{"title":"由氧化石墨烯和消费后回收聚丙烯制成的“玻璃体纳米复合材料”。","authors":"Indranil Dey, Debashrita Kundu, Sayon Ghosh, Samir Mandal, Ketaki Samanta, Suryasarathi Bose","doi":"10.1039/d4na00904e","DOIUrl":null,"url":null,"abstract":"<p><p>Post-consumer recycled polypropylene (PCR PP) is promising for sustainable applications, yet its limitations in electrical conductivity and mechanical properties require modifications. This study develops a vitrimer nanocomposite by modifying PCR PP <i>via</i> styrene-assisted maleic anhydride grafting and incorporating a molecule containing multiple epoxide groups facilitating effective crosslinking. Graphene oxide (GO) is added as a nanofiller, improving rheological, thermal, electrical and infrared thermal properties. Characterization techniques confirm structural enhancements, while tensile testing shows significant gains in strength and modulus. The vitrimer nanocomposite demonstrates recyclability and high performance, offering a sustainable path for advanced engineering applications within a circular economy framework.</p>","PeriodicalId":18806,"journal":{"name":"Nanoscale Advances","volume":" ","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11955918/pdf/","citationCount":"0","resultStr":"{\"title\":\"'Vitrimer nanocomposites' derived from graphene oxide and post-consumer recycled polypropylene.\",\"authors\":\"Indranil Dey, Debashrita Kundu, Sayon Ghosh, Samir Mandal, Ketaki Samanta, Suryasarathi Bose\",\"doi\":\"10.1039/d4na00904e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Post-consumer recycled polypropylene (PCR PP) is promising for sustainable applications, yet its limitations in electrical conductivity and mechanical properties require modifications. This study develops a vitrimer nanocomposite by modifying PCR PP <i>via</i> styrene-assisted maleic anhydride grafting and incorporating a molecule containing multiple epoxide groups facilitating effective crosslinking. Graphene oxide (GO) is added as a nanofiller, improving rheological, thermal, electrical and infrared thermal properties. Characterization techniques confirm structural enhancements, while tensile testing shows significant gains in strength and modulus. The vitrimer nanocomposite demonstrates recyclability and high performance, offering a sustainable path for advanced engineering applications within a circular economy framework.</p>\",\"PeriodicalId\":18806,\"journal\":{\"name\":\"Nanoscale Advances\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-03-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11955918/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanoscale Advances\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1039/d4na00904e\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale Advances","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4na00904e","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
'Vitrimer nanocomposites' derived from graphene oxide and post-consumer recycled polypropylene.
Post-consumer recycled polypropylene (PCR PP) is promising for sustainable applications, yet its limitations in electrical conductivity and mechanical properties require modifications. This study develops a vitrimer nanocomposite by modifying PCR PP via styrene-assisted maleic anhydride grafting and incorporating a molecule containing multiple epoxide groups facilitating effective crosslinking. Graphene oxide (GO) is added as a nanofiller, improving rheological, thermal, electrical and infrared thermal properties. Characterization techniques confirm structural enhancements, while tensile testing shows significant gains in strength and modulus. The vitrimer nanocomposite demonstrates recyclability and high performance, offering a sustainable path for advanced engineering applications within a circular economy framework.