硝酸铀酰与某些酰胺配体的配位化合物

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2025-04-11 DOI:10.1134/S1070328424600931

M. S. Polukhin, E. V. Savinkina, I. A. Karavaev, P. V. Akulinin, G. A. Buzanov, A. S. Kubasov, M. S. Grigor’ev, S. B. Strashnova

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引用次数: 0

摘要

通过 UO2(NO3)2 与酰胺 L（L = 乙酰胺、N,N-二甲基乙酰胺、丙酰胺、戊酰胺、苯甲酰胺、N-甲基脲）在水中的反应，制备了六种配位化合物 [UO2(L)2(NO3)2]。通过元素分析、红外光谱以及粉末和单晶 X 射线衍射，确定了产物的组成和结构。量子化学计算证实了所获化合物的分子结构和吸收带的分配。

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Coordination Compounds of Uranyl Nitrate with Some Amide Ligands

Six coordination compounds [UO₂(L)₂(NO₃)₂] were prepared by the reaction of UO₂(NO₃)₂ with amide L (L = acetamide, N,N-dimethylacetamide, propanamide, valeramide, benzamide, N-methylurea) in water. The composition and the structure of the products were established by elemental analysis, IR spectroscopy, and powder and single-crystal X-ray diffraction. The molecular structure and the assignment of absorption bands for the obtained compounds were confirmed by quantum chemical calculations.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.