一种稳定的室温化学H2气体传感器,在被水覆盖后,可以通过刷新其表面来恢复其初始状态

IF 8.3 2区 工程技术 Q1 CHEMISTRY, PHYSICAL
Meng Chen , Peisi Yin , Chengyi Gong , Hongrui Dou , Xiaoyu You , Xin Zhao , Xingyu Liu , Yongqi Yang , Xiangmin Du , Huaian Fu , Fei Song , Shanshan Yu , Kai Zhang , Zhipeng Tang , Jiacong Xu , Qiang Jing , Bo Liu
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引用次数: 0

摘要

迄今为止,还没有一种氢传感技术能够满足所有应用要求。氢传感器需要在极端条件下工作。化学电阻式气体传感器有很多优点,但相对湿度(RH)较高。此外,如果其表面被 H2O 覆盖,传感器就必须放弃,因为它无法再次工作。在此,我们制作了一种基于 Pt-WO3 复合致密薄膜的化学电阻式 H2 气体传感器,它能在被 H2O 覆盖后恢复到初始状态。首先通过吹干,然后退火来实现恢复。H2O-覆盖-恢复循环至少可以持续 10 次。对于 50 ppm 的 H2,其响应值从相对湿度=40% 到 90%(相对湿度设定和测量温度为 25 °C)仅下降 25%,温度为 120 °C。在 25 °C 下工作时,其检测极限为 10 ppm。该传感器还具有良好的响应重复性、长期稳定性(至少 1 年)、选择性和批间重现性。传感器的强大恢复能力可归因于 WO3 表面对 H2O 的易解吸特性及其致密的薄膜结构,这使得传感器可承受多次退火,但不会产生裂缝。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A stable room-temperature chemiresistive H2 gas sensor can restore itself to its initial state after being covered with H2O via refreshing its surface

A stable room-temperature chemiresistive H2 gas sensor can restore itself to its initial state after being covered with H2O via refreshing its surface
Until now, no one hydrogen sensing technology can meet all requirements of application. Hydrogen sensors working in extreme conditions are needed. Chemiresistive gas sensors own lots of merits but suffer from high relative humidity (RH). Furthermore, if its surface is covered with H2O, the sensor must be abandoned as it cannot work again. Here, a chemiresistive H2 gas sensor based on Pt-WO3 composite dense film which can restore itself to its initial state after being covered with H2O has been fabricated. The restoring is realized by first blow-drying then annealing. The H2O-covering–restoring circulation can last 10 times at least. Towards 50 ppm H2, its response value decreases only 25% from RH=40% to 90% (RH set and measured at 25 °C ) at 120 °C. Working at 25 °C, its detection limit is 10 ppm. The sensor also exhibits good response repeatability, long-term stability (1 year at least), selectivity and batch-to-batch reproducibility. The strong restoring ability of the sensor can be ascribed to the easy desorption character of H2O from the surface of WO3 and its dense-film structure, which makes the sensor afford many times of annealing, but do not produce cracks.
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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