豆荚生物质碳量子点（CQDs）在UVC和可见光照射下增强全氟烷基羧酸（PFCAs）光降解的复合光催化剂中的作用

IF 6.3 2区工程技术 Q1 ENGINEERING, CHEMICAL

Journal of water process engineering Pub Date : 2025-04-16 DOI:10.1016/j.jwpe.2025.107750

Mona Nejatpour , Bergüzar Yılmaz , Burcu Ozden , Sibel Barisci , Meral Dükkancı

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引用次数: 0

摘要

由于全氟烷基羧酸的环境持久性和有害影响，其修复面临重大挑战。本研究以豆荚生物质为原料，通过水热法制备碳量子点（CQDs），并将其掺入二氧化钛（TiO2）复合光催化剂中。化学、形态学和光学分析证实了CQD/TiO2复合材料的高效合成，并表现出增强的光学性能。光催化氧化实验表明，与原始TiO2相比，CQD/TiO2复合材料对全氟辛酸（PFOA-C8）的降解效率显著提高，在紫外- c （UVC）和可见光下分别提高26.3%和24.5%。此外，在可见光照射下，对短链PFCAs，特别是全氟己酸（PFHxA-C6）、全氟戊酸（PFPeA-C5）、全氟丁酸（PFBA-C4）和全氟丙酸（PFPrA-C3）的光催化氧化进行了评价。与纯TiO2相比，使用CQD偶联TiO2 （CQD/TiO2）对PFHxA-C6和PFPeA-C5的降解率分别从14.6%和19.6%显著提高到41.3%和52.1%。一阶速率常数表明，PPCQD/TiO2光催化剂加速了PFCA的降解。中间生成（C3-C6）和除氟分析表明，在CQD/TiO2复合物存在下，PFCAs逐步分解，CF 2剥离增强。还研究了清除剂在可见光下降解全氟辛烷的作用。本研究强调了cqd增强TiO2光催化剂在可持续条件下对PFCA进行有效修复的潜力。

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The function of carbon quantum dots (CQDs) derived from peapod biomass in composite photocatalysts for the enhanced photodegradation of perfluoroalkyl carboxylic acids (PFCAs) under UVC and visible light irradiation

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The remediation of perfluoroalkyl carboxylic acids (PFCAs) presents a significant challenge due to their environmental persistence and detrimental impact. In this study, carbon quantum dots (CQDs) were sustainably prepared using peapod biomass via the hydrothermal method and incorporated into a titanium dioxide (TiO₂) composite photocatalyst. Chemical, morphological, and optical analysis confirmed the efficient synthesis of the CQD/TiO₂ composite, which exhibited enhanced optical properties. Photocatalytic oxidation experiments demonstrated that the CQD/TiO₂ composite achieved significantly higher degradation efficiencies for perfluorooctanoic acid (PFOA-C₈) compared to pristine TiO₂, with 26.3 % and 24.5 % improvements when irradiated under Ultraviolet-C (UVC) and visible light, respectively. Furthermore, the photocatalytic oxidation of short-chain PFCAs, specifically perfluorohexanoic acid (PFHxA-C₆), perfluoropentanoic acid (PFPeA-C₅), perfluorobutanoic acid (PFBA-C₄), and perfluoropropanoic acid (PFPrA-C₃), were evaluated under visible light irradiation. Degradation rates for PFHxA-C₆ and PFPeA-C₅ significantly enhanced from 14.6 % and 19.6 % to 41.3 % and 52.1 %, respectively, when using CQD-coupled TiO₂ (CQD/TiO₂) compared to pure TiO₂. The first-order rate constants revealed accelerated PFCA degradation using PPCQD/TiO₂ photocatalysts. Intermediate formation (C₃–C₆) and defluorination analyses revealed stepwise decomposition of PFCAs, with enhanced CF₂ detachment in the presence of the CQD/TiO₂ composite. The role of scavengers in PFOA degradation under visible light was also examined. This research underscores the potential of CQD-enhanced TiO₂ photocatalysts for effective PFCA remediation under sustainable conditions.

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来源期刊

Journal of water process engineering Biochemistry, Genetics and Molecular Biology-Biotechnology

CiteScore

10.70

自引率

8.60%

发文量

846

审稿时长

24 days

期刊介绍： The Journal of Water Process Engineering aims to publish refereed, high-quality research papers with significant novelty and impact in all areas of the engineering of water and wastewater processing . Papers on advanced and novel treatment processes and technologies are particularly welcome. The Journal considers papers in areas such as nanotechnology and biotechnology applications in water, novel oxidation and separation processes, membrane processes (except those for desalination) , catalytic processes for the removal of water contaminants, sustainable processes, water reuse and recycling, water use and wastewater minimization, integrated/hybrid technology, process modeling of water treatment and novel treatment processes. Submissions on the subject of adsorbents, including standard measurements of adsorption kinetics and equilibrium will only be considered if there is a genuine case for novelty and contribution, for example highly novel, sustainable adsorbents and their use: papers on activated carbon-type materials derived from natural matter, or surfactant-modified clays and related minerals, would not fulfil this criterion. The Journal particularly welcomes contributions involving environmentally, economically and socially sustainable technology for water treatment, including those which are energy-efficient, with minimal or no chemical consumption, and capable of water recycling and reuse that minimizes the direct disposal of wastewater to the aquatic environment. Papers that describe novel ideas for solving issues related to water quality and availability are also welcome, as are those that show the transfer of techniques from other disciplines. The Journal will consider papers dealing with processes for various water matrices including drinking water (except desalination), domestic, urban and industrial wastewaters, in addition to their residues. It is expected that the journal will be of particular relevance to chemical and process engineers working in the field. The Journal welcomes Full Text papers, Short Communications, State-of-the-Art Reviews and Letters to Editors and Case Studies