Balancing performance and stability characteristics in organic electrochemical transistor

Nowadays organic electrochemical transistors (OECTs) are becoming a promising platform for bioelectronics and biosensing due to its biocompatibility, high sensitivity and selectivity, low driving voltages, high transconductance and flexibility. However, the existing problems associated with degradation processes within the OECT during long-term operation hinder their widespread implementation. Moreover, trade-offs often arise between OECT transconductance and speed, fast ion transport and electron mobility, electrochemical stability and sensitivity, cycling stability and signal amplification, and other metrics. Ensuring high performance characteristics and achieving enhanced stability in OECTs are distinct strategies that do not always align, as progress in one aspect often necessitates a trade-off with the other. This dynamic arises from the need to find a balance between reversible and irreversible processes in the behavior of OECT active layers, and providing simultaneously favorable conditions for ion and electron transport and their efficient charge coupling. This review article systematically summarizes the phenomenological and physical-chemical aspects associated with factors and mechanisms that determine both performance and long-term stability of OECT, paying special attention to the consideration of existing and promising approaches to extend the OECT lifespan, while maintaining (or even increasing) high effectiveness of its operation.