Shammi Aktar , Abu Reza Md Towfiqul Islam , Md Moniruzzaman , Md Abu Bakar Siddique , Md Abdullah Al Masud , Aznarul Islam , Subodh Chandra Pal , N. Subba Rao , Javed Maallick
{"title":"沿海多层含水层的氟化物富集和水文地球化学特征:对公众健康和营养的影响","authors":"Shammi Aktar , Abu Reza Md Towfiqul Islam , Md Moniruzzaman , Md Abu Bakar Siddique , Md Abdullah Al Masud , Aznarul Islam , Subodh Chandra Pal , N. Subba Rao , Javed Maallick","doi":"10.1016/j.pce.2025.103924","DOIUrl":null,"url":null,"abstract":"<div><div>Coastal freshwater is essential for drinking water needs, but its scarcity is increasing due to saltwater intrusion and human inputs in many tropical anthropogenically modified coasts around the worldwide. However, in some areas, including Bangladesh, groundwater quality has not been extensively studied concerning fluoride contamination, its hydrogeochemical properties, human health impacts, and nutrient dynamics. The present study aimed to assess the fluoride enrichment and broad hydrogeochemical properties of multiple aquifers along the modified tropical coast of Cox's Bazar, Bangladesh. A total of 91 groundwater samples from shallow aquifers (SA), middle aquifers (MA), and deep aquifers (DA) were analyzed for hydrogeochemical elements. The results revealed that fluoride concentrations exceeded the permissible limit (1.50 mg/L) in 29 %, 25 %, and 27 % of SA, MA, and DA samples, with a maximum concentration of 13.5 mg/L. The saturation index indicated that evaporation intensified fluoride enrichment in over 40 % of groundwater samples, coinciding with increased total dissolved solids (TDS). The fluoride enrichment in the SA system was attributed to evaporite dissolution, carbonate weathering, desorption, competitive adsorption, cation exchange, and mineral dissolution-precipitation processes. Stable isotope analysis suggested that MA water was unaffected by evaporation during recharge, while recent recharge events influenced the isotopic composition of SA and DA waters, primarily through rainfall infiltration. The entropy water quality index classified 87.4 %, 91.8 %, and 82.9 % of respective SA, MA, and DA groundwater samples as very poor in quality. Health risk assessment revealed that SA posed the highest non-carcinogenic risk (83.02 %), followed by MA (12.03 %) and DA (9.75 %). Adults using SA water faced five times higher health risks than children, with the northern region identified as a hotspot for nutritional risks. Daily water intake exacerbated the health risks, particularly among adults. The findings emphasize the urgent need for sustainable groundwater management strategies to ensure safe drinking water supplies in tropical, anthropogenically altered coastal regions.</div></div>","PeriodicalId":54616,"journal":{"name":"Physics and Chemistry of the Earth","volume":"139 ","pages":"Article 103924"},"PeriodicalIF":3.0000,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fluoride enrichment and hydrogeochemical characteristics in coastal multi-aquifers: Implications for public health and nutrition\",\"authors\":\"Shammi Aktar , Abu Reza Md Towfiqul Islam , Md Moniruzzaman , Md Abu Bakar Siddique , Md Abdullah Al Masud , Aznarul Islam , Subodh Chandra Pal , N. Subba Rao , Javed Maallick\",\"doi\":\"10.1016/j.pce.2025.103924\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Coastal freshwater is essential for drinking water needs, but its scarcity is increasing due to saltwater intrusion and human inputs in many tropical anthropogenically modified coasts around the worldwide. However, in some areas, including Bangladesh, groundwater quality has not been extensively studied concerning fluoride contamination, its hydrogeochemical properties, human health impacts, and nutrient dynamics. The present study aimed to assess the fluoride enrichment and broad hydrogeochemical properties of multiple aquifers along the modified tropical coast of Cox's Bazar, Bangladesh. A total of 91 groundwater samples from shallow aquifers (SA), middle aquifers (MA), and deep aquifers (DA) were analyzed for hydrogeochemical elements. The results revealed that fluoride concentrations exceeded the permissible limit (1.50 mg/L) in 29 %, 25 %, and 27 % of SA, MA, and DA samples, with a maximum concentration of 13.5 mg/L. The saturation index indicated that evaporation intensified fluoride enrichment in over 40 % of groundwater samples, coinciding with increased total dissolved solids (TDS). The fluoride enrichment in the SA system was attributed to evaporite dissolution, carbonate weathering, desorption, competitive adsorption, cation exchange, and mineral dissolution-precipitation processes. Stable isotope analysis suggested that MA water was unaffected by evaporation during recharge, while recent recharge events influenced the isotopic composition of SA and DA waters, primarily through rainfall infiltration. The entropy water quality index classified 87.4 %, 91.8 %, and 82.9 % of respective SA, MA, and DA groundwater samples as very poor in quality. Health risk assessment revealed that SA posed the highest non-carcinogenic risk (83.02 %), followed by MA (12.03 %) and DA (9.75 %). Adults using SA water faced five times higher health risks than children, with the northern region identified as a hotspot for nutritional risks. Daily water intake exacerbated the health risks, particularly among adults. The findings emphasize the urgent need for sustainable groundwater management strategies to ensure safe drinking water supplies in tropical, anthropogenically altered coastal regions.