由氧化石墨烯和消费后回收聚丙烯制成的“玻璃体纳米复合材料”。

IF 4.6 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Indranil Dey, Debashrita Kundu, Sayon Ghosh, Samir Mandal, Ketaki Samanta, Suryasarathi Bose
{"title":"由氧化石墨烯和消费后回收聚丙烯制成的“玻璃体纳米复合材料”。","authors":"Indranil Dey, Debashrita Kundu, Sayon Ghosh, Samir Mandal, Ketaki Samanta, Suryasarathi Bose","doi":"10.1039/d4na00904e","DOIUrl":null,"url":null,"abstract":"<p><p>Post-consumer recycled polypropylene (PCR PP) is promising for sustainable applications, yet its limitations in electrical conductivity and mechanical properties require modifications. This study develops a vitrimer nanocomposite by modifying PCR PP <i>via</i> styrene-assisted maleic anhydride grafting and incorporating a molecule containing multiple epoxide groups facilitating effective crosslinking. Graphene oxide (GO) is added as a nanofiller, improving rheological, thermal, electrical and infrared thermal properties. Characterization techniques confirm structural enhancements, while tensile testing shows significant gains in strength and modulus. The vitrimer nanocomposite demonstrates recyclability and high performance, offering a sustainable path for advanced engineering applications within a circular economy framework.</p>","PeriodicalId":18806,"journal":{"name":"Nanoscale Advances","volume":" ","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11955918/pdf/","citationCount":"0","resultStr":"{\"title\":\"'Vitrimer nanocomposites' derived from graphene oxide and post-consumer recycled polypropylene.\",\"authors\":\"Indranil Dey, Debashrita Kundu, Sayon Ghosh, Samir Mandal, Ketaki Samanta, Suryasarathi Bose\",\"doi\":\"10.1039/d4na00904e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Post-consumer recycled polypropylene (PCR PP) is promising for sustainable applications, yet its limitations in electrical conductivity and mechanical properties require modifications. This study develops a vitrimer nanocomposite by modifying PCR PP <i>via</i> styrene-assisted maleic anhydride grafting and incorporating a molecule containing multiple epoxide groups facilitating effective crosslinking. Graphene oxide (GO) is added as a nanofiller, improving rheological, thermal, electrical and infrared thermal properties. Characterization techniques confirm structural enhancements, while tensile testing shows significant gains in strength and modulus. The vitrimer nanocomposite demonstrates recyclability and high performance, offering a sustainable path for advanced engineering applications within a circular economy framework.</p>\",\"PeriodicalId\":18806,\"journal\":{\"name\":\"Nanoscale Advances\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-03-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11955918/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanoscale Advances\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1039/d4na00904e\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale Advances","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4na00904e","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

消费后再生聚丙烯(PCR PP)具有可持续应用的前景,但其在导电性和机械性能方面的局限性需要修改。本研究通过苯乙烯辅助马来酸酐接枝修饰PCR PP,并加入含有多个环氧基团的分子,促进有效交联,开发了一种玻璃聚合物纳米复合材料。添加氧化石墨烯(GO)作为纳米填料,改善流变性、热学、电学和红外热性能。表征技术证实结构增强,而拉伸测试显示强度和模量显著增加。玻璃聚合物纳米复合材料具有可回收性和高性能,为循环经济框架下的先进工程应用提供了可持续发展的途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
'Vitrimer nanocomposites' derived from graphene oxide and post-consumer recycled polypropylene.

Post-consumer recycled polypropylene (PCR PP) is promising for sustainable applications, yet its limitations in electrical conductivity and mechanical properties require modifications. This study develops a vitrimer nanocomposite by modifying PCR PP via styrene-assisted maleic anhydride grafting and incorporating a molecule containing multiple epoxide groups facilitating effective crosslinking. Graphene oxide (GO) is added as a nanofiller, improving rheological, thermal, electrical and infrared thermal properties. Characterization techniques confirm structural enhancements, while tensile testing shows significant gains in strength and modulus. The vitrimer nanocomposite demonstrates recyclability and high performance, offering a sustainable path for advanced engineering applications within a circular economy framework.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Nanoscale Advances
Nanoscale Advances Multiple-
CiteScore
8.00
自引率
2.10%
发文量
461
审稿时长
9 weeks
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信