Yuexin Lin, Zhichao Lin, Shili Lv, Yuan Shui, Wenjing Zhu, Zuhong Zhang, Wenhan Yang, Jinbo Zhao, Hao Gu, Junmin Xia, Danning Wang, Fenqi Du, Annan Zhu, Jin Liu, Hairui Cai, Bin Wang, Nan Zhang, Haibin Wang, Xiaolong Liu, Tao Liu, Chuncai Kong, Di Zhou, Shi Chen, Zhimao Yang, Tao Li, Wei Ma, Guojia Fang, Luis Echegoyen, Guichuan Xing, Shengchun Yang, Tao Yang, Wenting Cai, Meng Li, Wei Huang, Chao Liang
{"title":"用于高效稳定的过氧化物太阳能电池的 Nd@C82 聚合物界面","authors":"Yuexin Lin, Zhichao Lin, Shili Lv, Yuan Shui, Wenjing Zhu, Zuhong Zhang, Wenhan Yang, Jinbo Zhao, Hao Gu, Junmin Xia, Danning Wang, Fenqi Du, Annan Zhu, Jin Liu, Hairui Cai, Bin Wang, Nan Zhang, Haibin Wang, Xiaolong Liu, Tao Liu, Chuncai Kong, Di Zhou, Shi Chen, Zhimao Yang, Tao Li, Wei Ma, Guojia Fang, Luis Echegoyen, Guichuan Xing, Shengchun Yang, Tao Yang, Wenting Cai, Meng Li, Wei Huang, Chao Liang","doi":"10.1038/s41586-025-08961-9","DOIUrl":null,"url":null,"abstract":"<p>A critical challenge in the commercialization of perovskite solar cells (PSCs) is the simultaneous attainment of high power conversion efficiency (PCE) and high stability. Employing polymers interfaces in PSCs can enhance durability by blocking water and oxygen, and by suppressing ions interdiffusion, but their electronic shielding poses a challenge for efficient and stable PSCs<sup>1–3</sup>. In this study, we report a magnetic endohedral metallofullerene Nd@C<sub>82</sub>-polymer coupling layer, which features ultra-fast electron extraction and in-situ encapsulation, thereby promoting homogeneous electron extraction and suppressing ions interdiffusion. The Nd@C<sub>82</sub>-polymer coupling layer in PSCs exhibited PCE of 26.78% (certified 26.29%) and 23.08% with an aperture area of 0.08 square centimetres and 16 square centimetres (modules), respectively. The unencapsulated devices retained ~82% of the initial PCE after 2,500 hours of continuous 1-sun maximum power point operation at 65 °C.</p>","PeriodicalId":18787,"journal":{"name":"Nature","volume":"1 1","pages":""},"PeriodicalIF":50.5000,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Nd@C82-polymer interface for efficient and stable perovskite solar cells\",\"authors\":\"Yuexin Lin, Zhichao Lin, Shili Lv, Yuan Shui, Wenjing Zhu, Zuhong Zhang, Wenhan Yang, Jinbo Zhao, Hao Gu, Junmin Xia, Danning Wang, Fenqi Du, Annan Zhu, Jin Liu, Hairui Cai, Bin Wang, Nan Zhang, Haibin Wang, Xiaolong Liu, Tao Liu, Chuncai Kong, Di Zhou, Shi Chen, Zhimao Yang, Tao Li, Wei Ma, Guojia Fang, Luis Echegoyen, Guichuan Xing, Shengchun Yang, Tao Yang, Wenting Cai, Meng Li, Wei Huang, Chao Liang\",\"doi\":\"10.1038/s41586-025-08961-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A critical challenge in the commercialization of perovskite solar cells (PSCs) is the simultaneous attainment of high power conversion efficiency (PCE) and high stability. Employing polymers interfaces in PSCs can enhance durability by blocking water and oxygen, and by suppressing ions interdiffusion, but their electronic shielding poses a challenge for efficient and stable PSCs<sup>1–3</sup>. In this study, we report a magnetic endohedral metallofullerene Nd@C<sub>82</sub>-polymer coupling layer, which features ultra-fast electron extraction and in-situ encapsulation, thereby promoting homogeneous electron extraction and suppressing ions interdiffusion. The Nd@C<sub>82</sub>-polymer coupling layer in PSCs exhibited PCE of 26.78% (certified 26.29%) and 23.08% with an aperture area of 0.08 square centimetres and 16 square centimetres (modules), respectively. The unencapsulated devices retained ~82% of the initial PCE after 2,500 hours of continuous 1-sun maximum power point operation at 65 °C.</p>\",\"PeriodicalId\":18787,\"journal\":{\"name\":\"Nature\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":50.5000,\"publicationDate\":\"2025-04-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature\",\"FirstCategoryId\":\"103\",\"ListUrlMain\":\"https://doi.org/10.1038/s41586-025-08961-9\",\"RegionNum\":1,\"RegionCategory\":\"综合性期刊\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature","FirstCategoryId":"103","ListUrlMain":"https://doi.org/10.1038/s41586-025-08961-9","RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
A Nd@C82-polymer interface for efficient and stable perovskite solar cells
A critical challenge in the commercialization of perovskite solar cells (PSCs) is the simultaneous attainment of high power conversion efficiency (PCE) and high stability. Employing polymers interfaces in PSCs can enhance durability by blocking water and oxygen, and by suppressing ions interdiffusion, but their electronic shielding poses a challenge for efficient and stable PSCs1–3. In this study, we report a magnetic endohedral metallofullerene Nd@C82-polymer coupling layer, which features ultra-fast electron extraction and in-situ encapsulation, thereby promoting homogeneous electron extraction and suppressing ions interdiffusion. The Nd@C82-polymer coupling layer in PSCs exhibited PCE of 26.78% (certified 26.29%) and 23.08% with an aperture area of 0.08 square centimetres and 16 square centimetres (modules), respectively. The unencapsulated devices retained ~82% of the initial PCE after 2,500 hours of continuous 1-sun maximum power point operation at 65 °C.
期刊介绍：
Nature is a prestigious international journal that publishes peer-reviewed research in various scientific and technological fields. The selection of articles is based on criteria such as originality, importance, interdisciplinary relevance, timeliness, accessibility, elegance, and surprising conclusions. In addition to showcasing significant scientific advances, Nature delivers rapid, authoritative, insightful news, and interpretation of current and upcoming trends impacting science, scientists, and the broader public. The journal serves a dual purpose: firstly, to promptly share noteworthy scientific advances and foster discussions among scientists, and secondly, to ensure the swift dissemination of scientific results globally, emphasizing their significance for knowledge, culture, and daily life.
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