用P-GeH-P配体负载的钴螯合物催化醇无受体脱氢

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-11 DOI:10.1039/d5cc01050k

Yu-Chao Liu, Dun-Xu Cao, Qi-Yang Ban, Wen-Jie Ma, Bin Xiao

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引用次数: 0

摘要

我们报道了一种新的P-GeH-P钳形配体及其钴(I)配合物，它催化醇的无受体脱氢。与硅基类似物相比，具有活性Ge-H键的Ge-Co配合物表现出独特的催化性能。此外，该配合物可以一锅合成2-喹诺酮类衍生物，突出了其在有机合成中的潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Catalytic acceptorless dehydrogenation of alcohols using cobalt(I) pincer complexes supported by a P–GeH–P ligand

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Catalytic acceptorless dehydrogenation of alcohols using cobalt(I) pincer complexes supported by a P–GeH–P ligand

We report a novel P–GeH–P pincer ligand and its cobalt(I) complex, which catalyzes the acceptorless dehydrogenation of alcohols. The Ge–Co complex, featuring a reactive Ge–H bond, shows distinct catalytic properties compared to silicon-based analogues. Moreover, the complex enables the one-pot synthesis of 2-quinolone derivatives, highlighting its potential in organic synthesis.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.