{"title":"fexoy修饰的生物质衍生碳:一种轻质电磁波吸收剂和热导体","authors":"Ting Zhou , Jing Xu , Hao Zhao , Chunni Zhang , Yifeng Wei , Xiangyu Yin , Zhen Lu , Linxi Hou , Jingyu Cai","doi":"10.1016/j.colsurfa.2025.136886","DOIUrl":null,"url":null,"abstract":"<div><div>The natural porosity architectures, polar functional groups, low density, and biocompatibility of biomass carbon materials make them highly promising for the development of lightweight electromagnetic microwave absorbers. Sugarcane bagasse served as the raw material for this investigation, and sugarcane bagasse-derived carbon/Fe<sub>x</sub>O<sub>y</sub> was prepared using the in-situ growth method and temperature field-directed casting. By adjusting the content of ferrite hollow spheres, magnetic conduction losses and heterogeneous interfacial polarization losses are improved. Controlling the electrical conductivity losses and multiple scattering structures of biomass-derived carbon at different annealing temperatures, impedance matching is achieved through the synergistic operation of various loss mechanisms. [email protected]–750 exhibited a minimum reflection loss (RL<sub>min</sub>) of −46.6 dB at a filler content of only 5 wt% and a thickness of 1.9 mm and obtained a maximum effective absorption bandwidth (EAB<sub>max</sub>) of 5.52 GHz at the same thickness. The ice template directional casting formed an orderly thermal conduction path, providing channels for phonon and electron transport, which is beneficial for the efficient heat dissipation of the microwave absorber. This finding thus offers a promising technique for creating ultra-lightweight microwave absorbers that facilitate heat dissipation.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"717 ","pages":"Article 136886"},"PeriodicalIF":5.4000,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"FexOy-decorated biomass-derived carbon: A lightweight electromagnetic wave absorber and thermal conductor\",\"authors\":\"Ting Zhou , Jing Xu , Hao Zhao , Chunni Zhang , Yifeng Wei , Xiangyu Yin , Zhen Lu , Linxi Hou , Jingyu Cai\",\"doi\":\"10.1016/j.colsurfa.2025.136886\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The natural porosity architectures, polar functional groups, low density, and biocompatibility of biomass carbon materials make them highly promising for the development of lightweight electromagnetic microwave absorbers. Sugarcane bagasse served as the raw material for this investigation, and sugarcane bagasse-derived carbon/Fe<sub>x</sub>O<sub>y</sub> was prepared using the in-situ growth method and temperature field-directed casting. By adjusting the content of ferrite hollow spheres, magnetic conduction losses and heterogeneous interfacial polarization losses are improved. Controlling the electrical conductivity losses and multiple scattering structures of biomass-derived carbon at different annealing temperatures, impedance matching is achieved through the synergistic operation of various loss mechanisms. [email protected]–750 exhibited a minimum reflection loss (RL<sub>min</sub>) of −46.6 dB at a filler content of only 5 wt% and a thickness of 1.9 mm and obtained a maximum effective absorption bandwidth (EAB<sub>max</sub>) of 5.52 GHz at the same thickness. The ice template directional casting formed an orderly thermal conduction path, providing channels for phonon and electron transport, which is beneficial for the efficient heat dissipation of the microwave absorber. This finding thus offers a promising technique for creating ultra-lightweight microwave absorbers that facilitate heat dissipation.</div></div>\",\"PeriodicalId\":278,\"journal\":{\"name\":\"Colloids and Surfaces A: Physicochemical and Engineering Aspects\",\"volume\":\"717 \",\"pages\":\"Article 136886\"},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2025-04-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloids and Surfaces A: Physicochemical and Engineering Aspects\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927775725007897\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927775725007897","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
FexOy-decorated biomass-derived carbon: A lightweight electromagnetic wave absorber and thermal conductor
The natural porosity architectures, polar functional groups, low density, and biocompatibility of biomass carbon materials make them highly promising for the development of lightweight electromagnetic microwave absorbers. Sugarcane bagasse served as the raw material for this investigation, and sugarcane bagasse-derived carbon/FexOy was prepared using the in-situ growth method and temperature field-directed casting. By adjusting the content of ferrite hollow spheres, magnetic conduction losses and heterogeneous interfacial polarization losses are improved. Controlling the electrical conductivity losses and multiple scattering structures of biomass-derived carbon at different annealing temperatures, impedance matching is achieved through the synergistic operation of various loss mechanisms. [email protected]–750 exhibited a minimum reflection loss (RLmin) of −46.6 dB at a filler content of only 5 wt% and a thickness of 1.9 mm and obtained a maximum effective absorption bandwidth (EABmax) of 5.52 GHz at the same thickness. The ice template directional casting formed an orderly thermal conduction path, providing channels for phonon and electron transport, which is beneficial for the efficient heat dissipation of the microwave absorber. This finding thus offers a promising technique for creating ultra-lightweight microwave absorbers that facilitate heat dissipation.
期刊介绍:
Colloids and Surfaces A: Physicochemical and Engineering Aspects is an international journal devoted to the science underlying applications of colloids and interfacial phenomena.
The journal aims at publishing high quality research papers featuring new materials or new insights into the role of colloid and interface science in (for example) food, energy, minerals processing, pharmaceuticals or the environment.