Near-Infrared and Visible Dual-Band Self-Trapped Exciton Emissions from Li+-Doped Cs2NaScCl6 Double Perovskites

Self-trapped excitons (STEs) have garnered significant attention due to their broadband emission and large Stokes shift. However, achieving multiband, particularly near-infrared (NIR) STE emissions remains a challenge, restricting their optoelectronic applications. Herein, we realize efficient dual-band STE emissions encompassing blue and NIR regions based on Cs₂NaScCl₆ double perovskites (DPs) via minor Li⁺-doping structural engineering. The dual-band emissions in the blue and NIR regions originated from the STE states associated with [ScCl₆]^3– and [NaCl₆]^5– octahedra, respectively. Li⁺ doping markedly enhanced the photoluminescence (PL) quantum yields of dual-band STE emissions from 3.2% and 2.7% to 98.2% and 45.4%, respectively. Steady-state/transient PL spectroscopies and density functional theory calculations revealed that Li⁺ doping intensified sublattice distortion and enhanced charge carrier localization within Cs₂NaScCl₆ DPs, thus boosting the dual-band STE emissions. These findings gain deep insights into STE manipulation in DPs through local structural engineering, thus stimulating the exploitation of DPs toward versatile applications.