银包埋ZnO纳米复合材料的光催化和抗氧化性能研究。

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-03-20 eCollection Date: 2025-04-01 DOI:10.1021/acsomega.4c08896
Sachin K Dhawale, Prashant D Sarvalkar, Chetan S Shinde, Neeraj R Prasad, Kalyanrao M Garadkar, Kiran Kumar K Sharma, Avinash A Ramteke
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引用次数: 0

摘要

本文主要研究了不同银(Ag)含量(1、3、5 wt %)的银包埋ZnO纳米复合材料的合成和表征,以评价其光催化和抗氧化活性。采用溶胶-凝胶法合成纳米复合材料,然后进行热分解,并通过XRD、SEM、BET、Raman、EDS、TEM、FTIR和UV-vis光谱对其进行表征。在紫外光下测试了罗丹明6G (R6G)染料的光催化降解,并通过DPPH、ABTS、FRAP和FIC测定了其抗氧化能力。在所合成的样品中,ZnO-5 wt % Ag纳米复合材料的光催化效率提高,对R6G的降解率达到93.36%,反应速率常数为6.54 × 10-3 min-1。它还具有可回收性,在五次循环后仍保持91%以上的效率。在抗氧化实验中,ZnO-5 wt % Ag复合物显示出增强的自由基清除能力,证实了其强大的抗氧化潜力。这些银包埋ZnO纳米复合材料具有双重功能,增强了光催化和抗氧化活性。未来的研究将集中在其可扩展性和可见光催化性能上,以加强其在环境修复和生物医学方面的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Studies on Photocatalytic and Antioxidant Efficacy of Ag-Embedded ZnO Nanocomposites.

This study focuses on the synthesis and characterization of Ag-embedded ZnO nanocomposites with varying silver (Ag) contents (1, 3, and 5 wt %) to evaluate their photocatalytic and antioxidant activities. The nanocomposites were synthesized using a sol-gel method, followed by thermal decomposition, and characterized by XRD, SEM, BET, Raman, EDS, TEM, FTIR, and UV-vis spectroscopy. The photocatalytic degradation of the rhodamine 6G (R6G) dye was tested under UV light, and its antioxidant capacity was evaluated using DPPH, ABTS, FRAP, and FIC assays. Among the synthesized samples, the ZnO-5 wt % Ag nanocomposite exhibited the enhanced photocatalytic efficiency, achieving 93.36% degradation of R6G, with a reaction rate constant of 6.54 × 10-3 min-1. It also demonstrated recyclability, retaining over 91% efficiency after five cycles. In the antioxidant assays, the ZnO-5 wt % Ag composite showed enhanced free radical scavenging capacity, confirming its strong antioxidant potential. These Ag-embedded ZnO nanocomposites offer a dual functionality, enhancing both photocatalytic and antioxidant activities. Future research will focus on their scalability and visible-light photocatalytic performance to enhance their applications in environmental remediation and biomedical applications.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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