Shujie Xie, Jiaheng He, Xuankun Wu, Zhe Cheng, Lian Zhang, Changxin Mi, Qiao Xie and Yun Zhang*,
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In this study, we propose an approach to relieve the FLP effect and achieve ultralow contact resistivity by forming an approximately 2 nm gallium oxide passivation layer at the Ti/n<sup>+</sup>-GaN interface through air annealing of the n<sup>+</sup>-GaN surface. This passivation method yields 0.24 eV Schottky barrier height and a low specific contact resistivity of 3 × 10<sup>–8</sup> Ω·cm<sup>2</sup> for GaN Ohmic contact. Atomic force microscopy (AFM), transmission electron microscopy (TEM), and energy-dispersive X-ray spectroscopy (EDX) confirm the formation of various oxide layers under different annealing conditions. 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引用次数: 0
摘要
随着氮化镓(GaN)器件向更高频率性能扩展,其发展越来越受到欧姆接触电阻升高导致的寄生延迟的限制。为缓解这一问题,以钛(Ti)作为欧姆接触金属的选择性面积生长 n 型掺杂氮化镓(n+-GaN)已得到广泛应用,实现了 1 × 10-7 Ω-cm2 的比接触电阻率。然而,Ti/n+-GaN 界面比接触电阻率的进一步降低受到费米级针销(FLP)效应的限制,该效应源于金属诱导的间隙态和界面悬空键合态。在本研究中,我们提出了一种缓解 FLP 效应并实现超低接触电阻率的方法,即通过对 n+-GaN 表面进行空气退火,在 Ti/n+-GaN 界面形成约 2 nm 的氧化镓钝化层。这种钝化方法使 GaN 欧姆触点的肖特基势垒高度达到 0.24 eV,比接触电阻率低至 3 × 10-8 Ω-cm2。原子力显微镜(AFM)、透射电子显微镜(TEM)和能量色散 X 射线光谱(EDX)证实了不同退火条件下各种氧化层的形成。这项研究展示了降低欧姆接触电阻、解决寄生电阻以及进一步扩展 GaN 器件以提高性能的有效策略。
Achieving Ultralow Specific Contact Resistivity in Ti/n+-GaN Ohmic Contacts by Mitigating the FLP Effect with a Gallium Oxide Interlayer
As gallium nitride (GaN) devices are scaled for higher-frequency performance, their advancement is increasingly limited by parasitic delays due to elevated Ohmic contact resistance. To mitigate this, selective-area growth n-type doped GaN (n+-GaN) with titanium (Ti) as the Ohmic contact metal has been widely used, achieving specific contact resistivity in the range of 1 × 10–7 Ω·cm2. However, further reductions of Ti/n+-GaN interfacial specific contact resistivity are constrained by the Fermi-level pinning (FLP) effect that originated from the metal-induced gap states and interfacial dangling bonding states. In this study, we propose an approach to relieve the FLP effect and achieve ultralow contact resistivity by forming an approximately 2 nm gallium oxide passivation layer at the Ti/n+-GaN interface through air annealing of the n+-GaN surface. This passivation method yields 0.24 eV Schottky barrier height and a low specific contact resistivity of 3 × 10–8 Ω·cm2 for GaN Ohmic contact. Atomic force microscopy (AFM), transmission electron microscopy (TEM), and energy-dispersive X-ray spectroscopy (EDX) confirm the formation of various oxide layers under different annealing conditions. This study demonstrates an effective strategy for reducing Ohmic contact resistance, addressing parasitic resistance, and enabling further scaling of GaN devices for enhanced performance.
期刊介绍:
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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