{"title":"综合奇点-能量分析揭示矿化相关地球化学模式","authors":"Saeid Esmaeiloghli , Mahyar Yousefi","doi":"10.1016/j.gexplo.2025.107788","DOIUrl":null,"url":null,"abstract":"<div><div>During the last two decades, local singularity analysis (LSA) has become a leading technique to enhance weak geochemical anomalies associated with non-linear ore-forming processes operating in complex Earth systems. Singularity maps of multiple ore-forming elements are preferably synthesized to reveal multi-element geochemical anomalies and to portray them as stronger mineralization-related geochemical signatures. In this regard, classifying anomalous components is crucial to identify different patterns of ore formation-related geochemical anomalies, a step forward to delimit target areas for metal exploration. This research puts forward an integrated singularity–energy (S–E) analysis dealing with the variety in the metal enrichment patterns obtained from singularity mapping of multiple ore-forming elements. As per the S–E methodology, the LSA is applied to the rasterized geochemical maps with the aim of reducing the adverse effects of overburden and enhancing weak geochemical anomalies. Relying on multi-sample energy statistics, a <em>k</em>-groups partitioning based on energy distance is then devised to classify singularity maps into <span><math><mi>k</mi></math></span> patterns with contrasting probability distributions, thereby recognizing different patterns of multi-element geochemical anomalies. Eventually, prospectivity indices for the resulting S–E patterns are calculated to prioritize mineralization-related patterns and to automate the definition of exploration targets. The potential application of the S–E analysis is demonstrated by a stream sediment geochemical dataset (viz. Cu, Au, Pb, and Zn) pertaining to the Moalleman district, NE Iran. Moreover, additional geochemical patterns are recognized by concentration–area multifractal modeling of additive geochemical indices and by <em>k</em>-means clustering of singularity maps of ore-forming elements, serving as traditional references to constitute comparative analyses. Appraisal by success-rate curves indicates that metal enrichment patterns derived from S–E analysis, compared to those from traditional approaches, establish a more significant spatial conformity with hydrothermal- and epithermal-type mineralization events within the study area. The findings suggest that the proposed technique has robust properties to bring more efficient exploration knowledge and reliable evidence for prospecting buried and covered metal deposits within complex Earth systems.</div></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"275 ","pages":"Article 107788"},"PeriodicalIF":3.4000,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"An integrated singularity–energy analysis to reveal mineralization-related geochemical patterns\",\"authors\":\"Saeid Esmaeiloghli , Mahyar Yousefi\",\"doi\":\"10.1016/j.gexplo.2025.107788\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>During the last two decades, local singularity analysis (LSA) has become a leading technique to enhance weak geochemical anomalies associated with non-linear ore-forming processes operating in complex Earth systems. Singularity maps of multiple ore-forming elements are preferably synthesized to reveal multi-element geochemical anomalies and to portray them as stronger mineralization-related geochemical signatures. In this regard, classifying anomalous components is crucial to identify different patterns of ore formation-related geochemical anomalies, a step forward to delimit target areas for metal exploration. This research puts forward an integrated singularity–energy (S–E) analysis dealing with the variety in the metal enrichment patterns obtained from singularity mapping of multiple ore-forming elements. As per the S–E methodology, the LSA is applied to the rasterized geochemical maps with the aim of reducing the adverse effects of overburden and enhancing weak geochemical anomalies. Relying on multi-sample energy statistics, a <em>k</em>-groups partitioning based on energy distance is then devised to classify singularity maps into <span><math><mi>k</mi></math></span> patterns with contrasting probability distributions, thereby recognizing different patterns of multi-element geochemical anomalies. Eventually, prospectivity indices for the resulting S–E patterns are calculated to prioritize mineralization-related patterns and to automate the definition of exploration targets. The potential application of the S–E analysis is demonstrated by a stream sediment geochemical dataset (viz. Cu, Au, Pb, and Zn) pertaining to the Moalleman district, NE Iran. Moreover, additional geochemical patterns are recognized by concentration–area multifractal modeling of additive geochemical indices and by <em>k</em>-means clustering of singularity maps of ore-forming elements, serving as traditional references to constitute comparative analyses. Appraisal by success-rate curves indicates that metal enrichment patterns derived from S–E analysis, compared to those from traditional approaches, establish a more significant spatial conformity with hydrothermal- and epithermal-type mineralization events within the study area. The findings suggest that the proposed technique has robust properties to bring more efficient exploration knowledge and reliable evidence for prospecting buried and covered metal deposits within complex Earth systems.</div></div>\",\"PeriodicalId\":16336,\"journal\":{\"name\":\"Journal of Geochemical Exploration\",\"volume\":\"275 \",\"pages\":\"Article 107788\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2025-04-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Geochemical Exploration\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0375674225001207\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0375674225001207","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
An integrated singularity–energy analysis to reveal mineralization-related geochemical patterns
During the last two decades, local singularity analysis (LSA) has become a leading technique to enhance weak geochemical anomalies associated with non-linear ore-forming processes operating in complex Earth systems. Singularity maps of multiple ore-forming elements are preferably synthesized to reveal multi-element geochemical anomalies and to portray them as stronger mineralization-related geochemical signatures. In this regard, classifying anomalous components is crucial to identify different patterns of ore formation-related geochemical anomalies, a step forward to delimit target areas for metal exploration. This research puts forward an integrated singularity–energy (S–E) analysis dealing with the variety in the metal enrichment patterns obtained from singularity mapping of multiple ore-forming elements. As per the S–E methodology, the LSA is applied to the rasterized geochemical maps with the aim of reducing the adverse effects of overburden and enhancing weak geochemical anomalies. Relying on multi-sample energy statistics, a k-groups partitioning based on energy distance is then devised to classify singularity maps into patterns with contrasting probability distributions, thereby recognizing different patterns of multi-element geochemical anomalies. Eventually, prospectivity indices for the resulting S–E patterns are calculated to prioritize mineralization-related patterns and to automate the definition of exploration targets. The potential application of the S–E analysis is demonstrated by a stream sediment geochemical dataset (viz. Cu, Au, Pb, and Zn) pertaining to the Moalleman district, NE Iran. Moreover, additional geochemical patterns are recognized by concentration–area multifractal modeling of additive geochemical indices and by k-means clustering of singularity maps of ore-forming elements, serving as traditional references to constitute comparative analyses. Appraisal by success-rate curves indicates that metal enrichment patterns derived from S–E analysis, compared to those from traditional approaches, establish a more significant spatial conformity with hydrothermal- and epithermal-type mineralization events within the study area. The findings suggest that the proposed technique has robust properties to bring more efficient exploration knowledge and reliable evidence for prospecting buried and covered metal deposits within complex Earth systems.
期刊介绍:
Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics.
Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to:
define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas.
analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation.
evaluate effects of historical mining activities on the surface environment.
trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices.
assess and quantify natural and technogenic radioactivity in the environment.
determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis.
assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches.
Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.