{"title":"液相还原法制备氮掺杂铂钕纳米合金氧还原催化剂","authors":"Hang Jiang, Qianwen Liu, Wei Song, Pei Gong, Zhihong Yu, Zhicheng Liang","doi":"10.1002/adsu.202400944","DOIUrl":null,"url":null,"abstract":"<p>Proton exchange membrane fuel cells (PEMFCs) have attracted significant research interest due to their ability to generate only water and energy. PEMFCs operate based on the principle of redox reactions, which require a catalyst for the individual half-reactions. However, the commonly used platinum (Pt)-based catalysts are expensive, and their performance needs enhancement. In this study, an effective strategy is presented for preparing Pt–rare earth nanoalloy catalysts, achieving improvements in catalytic performance while reducing costs. Additionally, through urea modification, a novel carbon carrier (XC-72) is successfully developed, which is widely utilized as a catalyst support in fuel cells. The Pt–Nd@HCN-400 catalyst is synthesized by combining the newly developed carrier with the Pt–Nd alloy. Under standard fuel cell operating conditions, this catalyst exhibited a 5% increase in durability compared to its unmodified counterpart. This study offers a promising approach for enhancing the durability of PEMFC catalysts.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5000,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Nitrogen-Doped Platinum–Neodymium Nanoalloy Catalyst by Liquid-Phase Reduction for Oxygen Reduction Reaction\",\"authors\":\"Hang Jiang, Qianwen Liu, Wei Song, Pei Gong, Zhihong Yu, Zhicheng Liang\",\"doi\":\"10.1002/adsu.202400944\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Proton exchange membrane fuel cells (PEMFCs) have attracted significant research interest due to their ability to generate only water and energy. PEMFCs operate based on the principle of redox reactions, which require a catalyst for the individual half-reactions. However, the commonly used platinum (Pt)-based catalysts are expensive, and their performance needs enhancement. In this study, an effective strategy is presented for preparing Pt–rare earth nanoalloy catalysts, achieving improvements in catalytic performance while reducing costs. Additionally, through urea modification, a novel carbon carrier (XC-72) is successfully developed, which is widely utilized as a catalyst support in fuel cells. The Pt–Nd@HCN-400 catalyst is synthesized by combining the newly developed carrier with the Pt–Nd alloy. Under standard fuel cell operating conditions, this catalyst exhibited a 5% increase in durability compared to its unmodified counterpart. This study offers a promising approach for enhancing the durability of PEMFC catalysts.</p>\",\"PeriodicalId\":7294,\"journal\":{\"name\":\"Advanced Sustainable Systems\",\"volume\":\"9 4\",\"pages\":\"\"},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2025-02-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Sustainable Systems\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400944\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Sustainable Systems","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400944","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Synthesis of Nitrogen-Doped Platinum–Neodymium Nanoalloy Catalyst by Liquid-Phase Reduction for Oxygen Reduction Reaction
Proton exchange membrane fuel cells (PEMFCs) have attracted significant research interest due to their ability to generate only water and energy. PEMFCs operate based on the principle of redox reactions, which require a catalyst for the individual half-reactions. However, the commonly used platinum (Pt)-based catalysts are expensive, and their performance needs enhancement. In this study, an effective strategy is presented for preparing Pt–rare earth nanoalloy catalysts, achieving improvements in catalytic performance while reducing costs. Additionally, through urea modification, a novel carbon carrier (XC-72) is successfully developed, which is widely utilized as a catalyst support in fuel cells. The Pt–Nd@HCN-400 catalyst is synthesized by combining the newly developed carrier with the Pt–Nd alloy. Under standard fuel cell operating conditions, this catalyst exhibited a 5% increase in durability compared to its unmodified counterpart. This study offers a promising approach for enhancing the durability of PEMFC catalysts.
期刊介绍:
Advanced Sustainable Systems, a part of the esteemed Advanced portfolio, serves as an interdisciplinary sustainability science journal. It focuses on impactful research in the advancement of sustainable, efficient, and less wasteful systems and technologies. Aligned with the UN's Sustainable Development Goals, the journal bridges knowledge gaps between fundamental research, implementation, and policy-making. Covering diverse topics such as climate change, food sustainability, environmental science, renewable energy, water, urban development, and socio-economic challenges, it contributes to the understanding and promotion of sustainable systems.