水溶性ZnPc(COOH)4/Ch/MgO自组装体系

IF 4.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
RSC Advances Pub Date : 2025-04-08 DOI:10.1039/D5RA01256B
Tamara Potlog, Ion Lungu, Mariana Diru, Alexandrina Druta and Marius Dobromir
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引用次数: 0

摘要

本研究开发了一种新型的金属氧化物NP/MPc衍生物复合材料,作为光动力治疗癌症和光催化活性的高效光敏剂。ZnPc(COOH)4/MgO复合材料由合成的水溶性四羧基酞菁锌衍生物和不同沉淀剂制备的氧化镁纳米颗粒组成。采用紫外可见光谱法和荧光分光光度法对ZnPc(COOH)4/MgO复合材料进行了研究。自组装的ZnPc(COOH)4/MgO复合材料的吸收光谱和发射光谱显示它们之间的Stokes位移接近119 nm。复合材料还表现出室温磷光,平均三重态寿命为5.01 μs,量子产率为10.63%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Water-soluble ZnPc(COOH)4/Ch/MgO self-assembled systems

Water-soluble ZnPc(COOH)4/Ch/MgO self-assembled systems

In this study, a new metal oxide NP/MPc derivative composite as efficient photosensitizer for photodynamic therapy of cancer and photocatalytic activities is developed. The ZnPc(COOH)4/MgO composite consists of the synthesized water soluble tetra-carboxy zinc phthalocyanine derivative and magnesium oxide nanoparticles prepared with different precipitating agents. The ZnPc(COOH)4/MgO composites were investigated by UV-Vis spectroscopy and fluorescence spectrophotometry. The absorption and emission spectra of the self-assembled ZnPc(COOH)4/MgO composite highlight the Stokes shift between them, which is near 119 nm. The composites also exhibited room-temperature phosphorescence with an average triplet state lifetime of 5.01 μs and a quantum yield of 10.63%.

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来源期刊
RSC Advances
RSC Advances chemical sciences-
CiteScore
7.50
自引率
2.60%
发文量
3116
审稿时长
1.6 months
期刊介绍: An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.
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