刺激响应智能溶剂及其在液-液（微）萃取分析技术中的应用

IF 11.8 1区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Analytical Chemistry Pub Date : 2025-04-14 DOI:10.1016/j.trac.2025.118267

Miguel Ángel Aguirre , Lorena Vidal , Mazaher Ahmadi , Antonio Canals

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引用次数: 0

摘要

可切换亲水性溶剂是一种新型溶剂，在液-液（微）萃取中具有广阔的应用前景。然而，它们很少用于化学分析的这一关键步骤。这篇文章提出了一个全面的和关键的审查基本，化学因素和刺激，可逆地改变这些溶剂的极性。这种独特的特性允许溶剂从疏水状态到亲水状态的可逆转变，有利于液-液（微）萃取。特别关注了光和电压等新型刺激，以扩大这些激励溶剂在液液（微）萃取中的适用性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Stimulus-responsive smart solvents and their application in analytical liquid-liquid (micro)extraction techniques

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Stimulus-responsive smart solvents and their application in analytical liquid-liquid (micro)extraction techniques

Switchable-hydrophilicity solvents are a new type of solvents that could be very promising for liquid-liquid (micro)extraction. Nevertheless, they have been scarcely used in this critical step of chemical analysis. This article presents a comprehensive and critical review of fundamentals, chemical factors and stimulus, that reversibly modify the polarity of these solvents. This unique characteristic allows the reversible transition of the solvent from a hydrophobic to a hydrophilic state, favoring liquid-liquid (micro)extraction. Special attention is paid to new types of stimuli as light and voltage to extend the applicability of these exciting solvents in liquid-liquid (micro)extraction.

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来源期刊

Trends in Analytical Chemistry 化学-分析化学

CiteScore

20.00

自引率

4.60%

发文量

257

审稿时长

3.4 months

期刊介绍： TrAC publishes succinct and critical overviews of recent advancements in analytical chemistry, designed to assist analytical chemists and other users of analytical techniques. These reviews offer excellent, up-to-date, and timely coverage of various topics within analytical chemistry. Encompassing areas such as analytical instrumentation, biomedical analysis, biomolecular analysis, biosensors, chemical analysis, chemometrics, clinical chemistry, drug discovery, environmental analysis and monitoring, food analysis, forensic science, laboratory automation, materials science, metabolomics, pesticide-residue analysis, pharmaceutical analysis, proteomics, surface science, and water analysis and monitoring, these critical reviews provide comprehensive insights for practitioners in the field.