{"title":"响应面法：丝瓜海绵生物炭对盐酸土霉素的吸附作用","authors":"Fanbao Deng, Jihong Zhao, Xiaoqian Yin, Xue Song, Yongde Liu, Jie Zhang, Tianrun Bai, Liwen Zhang","doi":"10.1002/clen.70011","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>A potential biochar (KLS<sub>F</sub>-BC) was prepared by pyrolysis of loofah sponge (LS) at 600°C using KOH as an activator to adsorb oxytetracycline hydrochloride (OTCH). The response surface method (RSM) was applied to obtain the best preparation parameters (the first pyrolysis temperature of 573°C and pyrolysis time of 138 min, LS<sub>F</sub>-BC/KOH, 1:3, m/m) and adsorption conditions (OTCH concentration: 100 mg L<sup>−1</sup>, adsorbent dosage: 0.84 g L<sup>−1</sup>, adsorption time: 28 min, initial solution pH: 5.1), under which the adsorption capacity of KLS<sub>F</sub>-BC for OTCH was 662.96 mg g<sup>−1</sup>. The adsorption data of OTCH on KLS<sub>F</sub>-BC conformed to the pseudo-second-order model and Freundlich model. The removal mechanisms of OTCH involved hydrogen bonding, π–π EDA interaction, pore filling, and electrostatic interactions. The study confirmed the great potential and significant application prospects of KLS<sub>F</sub>-BC for removing OTCH from wastewater, providing a valuable reference for biomass resource utilization and antibiotics treatment.</p>\n </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 4","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Oxytetracycline Hydrochloride Adsorption by Biochar From Loofah Sponge Using Response Surface Method\",\"authors\":\"Fanbao Deng, Jihong Zhao, Xiaoqian Yin, Xue Song, Yongde Liu, Jie Zhang, Tianrun Bai, Liwen Zhang\",\"doi\":\"10.1002/clen.70011\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>A potential biochar (KLS<sub>F</sub>-BC) was prepared by pyrolysis of loofah sponge (LS) at 600°C using KOH as an activator to adsorb oxytetracycline hydrochloride (OTCH). The response surface method (RSM) was applied to obtain the best preparation parameters (the first pyrolysis temperature of 573°C and pyrolysis time of 138 min, LS<sub>F</sub>-BC/KOH, 1:3, m/m) and adsorption conditions (OTCH concentration: 100 mg L<sup>−1</sup>, adsorbent dosage: 0.84 g L<sup>−1</sup>, adsorption time: 28 min, initial solution pH: 5.1), under which the adsorption capacity of KLS<sub>F</sub>-BC for OTCH was 662.96 mg g<sup>−1</sup>. The adsorption data of OTCH on KLS<sub>F</sub>-BC conformed to the pseudo-second-order model and Freundlich model. The removal mechanisms of OTCH involved hydrogen bonding, π–π EDA interaction, pore filling, and electrostatic interactions. The study confirmed the great potential and significant application prospects of KLS<sub>F</sub>-BC for removing OTCH from wastewater, providing a valuable reference for biomass resource utilization and antibiotics treatment.</p>\\n </div>\",\"PeriodicalId\":10306,\"journal\":{\"name\":\"Clean-soil Air Water\",\"volume\":\"53 4\",\"pages\":\"\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-04-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Clean-soil Air Water\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/clen.70011\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Clean-soil Air Water","FirstCategoryId":"93","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/clen.70011","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Oxytetracycline Hydrochloride Adsorption by Biochar From Loofah Sponge Using Response Surface Method
A potential biochar (KLSF-BC) was prepared by pyrolysis of loofah sponge (LS) at 600°C using KOH as an activator to adsorb oxytetracycline hydrochloride (OTCH). The response surface method (RSM) was applied to obtain the best preparation parameters (the first pyrolysis temperature of 573°C and pyrolysis time of 138 min, LSF-BC/KOH, 1:3, m/m) and adsorption conditions (OTCH concentration: 100 mg L−1, adsorbent dosage: 0.84 g L−1, adsorption time: 28 min, initial solution pH: 5.1), under which the adsorption capacity of KLSF-BC for OTCH was 662.96 mg g−1. The adsorption data of OTCH on KLSF-BC conformed to the pseudo-second-order model and Freundlich model. The removal mechanisms of OTCH involved hydrogen bonding, π–π EDA interaction, pore filling, and electrostatic interactions. The study confirmed the great potential and significant application prospects of KLSF-BC for removing OTCH from wastewater, providing a valuable reference for biomass resource utilization and antibiotics treatment.
期刊介绍：
CLEAN covers all aspects of Sustainability and Environmental Safety. The journal focuses on organ/human--environment interactions giving interdisciplinary insights on a broad range of topics including air pollution, waste management, the water cycle, and environmental conservation. With a 2019 Journal Impact Factor of 1.603 (Journal Citation Reports (Clarivate Analytics, 2020), the journal publishes an attractive mixture of peer-reviewed scientific reviews, research papers, and short communications.
Papers dealing with environmental sustainability issues from such fields as agriculture, biological sciences, energy, food sciences, geography, geology, meteorology, nutrition, soil and water sciences, etc., are welcome.
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