Luyao Wang , Kai Liu , Li Wan , Wuhui Jia , Shouchuan Zhang , Haoming Tang , Gaoyang Bu , Xinrui Yue
{"title":"断控型地热系统气体地球化学特征及热源机制——以武公山西部地区为例","authors":"Luyao Wang , Kai Liu , Li Wan , Wuhui Jia , Shouchuan Zhang , Haoming Tang , Gaoyang Bu , Xinrui Yue","doi":"10.1016/j.gexplo.2025.107768","DOIUrl":null,"url":null,"abstract":"<div><div>Geothermal systems controlled by active fault zones represent a critical component of sustainable energy exploration, yet their fluid genesis and heat source mechanisms remain poorly constrained in complex tectonic settings. This study investigates the chemical composition and isotopic data of dissolved gases from multiple water bodies in the western Wugongshan area to elucidate the sources of hydrothermal volatiles, reservoir temperature, lithospheric thermal structure, and heat source mechanisms. Our findings reveal a distinctive gas assemblage dominated by N<sub>2</sub> (74.51–90.83 vol%), with subordinate O<sub>2</sub> (3.58–18.19 vol%) and CO<sub>2</sub> (1.17–5.93 vol%). Helium isotopic signatures (0.08–0.16 Ra) indicate a primary crustal radiogenic origin (97.79–99.21 %), while δ<sup>13</sup>C<sub>CO2</sub>values (−11.9 ‰ to −21.9 ‰ VPDB) and δ<sup>13</sup>C<sub>CH4</sub> values (−49.8 ‰ to −74.8 ‰ VPDB) suggest that CO<sub>2</sub> predominantly originates from crustal organic sources and CH<sub>4</sub> is primarily generated through thermogenic and microbiological processes. The application of IMG and CO<sub>2</sub>-CH<sub>4</sub> gas isotope geothermometers indicates that the temperature of the deep gas source varies between 100.2 °C and 197.3 °C, which is marginally above the temperature range of the geothermal water reservoir, recorded at 120.3 °C to 137.1 °C. Furthermore, integrated analysis of <sup>3</sup>He/<sup>4</sup>He, borehole temperature measurements, and rock thermophysical properties indicate that the lithospheric thermal structure of the study area is classified as “hot crust-cold mantle,” with a crust-mantle heat flow ratio ranging from 1.36 to 1.56. Finally, the heat source mechanism of the fault-controlled geothermal system in the western Wugongshan area was presented: (1) thermal accumulation of blanket-shaped heat flow conduction and Moho surface thinning diffluence; (2) radioactive decay heat from crustal concentrated layers; and (3) convective heat from deep faults. This study provides a new perspective on the heat source mechanisms of fault-controlled geothermal systems and serves as an important reference for the exploration and utilization of geothermal resources with similar origins.</div></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"274 ","pages":"Article 107768"},"PeriodicalIF":3.4000,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gas geochemical characteristics and heat source mechanisms of a fault-controlled geothermal system: A case study from the western Wugongshan area, South China\",\"authors\":\"Luyao Wang , Kai Liu , Li Wan , Wuhui Jia , Shouchuan Zhang , Haoming Tang , Gaoyang Bu , Xinrui Yue\",\"doi\":\"10.1016/j.gexplo.2025.107768\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Geothermal systems controlled by active fault zones represent a critical component of sustainable energy exploration, yet their fluid genesis and heat source mechanisms remain poorly constrained in complex tectonic settings. This study investigates the chemical composition and isotopic data of dissolved gases from multiple water bodies in the western Wugongshan area to elucidate the sources of hydrothermal volatiles, reservoir temperature, lithospheric thermal structure, and heat source mechanisms. Our findings reveal a distinctive gas assemblage dominated by N<sub>2</sub> (74.51–90.83 vol%), with subordinate O<sub>2</sub> (3.58–18.19 vol%) and CO<sub>2</sub> (1.17–5.93 vol%). Helium isotopic signatures (0.08–0.16 Ra) indicate a primary crustal radiogenic origin (97.79–99.21 %), while δ<sup>13</sup>C<sub>CO2</sub>values (−11.9 ‰ to −21.9 ‰ VPDB) and δ<sup>13</sup>C<sub>CH4</sub> values (−49.8 ‰ to −74.8 ‰ VPDB) suggest that CO<sub>2</sub> predominantly originates from crustal organic sources and CH<sub>4</sub> is primarily generated through thermogenic and microbiological processes. The application of IMG and CO<sub>2</sub>-CH<sub>4</sub> gas isotope geothermometers indicates that the temperature of the deep gas source varies between 