Meng Chen , Peisi Yin , Chengyi Gong , Hongrui Dou , Xiaoyu You , Xin Zhao , Xingyu Liu , Yongqi Yang , Xiangmin Du , Huaian Fu , Fei Song , Shanshan Yu , Kai Zhang , Zhipeng Tang , Jiacong Xu , Qiang Jing , Bo Liu
{"title":"一种稳定的室温化学H2气体传感器,在被水覆盖后,可以通过刷新其表面来恢复其初始状态","authors":"Meng Chen , Peisi Yin , Chengyi Gong , Hongrui Dou , Xiaoyu You , Xin Zhao , Xingyu Liu , Yongqi Yang , Xiangmin Du , Huaian Fu , Fei Song , Shanshan Yu , Kai Zhang , Zhipeng Tang , Jiacong Xu , Qiang Jing , Bo Liu","doi":"10.1016/j.ijhydene.2025.04.012","DOIUrl":null,"url":null,"abstract":"<div><div>Until now, no one hydrogen sensing technology can meet all requirements of application. Hydrogen sensors working in extreme conditions are needed. Chemiresistive gas sensors own lots of merits but suffer from high relative humidity (RH). Furthermore, if its surface is covered with H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O, the sensor must be abandoned as it cannot work again. Here, a chemiresistive H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> gas sensor based on Pt-WO<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> composite dense film which can restore itself to its initial state after being covered with H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O has been fabricated. The restoring is realized by first blow-drying then annealing. The H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O-covering–restoring circulation can last 10 times at least. Towards 50 ppm H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>, its response value decreases only 25% from RH=40% to 90% (RH set and measured at 25 °C ) at 120 °C. Working at 25 °C, its detection limit is 10 ppm. The sensor also exhibits good response repeatability, long-term stability (1 year at least), selectivity and batch-to-batch reproducibility. The strong restoring ability of the sensor can be ascribed to the easy desorption character of H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O from the surface of WO<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> and its dense-film structure, which makes the sensor afford many times of annealing, but do not produce cracks.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"128 ","pages":"Pages 386-394"},"PeriodicalIF":8.3000,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A stable room-temperature chemiresistive H2 gas sensor can restore itself to its initial state after being covered with H2O via refreshing its surface\",\"authors\":\"Meng Chen , Peisi Yin , Chengyi Gong , Hongrui Dou , Xiaoyu You , Xin Zhao , Xingyu Liu , Yongqi Yang , Xiangmin Du , Huaian Fu , Fei Song , Shanshan Yu , Kai Zhang , Zhipeng Tang , Jiacong Xu , Qiang Jing , Bo Liu\",\"doi\":\"10.1016/j.ijhydene.2025.04.012\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Until now, no one hydrogen sensing technology can meet all requirements of application. Hydrogen sensors working in extreme conditions are needed. Chemiresistive gas sensors own lots of merits but suffer from high relative humidity (RH). Furthermore, if its surface is covered with H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O, the sensor must be abandoned as it cannot work again. Here, a chemiresistive H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> gas sensor based on Pt-WO<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> composite dense film which can restore itself to its initial state after being covered with H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O has been fabricated. The restoring is realized by first blow-drying then annealing. The H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O-covering–restoring circulation can last 10 times at least. Towards 50 ppm H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>, its response value decreases only 25% from RH=40% to 90% (RH set and measured at 25 °C ) at 120 °C. Working at 25 °C, its detection limit is 10 ppm. The sensor also exhibits good response repeatability, long-term stability (1 year at least), selectivity and batch-to-batch reproducibility. The strong restoring ability of the sensor can be ascribed to the easy desorption character of H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O from the surface of WO<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> and its dense-film structure, which makes the sensor afford many times of annealing, but do not produce cracks.</div></div>\",\"PeriodicalId\":337,\"journal\":{\"name\":\"International Journal of Hydrogen Energy\",\"volume\":\"128 \",\"pages\":\"Pages 386-394\"},\"PeriodicalIF\":8.3000,\"publicationDate\":\"2025-04-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Hydrogen Energy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0360319925016209\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Hydrogen Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0360319925016209","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
A stable room-temperature chemiresistive H2 gas sensor can restore itself to its initial state after being covered with H2O via refreshing its surface
Until now, no one hydrogen sensing technology can meet all requirements of application. Hydrogen sensors working in extreme conditions are needed. Chemiresistive gas sensors own lots of merits but suffer from high relative humidity (RH). Furthermore, if its surface is covered with HO, the sensor must be abandoned as it cannot work again. Here, a chemiresistive H gas sensor based on Pt-WO composite dense film which can restore itself to its initial state after being covered with HO has been fabricated. The restoring is realized by first blow-drying then annealing. The HO-covering–restoring circulation can last 10 times at least. Towards 50 ppm H, its response value decreases only 25% from RH=40% to 90% (RH set and measured at 25 °C ) at 120 °C. Working at 25 °C, its detection limit is 10 ppm. The sensor also exhibits good response repeatability, long-term stability (1 year at least), selectivity and batch-to-batch reproducibility. The strong restoring ability of the sensor can be ascribed to the easy desorption character of HO from the surface of WO and its dense-film structure, which makes the sensor afford many times of annealing, but do not produce cracks.
期刊介绍:
The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc.
The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.