ZnO纳米颗粒包被稻壳生物吸附剂去除污染水样中的砷、磷酸盐和氟化物

Md. Iftikar Hussain , Nazrin Akhtara Rahman , Happymoni Dutta , Dipjyoti Dutta , Rekha Rani Dutta
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引用次数: 0

摘要

研究了一种新型高效生物吸附剂,利用ZnO纳米颗粒包覆稻壳粉去除水样中的砷(V)、磷酸(PO43-)和氟化物(F-)。本文采用化学沉淀法以腐烂的甘薯果肉为原料合成氧化锌纳米颗粒。利用稻壳渣作为吸附载体是本研究的重要发现和新颖之处。纳米氧化锌与稻壳的结合不仅提供了大的吸附表面积,而且提高了吸附速率。通过pH、接触时间、初始吸附浓度等因素对所研制的生物吸附剂进行了批量吸附研究。所研制的生物吸附剂在最小吸附剂用量(2 g L−1)和180 min的接触时间下具有较高的去除效果。采用非线性曲线拟合的方法对Langmuir和Freundlich等温线和动力学模型的吸附平衡数据进行了研究。砷的吸附平衡符合Langmuir等温线(R2= 0.9975),磷酸盐的吸附平衡符合Freundlich等温线(R2= 0)。88257)和氟(R2= 0.91887)。非线性曲线拟合模型得到的最大吸附量分别为砷28.23 mg/g、磷酸盐7.928 mg/g和氟化物23.01 mg/g。从实际污染水样中100% %的As (III)去除率表明,所开发的生物吸附剂将是去除污染地下水中毒素的绝佳机会。通过一个简单的机理解释了所开发的生物吸附剂的工作原理,突出了本工作的新方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ZnO nanoparticles coated rice husk bio adsorbent for the removal of arsenic, phosphate and fluoride from contaminated water samples
A novel and cost effective bio adsorbent is developed for the removal of As (V), phosphate (PO43-) and fluoride (F-) from water samples by using ZnO nanoparticles coated waste rice husk powder. ZnO nano particles used in this work are synthesized from rotten sweet potato pulp through Chemical precipitation method. The use of rice husk waste as an adsorption support is the key finding and novelty of this work. Integration of ZnO nano with rice husk not only provides high surface area for adsorption but also increase the adsorption rate. The batch adsorption study of the developed bio adsorbent was systematically carried out through the effect of pH, contact time, initial adsorbate concentrations etc. The developed bio adsorbent showed high removal efficiency with a minimum dosage of adsorbent (2 g L−1) and 180 minutes of contact time. The sorption equilibrium data fitted to Langmuir and Freundlich isotherm and kinetic model was studied by nonlinear curve fitting. The sorption equilibrium well to Langmuir (R2 = 0.9975) isotherm for arsenic, Freundlich isotherm for both phosphate (R2= 0. 88257) and fluoride (R2= 0.91887). The maximum adsorption capacity is 28.23 mg/g for arsenic, 7.928 mg/g for phosphate and 23.01 mg/g for fluoride obtained from nonlinear curve fitting model. The 100 % removal of As (III) from real contaminated water sample signifies that the developed bio adsorbent will be an excellent opportunity for the removal of toxins from contaminated ground water. The developed bio adsorbent’s working principle is explained through a simple mechanism, highlighting a novel approach in this work.
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