{"title":"热场和流场对 PVT 法生长氮化铝晶体应力分布的协同效应","authors":"Jiahao Chen, Jiamin Chen, Chuhao Yang, Yuheng Du, Hao Yang, Zeren Wang, Huangshu Zhang, Yuchun Xu, Zheng Li, Hailong Wei, Jiahua Zhang, Lun Dai, Jiejun Wu* and Tongjun Yu*, ","doi":"10.1021/acs.cgd.5c0017710.1021/acs.cgd.5c00177","DOIUrl":null,"url":null,"abstract":"<p >Excessive thermal stress is a serious issue that causes cracking in AlN single crystals during physical vapor transport (PVT) growth. Herein, with numerical simulations and PVT experiments, the thermal stress distribution was investigated to address the challenges in crystal growth. The free side and inclined surfaces of crystals were identified as favorable factors to reduce thermal stress. We proposed a strategy of synergistic control of the thermal and flow fields and carried out PVT growth under the conditions by combining the thermal adjustment components and the integrated flow field regulation components. A positive correlation was established between the simulated von Mises stress of the crystal and the experimentally measured crack density of the wafer. Effective synergistic control ensures a low and evenly distributed thermal stress in crystal growth, facilitating the production of high-quality, crack-free wafers.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":"25 8","pages":"2691–2699 2691–2699"},"PeriodicalIF":3.2000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic Effect of Thermal and Flow Fields on Stress Distribution in AlN Crystal Growth by PVT\",\"authors\":\"Jiahao Chen, Jiamin Chen, Chuhao Yang, Yuheng Du, Hao Yang, Zeren Wang, Huangshu Zhang, Yuchun Xu, Zheng Li, Hailong Wei, Jiahua Zhang, Lun Dai, Jiejun Wu* and Tongjun Yu*, \",\"doi\":\"10.1021/acs.cgd.5c0017710.1021/acs.cgd.5c00177\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Excessive thermal stress is a serious issue that causes cracking in AlN single crystals during physical vapor transport (PVT) growth. Herein, with numerical simulations and PVT experiments, the thermal stress distribution was investigated to address the challenges in crystal growth. The free side and inclined surfaces of crystals were identified as favorable factors to reduce thermal stress. We proposed a strategy of synergistic control of the thermal and flow fields and carried out PVT growth under the conditions by combining the thermal adjustment components and the integrated flow field regulation components. A positive correlation was established between the simulated von Mises stress of the crystal and the experimentally measured crack density of the wafer. Effective synergistic control ensures a low and evenly distributed thermal stress in crystal growth, facilitating the production of high-quality, crack-free wafers.</p>\",\"PeriodicalId\":34,\"journal\":{\"name\":\"Crystal Growth & Design\",\"volume\":\"25 8\",\"pages\":\"2691–2699 2691–2699\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-03-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Growth & Design\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.cgd.5c00177\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Growth & Design","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.5c00177","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synergistic Effect of Thermal and Flow Fields on Stress Distribution in AlN Crystal Growth by PVT
Excessive thermal stress is a serious issue that causes cracking in AlN single crystals during physical vapor transport (PVT) growth. Herein, with numerical simulations and PVT experiments, the thermal stress distribution was investigated to address the challenges in crystal growth. The free side and inclined surfaces of crystals were identified as favorable factors to reduce thermal stress. We proposed a strategy of synergistic control of the thermal and flow fields and carried out PVT growth under the conditions by combining the thermal adjustment components and the integrated flow field regulation components. A positive correlation was established between the simulated von Mises stress of the crystal and the experimentally measured crack density of the wafer. Effective synergistic control ensures a low and evenly distributed thermal stress in crystal growth, facilitating the production of high-quality, crack-free wafers.
期刊介绍:
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.