{"title":"增强Zn2SnO4/聚苯胺异质结的自供电紫外光探测性能","authors":"Songchi Liao, Chengfeng Wang, Huan He, Yuechun Fu","doi":"10.1016/j.optmat.2025.117032","DOIUrl":null,"url":null,"abstract":"<div><div>Inorganic/organic self-powered UV photodetectors based on Zn<sub>2</sub>SnO<sub>4</sub>/polyaniline (PANI) heterojunction are investigated in this study. Zn<sub>2</sub>SnO<sub>4</sub> microspheres were synthesized by the hydrothermal method, and PANI was directly polymerized on Zn<sub>2</sub>SnO<sub>4</sub> microspheres to form Zn<sub>2</sub>SnO<sub>4</sub>/PANI (ZP) compounds. The photodetectors constructed by n-Zn<sub>2</sub>SnO<sub>4</sub>/p-ZP heterojunction show excellent self-powered behavior with good stability and repeatability under UV light illumination. In particular, the device based on Zn<sub>2</sub>SnO<sub>4</sub>/ZP-30 displays the high photocurrent (10.805 μA), responsivity (251.279 mA W<sup>−1</sup>) and detectivity (1.629 × 10<sup>12</sup> Jones) at zero bias. The favorable bandgap difference and structure are contributed to separate and transport photogenerated carriers rapidly and thus enhance its photoresponse performances.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"163 ","pages":"Article 117032"},"PeriodicalIF":3.8000,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced self-powered UV photodetection performance of Zn2SnO4/polyaniline based heterojunction\",\"authors\":\"Songchi Liao, Chengfeng Wang, Huan He, Yuechun Fu\",\"doi\":\"10.1016/j.optmat.2025.117032\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Inorganic/organic self-powered UV photodetectors based on Zn<sub>2</sub>SnO<sub>4</sub>/polyaniline (PANI) heterojunction are investigated in this study. Zn<sub>2</sub>SnO<sub>4</sub> microspheres were synthesized by the hydrothermal method, and PANI was directly polymerized on Zn<sub>2</sub>SnO<sub>4</sub> microspheres to form Zn<sub>2</sub>SnO<sub>4</sub>/PANI (ZP) compounds. The photodetectors constructed by n-Zn<sub>2</sub>SnO<sub>4</sub>/p-ZP heterojunction show excellent self-powered behavior with good stability and repeatability under UV light illumination. In particular, the device based on Zn<sub>2</sub>SnO<sub>4</sub>/ZP-30 displays the high photocurrent (10.805 μA), responsivity (251.279 mA W<sup>−1</sup>) and detectivity (1.629 × 10<sup>12</sup> Jones) at zero bias. The favorable bandgap difference and structure are contributed to separate and transport photogenerated carriers rapidly and thus enhance its photoresponse performances.</div></div>\",\"PeriodicalId\":19564,\"journal\":{\"name\":\"Optical Materials\",\"volume\":\"163 \",\"pages\":\"Article 117032\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-04-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optical Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925346725003921\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925346725003921","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
研究了基于Zn2SnO4/聚苯胺(PANI)异质结的无机/有机自供电紫外光电探测器。采用水热法合成了Zn2SnO4微球,并将聚苯胺直接聚合在Zn2SnO4微球上,形成了Zn2SnO4/PANI (ZP)化合物。由n-Zn2SnO4/p-ZP异质结构建的光电探测器在紫外光照射下表现出良好的自供电性能,具有良好的稳定性和重复性。特别是,基于Zn2SnO4/ZP-30的器件在零偏置下具有高光电流(10.805 μA)、响应度(251.279 mA W−1)和探测率(1.629 × 1012 Jones)。良好的带隙差和结构有助于快速分离和传输光生载流子,从而提高其光响应性能。
Enhanced self-powered UV photodetection performance of Zn2SnO4/polyaniline based heterojunction
Inorganic/organic self-powered UV photodetectors based on Zn2SnO4/polyaniline (PANI) heterojunction are investigated in this study. Zn2SnO4 microspheres were synthesized by the hydrothermal method, and PANI was directly polymerized on Zn2SnO4 microspheres to form Zn2SnO4/PANI (ZP) compounds. The photodetectors constructed by n-Zn2SnO4/p-ZP heterojunction show excellent self-powered behavior with good stability and repeatability under UV light illumination. In particular, the device based on Zn2SnO4/ZP-30 displays the high photocurrent (10.805 μA), responsivity (251.279 mA W−1) and detectivity (1.629 × 1012 Jones) at zero bias. The favorable bandgap difference and structure are contributed to separate and transport photogenerated carriers rapidly and thus enhance its photoresponse performances.
期刊介绍:
Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials.
OPTICAL MATERIALS focuses on:
• Optical Properties of Material Systems;
• The Materials Aspects of Optical Phenomena;
• The Materials Aspects of Devices and Applications.
Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.