具有发散光催化性能的亚胺键共价有机笼的结构异构体

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-15 DOI:10.1039/d5cc00380f

Jiajia Li, Yanping Yang, Shan Shiang Shiang Hii, Xinyuan Zhu, Youfu Wang

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引用次数: 0

摘要

本文首次研究了共价有机笼（COCs）的键取向对其整体性能的影响。合成了以三苯胺为供体，蒽为受体的亚胺连接的异构体COCs TNCA和TCNA，它们的光电性能存在显著差异，从而影响了它们的光催化性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Structural isomers of imine-linked covalent organic cages with divergent photocatalytic properties

The impact of linkage orientation as minor structural changes on the overall properties of covalent organic cages (COCs) has been investigated for the first time. Isomeric imine-linked donor–acceptor COCs, featuring triphenylamine as the donor and anthracene as the acceptor, TNCA and TCNA, were synthesized and exhibited significant differences in their optoelectronic properties, which in turn affect their photocatalytic performance.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.