100.2 °C and 197.3 °C, which is marginally above the temperature range of the geothermal water reservoir, recorded at 120.3 °C to 137.1 °C. Furthermore, integrated analysis of <sup>3</sup>He/<sup>4</sup>He, borehole temperature measurements, and rock thermophysical properties indicate that the lithospheric thermal structure of the study area is classified as “hot crust-cold mantle,” with a crust-mantle heat flow ratio ranging from 1.36 to 1.56. Finally, the heat source mechanism of the fault-controlled geothermal system in the western Wugongshan area was presented: (1) thermal accumulation of blanket-shaped heat flow conduction and Moho surface thinning diffluence; (2) radioactive decay heat from crustal concentrated layers; and (3) convective heat from deep faults. This study provides a new perspective on the heat source mechanisms of fault-controlled geothermal systems and serves as an important reference for the exploration and utilization of geothermal resources with similar origins.</div></div>\",\"PeriodicalId\":16336,\"journal\":{\"name\":\"Journal of Geochemical Exploration\",\"volume\":\"274 \",\"pages\":\"Article 107768\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2025-04-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Geochemical Exploration\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0375674225001001\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0375674225001001","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Gas geochemical characteristics and heat source mechanisms of a fault-controlled geothermal system: A case study from the western Wugongshan area, South China
Geothermal systems controlled by active fault zones represent a critical component of sustainable energy exploration, yet their fluid genesis and heat source mechanisms remain poorly constrained in complex tectonic settings. This study investigates the chemical composition and isotopic data of dissolved gases from multiple water bodies in the western Wugongshan area to elucidate the sources of hydrothermal volatiles, reservoir temperature, lithospheric thermal structure, and heat source mechanisms. Our findings reveal a distinctive gas assemblage dominated by N2 (74.51–90.83 vol%), with subordinate O2 (3.58–18.19 vol%) and CO2 (1.17–5.93 vol%). Helium isotopic signatures (0.08–0.16 Ra) indicate a primary crustal radiogenic origin (97.79–99.21 %), while δ13CCO2values (−11.9 ‰ to −21.9 ‰ VPDB) and δ13CCH4 values (−49.8 ‰ to −74.8 ‰ VPDB) suggest that CO2 predominantly originates from crustal organic sources and CH4 is primarily generated through thermogenic and microbiological processes. The application of IMG and CO2-CH4 gas isotope geothermometers indicates that the temperature of the deep gas source varies between 100.2 °C and 197.3 °C, which is marginally above the temperature range of the geothermal water reservoir, recorded at 120.3 °C to 137.1 °C. Furthermore, integrated analysis of 3He/4He, borehole temperature measurements, and rock thermophysical properties indicate that the lithospheric thermal structure of the study area is classified as “hot crust-cold mantle,” with a crust-mantle heat flow ratio ranging from 1.36 to 1.56. Finally, the heat source mechanism of the fault-controlled geothermal system in the western Wugongshan area was presented: (1) thermal accumulation of blanket-shaped heat flow conduction and Moho surface thinning diffluence; (2) radioactive decay heat from crustal concentrated layers; and (3) convective heat from deep faults. This study provides a new perspective on the heat source mechanisms of fault-controlled geothermal systems and serves as an important reference for the exploration and utilization of geothermal resources with similar origins.
期刊介绍:
Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics.
Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to:
define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas.
analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation.
evaluate effects of historical mining activities on the surface environment.
trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices.
assess and quantify natural and technogenic radioactivity in the environment.
determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis.
assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches.
Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.