金属有机框架(MOFs):环境可持续性的多功能平台。

IF 7.5 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Velu Manikandan, Jothi Vinoth Kumar, Duraisamy Elango, Velu Subash, Palaniyappan Jayanthi, Saurav Dixit, Subhav Singh
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引用次数: 0

摘要

金属有机框架(mof)已经成为连接无机化学和有机化学的多功能材料,以应对关键的环境挑战。这些晶体结构由金属节点和有机连接物组成,具有独特的性能,如高表面积、可调孔径和结构多样性。mof合成的最新进展,特别是机械化学、微波辅助和超声波合成等创新方法,通过使用无毒溶剂、可再生原料和节能工艺,显著提高了可持续性,为减少对环境的影响提供了有前途的解决方案。本文综述了这些新方法及其在改善mof在环境修复、气体捕获和能量储存方面的应用方面的贡献。我们研究了mof在催化污染物降解、水净化和危险废物清除方面的潜力,以及它们在下一代储能技术(如超级电容器、电池和氢气生产)中的作用。此外,我们还解决了包括可扩展性、稳定性和长期性能在内的挑战,强调了持续创新合成技术以实现大规模mof应用的必要性。总的来说,mof作为多功能材料具有变革潜力,其合成和可持续性的进步对于其成功融入实际的环境和能源解决方案至关重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Metal-Organic Frameworks (MOFs): Multifunctional Platforms for Environmental Sustainability

Metal-Organic Frameworks (MOFs): Multifunctional Platforms for Environmental Sustainability

Metal-Organic Frameworks (MOFs) have emerged as versatile materials bridging inorganic and organic chemistry to address critical environmental challenges. Composed of metal nodes and organic linkers, these crystalline structures offer unique properties such as high surface area, tunable pore sizes, and structural diversity. Recent advancements in MOFs synthesis, particularly innovative approaches like mechanochemical, microwave-assisted, and ultrasonic synthesis, have significantly enhanced sustainability by utilizing non-toxic solvents, renewable feedstocks, and energy-efficient processes, offering promising solutions to reduce environmental impact. This review highlights these novel methods and their contributions to improving MOFs functionality for applications in environmental remediation, gas capture, and energy storage. We examine the potential of MOFs in catalysis for pollutant degradation, water purification, and hazardous waste removal, as well as their role in next-generation energy storage technologies, such as supercapacitors, batteries, and hydrogen production. Furthermore, we address challenges including scalability, stability, and long-term performance, underscoring the need for continued innovation in synthesis techniques to enable large-scale MOFs applications. Overall, MOFs hold transformative potential as multifunctional materials, and advancements in synthesis and sustainability are critical for their successful integration into practical environmental and energy solutions.

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来源期刊
Chemical record
Chemical record 化学-化学综合
CiteScore
11.00
自引率
3.00%
发文量
188
审稿时长
>12 weeks
期刊介绍: The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.
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