制革废水热废蚊香吸附剂对三价铬的吸附效果

IF 6.2
Md. Abul Hashem , Jannatul Nime Tabassum , Md. Shahriar Shahadat , Modinatul Maoya , Al Mizan , Md. Mukimujjaman Miem , Md. Enamul Hasan Zahin
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引用次数: 0

摘要

制革废水中含有三价铬,Cr(III)是一个重大的环境问题。因此,研究了高可用性和低成本吸附剂的性能评价。利用替代废物(吸附剂)的可用性和去除效率仍有很大的余地。研究了热废蚊香吸附剂(TWMCA)对制革废水中Cr(III)的吸附性能。采用扫描电镜(SEM)、傅里叶变换红外光谱(FTIR)、能量色散x射线(EDX)和零电荷pH点(pHpzc)对TWMCA进行了表征。在最佳条件下(1.0 g/50 mL废水,搅拌时间30 min,沉淀时间6 h,温度40℃,溶液相对pH为6.3),Cr的吸附率为99.97%,生化需氧量、氯化物、化学需氧量、总溶解固溶体和电导率分别降低81.17%、68.85%、50.00%、53.77%和45.43%。Freundlich等温线(R2=0.9893)和拟二级动力学模型(R2=0.9999)很好地解释了TWMCA对Cr的吸附。利用pHpzc描述了合适的吸附机理。解吸研究表明TWMCA具有可重复利用性。因此,利用TWMCA吸附制革废水中的铬是一种有效的环境保护技术。利用另一种废物的可持续和高效吸附技术推动工业向符合可持续发展目标的环保废物管理实践发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Trivalent chromium adsorption efficiency on thermic waste mosquito coil adsorbent from tannery wastewater

Trivalent chromium adsorption efficiency on thermic waste mosquito coil adsorbent from tannery wastewater
Emitted tannery wastewater containing trivalent chromium, Cr(III) is a significant environmental issue. Thus, performance evaluation of highly available and low-cost adsorbents has been investigated. There is much scope remaining to utilize alternative waste (adsorbent) for their availability and removal efficiency. This study is focused on the Cr(III) adsorption on the thermic waste mosquito coil adsorbent (TWMCA) from tannery wastewater. The TWMCA was characterized by Scanning Electronic Microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, Energy dispersive X-ray (EDX), and pH point of zero charge (pHpzc). The Cr adsorption was achieved at 99.97 % with optimum condition (dose 1.0 g/50 mL wastewater, stirring time 30 min, settling time 6 h, and at 40 °C temperature with a relative solution pH 6.3) which showed a reduction of biochemical oxygen demand, chloride, chemical oxygen demand, total dissolved solids, and electrical conductivity by 81.17 %, 68.85 %, 50.00 %, 53.77 %, and 45.43 %, respectively. The Freundlich isotherm (R2=0.9893) and pseudo-second-order kinetic model (R2=0.9999) well-explained the Cr adsorption on TWMCA. The well-fitted adsorption mechanism was described with the help of pHpzc. The desorption study suggests the reusability of TWMCA. Hence, using TWMCA for Cr adsorption from tannery wastewater is an effective technique to save the environment. A sustainable and efficient adsorption technique utilizing another waste drives industries toward environmentally conscious waste management practices that satisfy the Sustainable Development Goal.
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