液相还原法制备氮掺杂铂钕纳米合金氧还原催化剂

IF 6.5 3区 材料科学 Q2 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY
Hang Jiang, Qianwen Liu, Wei Song, Pei Gong, Zhihong Yu, Zhicheng Liang
{"title":"液相还原法制备氮掺杂铂钕纳米合金氧还原催化剂","authors":"Hang Jiang,&nbsp;Qianwen Liu,&nbsp;Wei Song,&nbsp;Pei Gong,&nbsp;Zhihong Yu,&nbsp;Zhicheng Liang","doi":"10.1002/adsu.202400944","DOIUrl":null,"url":null,"abstract":"<p>Proton exchange membrane fuel cells (PEMFCs) have attracted significant research interest due to their ability to generate only water and energy. PEMFCs operate based on the principle of redox reactions, which require a catalyst for the individual half-reactions. However, the commonly used platinum (Pt)-based catalysts are expensive, and their performance needs enhancement. In this study, an effective strategy is presented for preparing Pt–rare earth nanoalloy catalysts, achieving improvements in catalytic performance while reducing costs. Additionally, through urea modification, a novel carbon carrier (XC-72) is successfully developed, which is widely utilized as a catalyst support in fuel cells. The Pt–Nd@HCN-400 catalyst is synthesized by combining the newly developed carrier with the Pt–Nd alloy. Under standard fuel cell operating conditions, this catalyst exhibited a 5% increase in durability compared to its unmodified counterpart. This study offers a promising approach for enhancing the durability of PEMFC catalysts.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5000,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Nitrogen-Doped Platinum–Neodymium Nanoalloy Catalyst by Liquid-Phase Reduction for Oxygen Reduction Reaction\",\"authors\":\"Hang Jiang,&nbsp;Qianwen Liu,&nbsp;Wei Song,&nbsp;Pei Gong,&nbsp;Zhihong Yu,&nbsp;Zhicheng Liang\",\"doi\":\"10.1002/adsu.202400944\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Proton exchange membrane fuel cells (PEMFCs) have attracted significant research interest due to their ability to generate only water and energy. PEMFCs operate based on the principle of redox reactions, which require a catalyst for the individual half-reactions. However, the commonly used platinum (Pt)-based catalysts are expensive, and their performance needs enhancement. In this study, an effective strategy is presented for preparing Pt–rare earth nanoalloy catalysts, achieving improvements in catalytic performance while reducing costs. Additionally, through urea modification, a novel carbon carrier (XC-72) is successfully developed, which is widely utilized as a catalyst support in fuel cells. The Pt–Nd@HCN-400 catalyst is synthesized by combining the newly developed carrier with the Pt–Nd alloy. Under standard fuel cell operating conditions, this catalyst exhibited a 5% increase in durability compared to its unmodified counterpart. This study offers a promising approach for enhancing the durability of PEMFC catalysts.</p>\",\"PeriodicalId\":7294,\"journal\":{\"name\":\"Advanced Sustainable Systems\",\"volume\":\"9 4\",\"pages\":\"\"},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2025-02-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Sustainable Systems\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400944\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Sustainable Systems","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400944","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY","Score":null,"Total":0}
引用次数: 0

摘要

质子交换膜燃料电池(pemfc)由于其只产生水和能量的能力而引起了人们极大的研究兴趣。pemfc的工作原理基于氧化还原反应,这需要催化剂来进行单个半反应。然而,常用的铂基催化剂价格昂贵,性能有待提高。本研究提出了一种制备pt -稀土纳米合金催化剂的有效策略,在提高催化性能的同时降低了成本。此外,通过尿素改性,成功研制出一种新型碳载体(XC-72),广泛应用于燃料电池的催化剂载体。将新研制的载体与Pt - nd合金结合,合成了Pt - Nd@HCN-400催化剂。在标准燃料电池运行条件下,这种催化剂的耐久性比未改性的催化剂提高了5%。该研究为提高PEMFC催化剂的耐久性提供了一种有希望的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis of Nitrogen-Doped Platinum–Neodymium Nanoalloy Catalyst by Liquid-Phase Reduction for Oxygen Reduction Reaction

Synthesis of Nitrogen-Doped Platinum–Neodymium Nanoalloy Catalyst by Liquid-Phase Reduction for Oxygen Reduction Reaction

Proton exchange membrane fuel cells (PEMFCs) have attracted significant research interest due to their ability to generate only water and energy. PEMFCs operate based on the principle of redox reactions, which require a catalyst for the individual half-reactions. However, the commonly used platinum (Pt)-based catalysts are expensive, and their performance needs enhancement. In this study, an effective strategy is presented for preparing Pt–rare earth nanoalloy catalysts, achieving improvements in catalytic performance while reducing costs. Additionally, through urea modification, a novel carbon carrier (XC-72) is successfully developed, which is widely utilized as a catalyst support in fuel cells. The Pt–Nd@HCN-400 catalyst is synthesized by combining the newly developed carrier with the Pt–Nd alloy. Under standard fuel cell operating conditions, this catalyst exhibited a 5% increase in durability compared to its unmodified counterpart. This study offers a promising approach for enhancing the durability of PEMFC catalysts.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Advanced Sustainable Systems
Advanced Sustainable Systems Environmental Science-General Environmental Science
CiteScore
10.80
自引率
4.20%
发文量
186
期刊介绍: Advanced Sustainable Systems, a part of the esteemed Advanced portfolio, serves as an interdisciplinary sustainability science journal. It focuses on impactful research in the advancement of sustainable, efficient, and less wasteful systems and technologies. Aligned with the UN's Sustainable Development Goals, the journal bridges knowledge gaps between fundamental research, implementation, and policy-making. Covering diverse topics such as climate change, food sustainability, environmental science, renewable energy, water, urban development, and socio-economic challenges, it contributes to the understanding and promotion of sustainable systems.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信