随机森林机制识别18650锂离子电池外部短路初始条件

IF 2.4 4区 化学 Q3 CHEMISTRY, PHYSICAL
Ionics Pub Date : 2025-02-05 DOI:10.1007/s11581-025-06122-6
Joelton Deonei Gotz, José Rodolfo Galvão, Emilson Ribeiro Viana, Milton Borsato, Fernanda Cristina Corrêa, Alceu André Badin
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引用次数: 0

摘要

锂离子电池(LIB)是目前市场上主流的储能技术(ESS)技术,主要是因为它具有寿命长、密度大、容量大、自放电低等优点。尽管如此,LIB仍然对故障很敏感,如果管理不善,可以观察到几种类型的滥用,并导致性能和安全问题。因此,有必要了解主要的滥用行为、它们的原因、后果,以及如何防止它们发生。因此,本文的贡献分为两步:首先,它展示了18650 LIB中外部短路(ESC)实验的五种应用研究。然后,应用随机森林机制对决定ESC后果强度的条件进行分类。在第一部分中,进行了以下实验:(I)改变初始电压(从3.5到4.2 V), (II)改变ESC与放松时间之间的时间(2,10,20,30和60秒),(III)改变电池的容量(20毫安时,400毫安时,940毫安时,1202毫安时和1750毫安时),(IV)改变外部电阻(从50到250米\(\Omega \)与50米\(\Omega \)步长),(V)改变环境温度(30 \(^{\circ }\)℃,40 \(^{\circ }\)℃,50 \(^{\circ }\)℃,60 \(^{\circ }\)℃),和70 \(^{\circ }\) C)。结果表明,ESC电流曲线包括四个阶段。在电池内的高电流流动期间,温度显著升高。此外,外部电阻、ESC的时间、环境温度、电池容量和荷电状态(SOC)对ESC的强度和ESC电流的大小起着至关重要的作用。细胞电流被证明是用于ESC预防机制的主要参数,因为它代表了几乎所有ESC原因的相似行为。尽管如此,根据ESC的原因和临界程度,这项工作呈现出不同幅度的当前曲线。因此,从实验中收集的信息和专业知识可用于机器学习预防机制,以监测第一阶段的电池滥用和故障,而不需要新的传感器和硬件,这是本工作的第二个贡献。它包括应用随机森林机制,根据从电池收集的主要信号来识别ESC的原因/条件。结果表明,该模型对ESC初始条件的估计精度可达R2的0.99。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A random forest mechanism to identify the initial conditions of external short circuits in 18650 lithium-ion batteries

Lithium-ion battery (LIB) is the mainstream energy storage technology (ESS) technology in this market, mainly because it has several advantages such as long lifetime, high density and capacity, and low self-discharging. Despite that, LIB is still sensitive to failures, and if it is not well managed, several types of abuse can be observed and cause performance and security issues. Therefore, it is essential to understand the main abuses, their causes, consequences, and how they happen to prevent them. Thus, this paper presents a contribution of two steps: firstly, it demonstrates the study of five applications of external short-circuit (ESC) experiments in 18650 LIB. Then, a random forest mechanism was applied to classify the conditions that determine the intensity of the consequences of the ESC. In the first part, the following experiments have been performed: (I) varying initial voltage (from 3.5 to 4.2 V), (II) changing the time between ESC with a relaxing time (2, 10, 20, 30, and 60 s), (III) varying capacity of the cell (20 mAh, 400 mAh, 940 mAh, 1202 mAh, and 1750 mA), (IV) varying external resistance (from 50 to 250 m\(\Omega \) with 50 m\(\Omega \) step), and (V) varying the ambient temperature (30 \(^{\circ }\)C, 40 \(^{\circ }\)C, 50 \(^{\circ }\)C, 60 \(^{\circ }\)C, and 70 \(^{\circ }\)C). The results indicate that the ESC current curve comprises four stages. The temperature increases significantly during the high current flow in the cell. In addition, the external resistance, the time of the ESC, the ambient temperature, the cell’s capacity, and the state of charge (SOC) play a vital role in the ESC’s intensity and the ESC current’s magnitude. The cell current is shown to be the main parameter used for ESC prevention mechanisms because it represents a similar behavior for almost every cause of ESC. Despite that, this work presents different magnitudes of the current curve depending on the causes and criticality of the ESC. Therefore, the information and expertise collected from the experiments can be used for machine learning prevention mechanisms to monitor battery abuses and failures in the first stage without the demand for new sensors and hardware, which is the second contribution of this work. It consists of applying a random forest mechanism to identify the causes/conditions of the ESC based on the main signals collected from the batteries. The results indicated that the proposed model can estimate the initial conditions of the ESC up to 0.99 of R2.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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