Jing Chen*, Rong Deng, Lianqin Zhu, Yaqin Shi and Wenli Xue,
{"title":"基于Ti3C2量子点的水杨酸比荧光检测","authors":"Jing Chen*, Rong Deng, Lianqin Zhu, Yaqin Shi and Wenli Xue, ","doi":"10.1021/acsanm.4c0733210.1021/acsanm.4c07332","DOIUrl":null,"url":null,"abstract":"<p >Ti<sub>3</sub>C<sub>2</sub> QDs with stable blue luminescence at 352 nm were synthesized by using arginine (Arg) as a ligand. Based on the interaction between salicylic acid (SA) and Arg-Ti<sub>3</sub>C<sub>2</sub> QDs, an enhanced ratio fluorescence sensor was constructed for fluorescence detection of SA. When SA was added to the system, fluorescence through the internal filtration effect (IFE) of Arg-Ti<sub>3</sub>C<sub>2</sub> QDs at 352 nm was gradually weakened, while the interaction between SA and Arg-Ti<sub>3</sub>C<sub>2</sub> QDs through hydrogen led to the appearance and significant enhancement of fluorescence at 403.9 nm, leading to ratio fluorescence. The system has a good detection limit (LOD) of 0.57 μM and excellent selectivity. And it can be applied to the detection of SA in the essence of actual samples, which can effectively prevent harm to the human body caused by adding too much SA in cosmetics.</p>","PeriodicalId":6,"journal":{"name":"ACS Applied Nano Materials","volume":"8 13","pages":"6403–6410 6403–6410"},"PeriodicalIF":5.5000,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ratio Fluorescence Detection of Salicylic Acid Based on Ti3C2 Quantum Dots\",\"authors\":\"Jing Chen*, Rong Deng, Lianqin Zhu, Yaqin Shi and Wenli Xue, \",\"doi\":\"10.1021/acsanm.4c0733210.1021/acsanm.4c07332\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Ti<sub>3</sub>C<sub>2</sub> QDs with stable blue luminescence at 352 nm were synthesized by using arginine (Arg) as a ligand. Based on the interaction between salicylic acid (SA) and Arg-Ti<sub>3</sub>C<sub>2</sub> QDs, an enhanced ratio fluorescence sensor was constructed for fluorescence detection of SA. When SA was added to the system, fluorescence through the internal filtration effect (IFE) of Arg-Ti<sub>3</sub>C<sub>2</sub> QDs at 352 nm was gradually weakened, while the interaction between SA and Arg-Ti<sub>3</sub>C<sub>2</sub> QDs through hydrogen led to the appearance and significant enhancement of fluorescence at 403.9 nm, leading to ratio fluorescence. The system has a good detection limit (LOD) of 0.57 μM and excellent selectivity. And it can be applied to the detection of SA in the essence of actual samples, which can effectively prevent harm to the human body caused by adding too much SA in cosmetics.</p>\",\"PeriodicalId\":6,\"journal\":{\"name\":\"ACS Applied Nano Materials\",\"volume\":\"8 13\",\"pages\":\"6403–6410 6403–6410\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2025-03-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Nano Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsanm.4c07332\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Nano Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsanm.4c07332","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Ratio Fluorescence Detection of Salicylic Acid Based on Ti3C2 Quantum Dots
Ti3C2 QDs with stable blue luminescence at 352 nm were synthesized by using arginine (Arg) as a ligand. Based on the interaction between salicylic acid (SA) and Arg-Ti3C2 QDs, an enhanced ratio fluorescence sensor was constructed for fluorescence detection of SA. When SA was added to the system, fluorescence through the internal filtration effect (IFE) of Arg-Ti3C2 QDs at 352 nm was gradually weakened, while the interaction between SA and Arg-Ti3C2 QDs through hydrogen led to the appearance and significant enhancement of fluorescence at 403.9 nm, leading to ratio fluorescence. The system has a good detection limit (LOD) of 0.57 μM and excellent selectivity. And it can be applied to the detection of SA in the essence of actual samples, which can effectively prevent harm to the human body caused by adding too much SA in cosmetics.
期刊介绍：
ACS Applied Nano Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics and biology relevant to applications of nanomaterials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important applications of nanomaterials.
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