</div></div>\",\"PeriodicalId\":54616,\"journal\":{\"name\":\"Physics and Chemistry of the Earth\",\"volume\":\"139 \",\"pages\":\"Article 103924\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2025-04-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physics and Chemistry of the Earth\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1474706525000749\",\"RegionNum\":3,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics and Chemistry of the Earth","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1474706525000749","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
Fluoride enrichment and hydrogeochemical characteristics in coastal multi-aquifers: Implications for public health and nutrition
Coastal freshwater is essential for drinking water needs, but its scarcity is increasing due to saltwater intrusion and human inputs in many tropical anthropogenically modified coasts around the worldwide. However, in some areas, including Bangladesh, groundwater quality has not been extensively studied concerning fluoride contamination, its hydrogeochemical properties, human health impacts, and nutrient dynamics. The present study aimed to assess the fluoride enrichment and broad hydrogeochemical properties of multiple aquifers along the modified tropical coast of Cox's Bazar, Bangladesh. A total of 91 groundwater samples from shallow aquifers (SA), middle aquifers (MA), and deep aquifers (DA) were analyzed for hydrogeochemical elements. The results revealed that fluoride concentrations exceeded the permissible limit (1.50 mg/L) in 29 %, 25 %, and 27 % of SA, MA, and DA samples, with a maximum concentration of 13.5 mg/L. The saturation index indicated that evaporation intensified fluoride enrichment in over 40 % of groundwater samples, coinciding with increased total dissolved solids (TDS). The fluoride enrichment in the SA system was attributed to evaporite dissolution, carbonate weathering, desorption, competitive adsorption, cation exchange, and mineral dissolution-precipitation processes. Stable isotope analysis suggested that MA water was unaffected by evaporation during recharge, while recent recharge events influenced the isotopic composition of SA and DA waters, primarily through rainfall infiltration. The entropy water quality index classified 87.4 %, 91.8 %, and 82.9 % of respective SA, MA, and DA groundwater samples as very poor in quality. Health risk assessment revealed that SA posed the highest non-carcinogenic risk (83.02 %), followed by MA (12.03 %) and DA (9.75 %). Adults using SA water faced five times higher health risks than children, with the northern region identified as a hotspot for nutritional risks. Daily water intake exacerbated the health risks, particularly among adults. The findings emphasize the urgent need for sustainable groundwater management strategies to ensure safe drinking water supplies in tropical, anthropogenically altered coastal regions.
期刊介绍:
Physics and Chemistry of the Earth is an international interdisciplinary journal for the rapid publication of collections of refereed communications in separate thematic issues, either stemming from scientific meetings, or, especially compiled for the occasion. There is no restriction on the length of articles published in the journal. Physics and Chemistry of the Earth incorporates the separate Parts A, B and C which existed until the end of 2001.
Please note: the Editors are unable to consider submissions that are not invited or linked to a thematic issue. Please do not submit unsolicited papers.
The journal covers the following subject areas:
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(geology, geochemistry, tectonophysics, seismology, volcanology, palaeomagnetism and rock magnetism, electromagnetism and potential fields, marine and environmental geosciences as well as geodesy).
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(hydrology and water resources research, engineering and management, oceanography and oceanic chemistry, shelf, sea, lake and river sciences, meteorology and atmospheric sciences incl. chemistry as well as climatology and glaciology).
-Solar-Terrestrial and Planetary Science:
(solar, heliospheric and solar-planetary sciences, geology, geophysics and atmospheric sciences of planets, satellites and small bodies as well as cosmochemistry and exobiology).