Violeta Carolina Wills and Julie Katerine Rodriguez
{"title":"废物增值:利用沼气植物残留物生产燃料","authors":"Violeta Carolina Wills and Julie Katerine Rodriguez","doi":"10.1039/D5SE00227C","DOIUrl":null,"url":null,"abstract":"<p >Hydrothermal liquefaction (HTL) represents a transformative technology in the quest for net-zero emissions and the establishment of a circular bio-economy. This study investigates an innovative approach to waste valorization by converting digestate fibers from biogas plants into renewable fuels using HTL and catalytic upgrading. The HTL process yielded biocrude with 37 wt% and achieved 70 wt% energy recovery from the dry ash-free biomass, demonstrating HTL's efficiency in capturing energy from biowaste. Catalytic upgrading of the biocrude, including hydrotreatment (HDT) and other refining steps, reduced the oxygen content by 98% to 0.16 wt%, and boosted energy density to 45.8 MJ kg<small><sup>−1</sup></small>, aligning with ASTM D975 standards for diesel and ISO 8217 for marine fuels. The feasibility of co-processing biocrude with conventional heavy oil was also explored. Blending trials with 10 wt% partially upgraded biocrude showed stable performance over 200 hours in an HDT reactor, indicating compatibility and a viable pathway for integrating renewable biocrude with traditional heavy distillates, enhancing fuel production sustainability. This approach provides a promising route to incorporate renewable sources into conventional fuel production, supporting sustainable fuel technologies.</p>","PeriodicalId":104,"journal":{"name":"Sustainable Energy & Fuels","volume":" 8","pages":" 2045-2062"},"PeriodicalIF":5.0000,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Waste valorization: harnessing biogas plant residues for fuel production\",\"authors\":\"Violeta Carolina Wills and Julie Katerine Rodriguez\",\"doi\":\"10.1039/D5SE00227C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Hydrothermal liquefaction (HTL) represents a transformative technology in the quest for net-zero emissions and the establishment of a circular bio-economy. This study investigates an innovative approach to waste valorization by converting digestate fibers from biogas plants into renewable fuels using HTL and catalytic upgrading. The HTL process yielded biocrude with 37 wt% and achieved 70 wt% energy recovery from the dry ash-free biomass, demonstrating HTL's efficiency in capturing energy from biowaste. Catalytic upgrading of the biocrude, including hydrotreatment (HDT) and other refining steps, reduced the oxygen content by 98% to 0.16 wt%, and boosted energy density to 45.8 MJ kg<small><sup>−1</sup></small>, aligning with ASTM D975 standards for diesel and ISO 8217 for marine fuels. The feasibility of co-processing biocrude with conventional heavy oil was also explored. Blending trials with 10 wt% partially upgraded biocrude showed stable performance over 200 hours in an HDT reactor, indicating compatibility and a viable pathway for integrating renewable biocrude with traditional heavy distillates, enhancing fuel production sustainability. This approach provides a promising route to incorporate renewable sources into conventional fuel production, supporting sustainable fuel technologies.</p>\",\"PeriodicalId\":104,\"journal\":{\"name\":\"Sustainable Energy & Fuels\",\"volume\":\" 8\",\"pages\":\" 2045-2062\"},\"PeriodicalIF\":5.0000,\"publicationDate\":\"2025-03-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sustainable Energy & Fuels\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/se/d5se00227c\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Energy & Fuels","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/se/d5se00227c","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
水热液化(HTL)是一项追求净零排放和建立循环生物经济的变革性技术。本研究探讨了一种利用HTL和催化升级将沼气厂消化纤维转化为可再生燃料的废物增值创新方法。HTL工艺产生的生物原油重量为37%,从干燥的无灰生物质中实现了70%的能量回收,证明了HTL在从生物废物中捕获能量方面的效率。生物原油的催化升级,包括加氢处理(HDT)和其他精炼步骤,将氧含量降低98%至0.16 wt%,并将能量密度提高至45.8 MJ kg - 1,符合柴油的ASTM D975标准和船用燃料的ISO 8217标准。探讨了生物原油与常规重油协同加工的可行性。混合试验显示,在HDT反应器中,10%的部分升级生物原油在200小时内表现稳定,表明了可再生生物原油与传统重质馏出物的兼容性和可行途径,提高了燃料生产的可持续性。这种方法为将可再生能源纳入传统燃料生产提供了一条有希望的途径,支持可持续燃料技术。
Waste valorization: harnessing biogas plant residues for fuel production
Hydrothermal liquefaction (HTL) represents a transformative technology in the quest for net-zero emissions and the establishment of a circular bio-economy. This study investigates an innovative approach to waste valorization by converting digestate fibers from biogas plants into renewable fuels using HTL and catalytic upgrading. The HTL process yielded biocrude with 37 wt% and achieved 70 wt% energy recovery from the dry ash-free biomass, demonstrating HTL's efficiency in capturing energy from biowaste. Catalytic upgrading of the biocrude, including hydrotreatment (HDT) and other refining steps, reduced the oxygen content by 98% to 0.16 wt%, and boosted energy density to 45.8 MJ kg−1, aligning with ASTM D975 standards for diesel and ISO 8217 for marine fuels. The feasibility of co-processing biocrude with conventional heavy oil was also explored. Blending trials with 10 wt% partially upgraded biocrude showed stable performance over 200 hours in an HDT reactor, indicating compatibility and a viable pathway for integrating renewable biocrude with traditional heavy distillates, enhancing fuel production sustainability. This approach provides a promising route to incorporate renewable sources into conventional fuel production, supporting sustainable fuel technologies.
期刊介绍:
Sustainable Energy & Fuels will publish research that contributes to the development of sustainable energy technologies with a particular emphasis on new and next-generation technologies.