J.M. Angeles , A. Parrales , Sung-Hyuk Cha , D.E. Millán-Ocampo , R. López-Sesenes , J.A. Hernández
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引用次数: 0
摘要
建立并评价了不同配置的人工神经网络(ANN)模型,利用电化学噪声预测5-氨基四唑在盐水条件下(0.1 M和0.05 M NaCl)对AA6065-AZ31合金的缓蚀效果。训练数据集包括302,400个浸泡测试的测量值,抑制剂浓度为2 mM, 4 mM, 6 mM, 8 mM和10 mM。输入变量为时间、抑制剂浓度和电解质浓度,输出变量为电化学电阻。在隐层使用TanSig、LogSig、ElliotSig、Radbas、Softmax、dSiLU、Sqsinc、ReLU和SoftPlus等传递函数进行综合分析,这些传递函数均使用Levenberg-Marquardt算法进行训练。其中,采用9神经元隐层结构和dSiLU作为传递函数的模型性能最好。最佳模型的决定系数(R²)为0.9983,表明模拟数据与实验数据具有良好的相关性。最佳人工神经网络模型预测的缓蚀效率误差小于4 %,证实了人工神经网络在准确模拟电化学噪声方面的潜力。
Modeling and prediction of corrosion inhibition efficiency of 5-Aminotetrazole on AA6065-AZ31 alloy using electrochemical noise and artificial neural networks with different transfer functions
Different configurations of artificial neural network (ANN) models were developed and evaluated to predict the corrosion inhibition efficiency of 5-Aminotetrazole on AA6065-AZ31 alloy exposed to saline conditions (0.1 M and 0.05 M NaCl) using electrochemical noise. The training dataset consisted of 302,400 measurements from immersion tests with inhibitor concentrations of 2 mM, 4 mM, 6 mM, 8 mM, and 10 mM. The variables time, inhibitor concentration, and electrolyte concentration were used as input variables, while the output variable was electrochemical resistance. A comprehensive analysis was performed using different transfer functions in the hidden layer, including TanSig, LogSig, ElliotSig, Radbas, Softmax, dSiLU, Sqsinc, ReLU, and SoftPlus, all trained with the Levenberg-Marquardt algorithm. Among these configurations, the model employing a 9-neuron hidden layer architecture and dSiLU as transfer function achieved the best performance. The determination coefficient (R²) of 0.9983 obtained by the best model demonstrated an excellent correlation between simulated and experimental data. The corrosion inhibition efficiency predicted by the best ANN model obtained less than 4 % error, confirming the ANN's potential for accurately modeling electrochemical noise.
期刊介绍:
International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry