电子给体-受体（EDA）复合物介导的可见光驱动硫-氟键用碘化钾还原五氟磺酰芳烃。

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-03-24 DOI:10.1039/d5cc00764j

Tatsuhiro Uchikura , Fua Akutsu , Takahiko Akiyama

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引用次数: 0

摘要

描述了由电子供体-受体（EDA）络合物介导的五氟磺酰芳烃中硫-氟（S-F）键的还原。在光辐射条件下，烯丙基三丁基锡烷和碘化钾处理五氟磺酰芳烃，烯丙基硫化物收率高达81%。仅用碘化钾和可见光照射就实现了五氟磺酰芳烃S-F键的还原。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Electron donor–acceptor (EDA) complex mediated visible-light driven sulfur–fluorine bond reduction of pentafluorosulfanyl arenes using potassium iodide†‡

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Electron donor–acceptor (EDA) complex mediated visible-light driven sulfur–fluorine bond reduction of pentafluorosulfanyl arenes using potassium iodide†‡

The reduction of sulfur–fluorine (S–F) bonds in pentafluorosulfanyl arenes, which is mediated by an electron donor–acceptor (EDA) complex, is described. Treatment of pentafluorosulfanyl arenes with allyltributylstannane and potassium iodide under photoirradiation conditions furnished allyl sulfides in up to 81% yield. The S–F bond reduction in pentafluorosulfanyl arenes was realized using only potassium iodide and visible light irradiation.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.