Pr3+离子掺杂B2O3-P2O5-SiO2三层光子玻璃的光谱分析

IF 3.2 3区材料科学 Q1 MATERIALS SCIENCE, CERAMICS

Journal of Non-crystalline Solids Pub Date : 2025-04-12 DOI:10.1016/j.jnoncrysol.2025.123538

M N Vishnu Narayanan Namboothiri , S. Arul raja sekaran , A. Indhrapriyadarshini , K.A. Naseer , K. Marimuthu

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引用次数: 0

摘要

通过传统的熔体淬火方法，改变改性剂镉和铋氧化物的含量，研制出了一系列新的三价掺杂镨的三元玻璃。BPSXBiPr 玻璃的吸收光谱曲线几乎横跨整个电磁波谱。命名玻璃的 Judd-Ofelt 强度参数呈现出 Ω6>Ω2>Ω4 的趋势。在制备的五种玻璃中，BPS0BiPr 玻璃的发光光谱强度更大，跃迁 3P0→3H4（蓝色）和 3P0→3H6（红色）具有高敏感性。通过 CIE 颜色色度坐标，确认了样品的橙红色发射。本系列玻璃的σPE 值呈现出 BPS0BiPr>；BPS10BiPr>；BPS2.5BiPr>；BPS7.5BiPr>；BPS5BiPr 的趋势，这证明了 BPS0BiPr 玻璃具有更高的发光能力。当前系列中的所有玻璃都具有 60% 的量子效率，非常适合光子应用。

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Spectroscopic analysis of Pr3+ ions doped Barium incorporated B2O3-P2O5-SiO2 tri -former glasses for photonic applications

A new series of trivalent praseodymium-embedded tri-former glasses were developed by varying content among the modifier oxides of Cd and Bi through conventional melt quenching method. The absorption spectral profile of the BPSXBiPr glass spans almost the entire part of the electromagnetic spectrum. The Judd-Ofelt intensity parameters of the titled glass exhibit the trend as Ω₆>Ω₂>Ω_4. Of the five prepared glasses, BPS0BiPr glass shows greater intensity in the luminescence spectra and the transitions ³P₀→³H₄ (blue) and ³P₀→³H₆ (Red) are hypersensitive in nature. The reddish-orange emission of the samples were confirmed through the CIE color chromaticity coordinates. The

σ_{P}^{E}

value for the current set of glasses exhibits the trend as BPS0BiPr> BPS10BiPr> BPS2.5BiPr> BPS7.5BiPr> BPS5BiPr, which proves the higher lasing ability of the BPS0BiPr glass. All the glasses in the current series exhibits >60 % quantum efficacy and are well apt for photonic applications.

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来源期刊

Journal of Non-crystalline Solids 工程技术-材料科学：硅酸盐

CiteScore

6.50

自引率

11.40%

发文量

576

审稿时长

35 days

期刊介绍： The Journal of Non-Crystalline Solids publishes review articles, research papers, and Letters to the Editor on amorphous and glassy materials, including inorganic, organic, polymeric, hybrid and metallic systems. Papers on partially glassy materials, such as glass-ceramics and glass-matrix composites, and papers involving the liquid state are also included in so far as the properties of the liquid are relevant for the formation of the solid. In all cases the papers must demonstrate both novelty and importance to the field, by way of significant advances in understanding or application of non-crystalline solids; in the case of Letters, a compelling case must also be made for expedited handling.