeriodicalIF\":9.6000,\"publicationDate\":\"2025-04-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.nanolett.5c00552\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Letters","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acs.nanolett.5c00552","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
High-Performance Oxide Thin-Film Transistors with Atomic Layer Deposition-Grown HfO2/BeO Hetero-Dielectric
Atomic layer deposition-grown beryllium oxide (BeO) is gaining attention as a dielectric material that can minimize device power consumption because of its high dielectric constant, high thermal conductivity, and low leakage current enabled by its wide bandgap energy. In this study, the impact of BeO dielectrics on InSnZnO (ITZO) thin-film transistors (TFTs) was investigated, revealing that adding a hafnium dioxide (HfO2) layer can enhance electrical performance and bias stress reliability. Time-of-flight secondary-ion mass spectrometry and X-ray photoelectron spectroscopy confirmed that the single-BeO dielectric-based ITZO TFTs exhibited a low mobility of 27.6 cm2/V·s due to Be migration and demonstrated abnormal threshold voltage (VTH) shifts under bias stress. Conversely, the HfO2 20 nm/BeO hetero-dielectric ITZO TFTs exhibited a high mobility of 76.6 cm2/V·s and enhanced abnormal VTH shift characteristics. Therefore, these results demonstrate that our high-performance HfO2/BeO hetero-dielectric-based ITZO TFTs could be utilized in back-end-of-line devices for monolithic three-dimensional memory technologies.
期刊介绍:
Nano Letters serves as a dynamic platform for promptly disseminating original results in fundamental, applied, and emerging research across all facets of nanoscience and nanotechnology. A pivotal criterion for inclusion within Nano Letters is the convergence of at least two different areas or disciplines, ensuring a rich interdisciplinary scope. The journal is dedicated to fostering exploration in diverse areas, including:
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