具有发散光催化性能的亚胺键共价有机笼的结构异构体

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-16 DOI:10.1039/d5cc00380f

Jiajia Li , Yanping Yang , Shan Shiang Hii , Xinyuan Zhu , Youfu Wang

{"title":"具有发散光催化性能的亚胺键共价有机笼的结构异构体","authors":"Jiajia Li , Yanping Yang , Shan Shiang Hii , Xinyuan Zhu , Youfu Wang","doi":"10.1039/d5cc00380f","DOIUrl":null,"url":null,"abstract":"<div><div>The impact of linkage orientation as structural isomers on the properties of covalent organic cages (COCs) has been investigated. Isomeric imine-linked COCs, featuring triphenylamine as the donor and anthracene as the acceptor, TNCA and TCNA, were synthesized and exhibited significant differences in their optoelectronic properties, which in turn affect their photocatalytic performance.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 40","pages":"Pages 7281-7284"},"PeriodicalIF":4.2000,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural isomers of imine-linked covalent organic cages with divergent photocatalytic properties†\",\"authors\":\"Jiajia Li , Yanping Yang , Shan Shiang Hii , Xinyuan Zhu , Youfu Wang\",\"doi\":\"10.1039/d5cc00380f\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The impact of linkage orientation as structural isomers on the properties of covalent organic cages (COCs) has been investigated. Isomeric imine-linked COCs, featuring triphenylamine as the donor and anthracene as the acceptor, TNCA and TCNA, were synthesized and exhibited significant differences in their optoelectronic properties, which in turn affect their photocatalytic performance.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 40\",\"pages\":\"Pages 7281-7284\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-04-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S135973452500789X\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S135973452500789X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

本文首次研究了共价有机笼（COCs）的键取向对其整体性能的影响。合成了以三苯胺为供体，蒽为受体的亚胺连接的异构体COCs TNCA和TCNA，它们的光电性能存在显著差异，从而影响了它们的光催化性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Structural isomers of imine-linked covalent organic cages with divergent photocatalytic properties†

查看原文本刊更多论文

Structural isomers of imine-linked covalent organic cages with divergent photocatalytic properties†

The impact of linkage orientation as structural isomers on the properties of covalent organic cages (COCs) has been investigated. Isomeric imine-linked COCs, featuring triphenylamine as the donor and anthracene as the acceptor, TNCA and TCNA, were synthesized and exhibited significant differences in their optoelectronic properties, which in turn affect their photocatalytic performance.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.