使用新型酸性磁性氧化石墨烯催化剂一锅绿色合成吡唑衍生物

IF 4.4 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Communications Pub Date : 2025-04-04 DOI:10.1016/j.inoche.2025.114419

Sarieh Momeni , Ramin Ghorbani-Vaghei

{"title":"使用新型酸性磁性氧化石墨烯催化剂一锅绿色合成吡唑衍生物","authors":"Sarieh Momeni , Ramin Ghorbani-Vaghei","doi":"10.1016/j.inoche.2025.114419","DOIUrl":null,"url":null,"abstract":"<div><div>This research focuses on developing a novel acidic nano-catalyst by sulfonating magnetic graphene oxide coated with 5-amino-1<em>H</em>-tetrazole (GO/Fe<sub>3</sub>O<sub>4</sub>@CPTMS@5-amino-1<em>H</em>-tetrazole @SO<sub>3</sub>H). Various techniques, such as FTIR, EDX, mapping, FESEM, XRD and VSM analyses, were employed to investigate and confirm the properties of the synthesized nanocomposite. It demonstrated exceptional performance in the green synthesis of 4,4′-(arylmethylene)<em>bis</em>-(3-methyl-1-phenyl-1<em>H</em>-pyrazol-5-ol) derivatives. Key benefits of this process include its environmentally friendly catalyst, solvent-free conditions, straightforward purification, cost-efficiency, high product yield, short reaction time, and low reaction temperature. Furthermore, the magnetic catalyst exhibited excellent stability and reusability over four consecutive cycles, aligning with green chemistry principles.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114419"},"PeriodicalIF":4.4000,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-pot green synthesis of pyrazole derivatives using a new acidic magnetic graphene oxide catalyst\",\"authors\":\"Sarieh Momeni , Ramin Ghorbani-Vaghei\",\"doi\":\"10.1016/j.inoche.2025.114419\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This research focuses on developing a novel acidic nano-catalyst by sulfonating magnetic graphene oxide coated with 5-amino-1<em>H</em>-tetrazole (GO/Fe<sub>3</sub>O<sub>4</sub>@CPTMS@5-amino-1<em>H</em>-tetrazole @SO<sub>3</sub>H). Various techniques, such as FTIR, EDX, mapping, FESEM, XRD and VSM analyses, were employed to investigate and confirm the properties of the synthesized nanocomposite. It demonstrated exceptional performance in the green synthesis of 4,4′-(arylmethylene)<em>bis</em>-(3-methyl-1-phenyl-1<em>H</em>-pyrazol-5-ol) derivatives. Key benefits of this process include its environmentally friendly catalyst, solvent-free conditions, straightforward purification, cost-efficiency, high product yield, short reaction time, and low reaction temperature. Furthermore, the magnetic catalyst exhibited excellent stability and reusability over four consecutive cycles, aligning with green chemistry principles.</div></div>\",\"PeriodicalId\":13609,\"journal\":{\"name\":\"Inorganic Chemistry Communications\",\"volume\":\"178 \",\"pages\":\"Article 114419\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2025-04-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387700325005350\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387700325005350","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

本研究的重点是通过将磁性氧化石墨烯涂覆5-氨基- 1h -四唑（GO/Fe3O4@CPTMS@5-氨基- 1h -四唑@SO3H）磺化，开发一种新型酸性纳米催化剂。利用FTIR、EDX、图谱分析、FESEM、XRD和VSM等技术对合成的纳米复合材料进行了表征和表征。在绿色合成4,4′-（芳基亚甲基）双-（3-甲基-1-苯基- 1h -吡唑-5-醇）衍生物中表现出优异的性能。该工艺的主要优点包括其环保催化剂，无溶剂条件，简单的净化，成本效益，高产品收率，反应时间短，反应温度低。此外，磁性催化剂在连续四个循环中表现出优异的稳定性和可重复使用性，符合绿色化学原则。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

One-pot green synthesis of pyrazole derivatives using a new acidic magnetic graphene oxide catalyst

查看原文本刊更多论文

One-pot green synthesis of pyrazole derivatives using a new acidic magnetic graphene oxide catalyst

This research focuses on developing a novel acidic nano-catalyst by sulfonating magnetic graphene oxide coated with 5-amino-1H-tetrazole (GO/Fe₃O₄@CPTMS@5-amino-1H-tetrazole @SO₃H). Various techniques, such as FTIR, EDX, mapping, FESEM, XRD and VSM analyses, were employed to investigate and confirm the properties of the synthesized nanocomposite. It demonstrated exceptional performance in the green synthesis of 4,4′-(arylmethylene)bis-(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives. Key benefits of this process include its environmentally friendly catalyst, solvent-free conditions, straightforward purification, cost-efficiency, high product yield, short reaction time, and low reaction temperature. Furthermore, the magnetic catalyst exhibited excellent stability and reusability over four consecutive cycles, aligning with green chemistry principles.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Inorganic Chemistry Communications 化学-无机化学与核化学

CiteScore

5.50

自引率

7.90%

发文量

1013

审稿时长

53 days

期刊介绍： Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.