Mohamadreza Shakiba , Mehdi Faraji , Shirzad Jouybar , Amin Foroozandeh , Ashkan Bigham , Majid Abdouss , Majid Saidi , Vahid Vatanpour , Rajender S. Varma
{"title":"Advanced nanofibers for water treatment: Unveiling the potential of electrospun polyacrylonitrile membranes","authors":"Mohamadreza Shakiba , Mehdi Faraji , Shirzad Jouybar , Amin Foroozandeh , Ashkan Bigham , Majid Abdouss , Majid Saidi , Vahid Vatanpour , Rajender S. Varma","doi":"10.1016/j.envres.2025.121403","DOIUrl":null,"url":null,"abstract":"<div><div>The challenges pertaining to the potable water scarcity and pollution motivates us to envision innovative strategies. Industrial wastewater containing hazardous heavy metals, synthetic dyes, and oil exacerbates the pursuit of clean drinking water. Among the array of available technologies, electrospun nanofiber membranes have garnered attention due to their efficiency, high surface-to-volume ratio, cost-effectiveness, scalability, and multifunctionality. These membranes possess distinct physical and chemical attributes that position them as ideal solutions to water purification challenges. Their versatility enables effective contaminant removal through filtration, adsorption, and chemical interactions. Polyacrylonitrile (PAN) emerges as a frontrunner among electrospun polymers due to its affordability, remarkable physical and chemical characteristics, and the ease of production. Research efforts have been dedicated to the study of electrospun PAN membranes, exploring modifications in terms of the functionalization of PAN molecular chain, incorporation of appropriate nanoparticles, and composition with other functional polymers. Parameters such as functional groups, hydrophilicity, mechanical properties, porosity, pore structure, reusability, sustainability, zeta potential, and operational conditions significantly influence the performance of electrospun PAN membranes in treating the contaminated water. Despite progress, challenges surrounding fouling, toxicity, scalability, selectivity, and production costs ought to be addressed strategically to enhance their practicality and real-world viability. This review comprehensively scrutinizes the current landscape of available electrospun PAN membranes in water treatment encompassing diverse range of synthesized entities and experimental outcomes. Additionally, the review delves into various approaches undertaken to optimize the performance of electrospun PAN membranes while proposing potential strategies to overcome the existing hindrances. By carefully analyzing the parameters that impact the performance of these membranes, this overview offers invaluable guidelines for researchers and engineers, thus empowering them to design tailored electrospun nanofiber membranes for specific water purification applications. As the innovative research continues and strategic efforts address the current challenges, these membranes can play a pivotal role in enhancing water quality, mitigating water scarcity, and contributing to environmental sustainability. The widespread application of electrospun nanofiber membranes in water treatment has the potential to create a lasting positive impact on global water resources and the environment. A dedicated effort towards their implementation will undoubtedly mark a crucial step towards a more sustainable and water-secure future.</div></div>","PeriodicalId":312,"journal":{"name":"Environmental Research","volume":"276 ","pages":"Article 121403"},"PeriodicalIF":7.7000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Research","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0013935125006541","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
摘要
饮用水短缺和污染带来的挑战促使我们设想创新战略。含有有害重金属、合成染料和石油的工业废水加剧了人们对清洁饮用水的追求。在一系列可用技术中,电纺纳米纤维膜因其高效率、高表面体积比、成本效益、可扩展性和多功能性而备受关注。这些膜具有独特的物理和化学属性,是应对水净化挑战的理想解决方案。它们的多功能性可通过过滤、吸附和化学作用有效去除污染物。在电纺聚合物中,聚丙烯腈(PAN)因其经济实惠、物理和化学特性显著以及易于生产而成为佼佼者。研究人员一直致力于电纺聚丙烯腈膜的研究,探索聚丙烯腈分子链的功能化、适当纳米粒子的加入以及与其他功能聚合物的组合等方面的改性。功能基团、亲水性、机械性能、孔隙率、孔隙结构、可重复使用性、可持续性、ZETA 电位和操作条件等参数对电纺 PAN 膜处理污染水的性能有重大影响。尽管取得了进展,但仍需从战略上解决围绕污垢、毒性、可扩展性、选择性和生产成本的挑战,以提高其实用性和实际可行性。本综述全面审视了当前水处理领域可用的电纺 PAN 膜,包括各种合成实体和实验结果。此外,综述还深入探讨了优化电纺 PAN 膜性能的各种方法,同时提出了克服现有障碍的潜在策略。通过仔细分析影响这些膜性能的参数,本综述为研究人员和工程师提供了宝贵的指导,从而使他们能够为特定的水净化应用设计量身定制的电纺纳米纤维膜。随着创新研究的继续和应对当前挑战的战略努力,这些膜可以在提高水质、缓解水资源短缺和促进环境可持续发展方面发挥关键作用。电纺纳米纤维膜在水处理领域的广泛应用有可能对全球水资源和环境产生持久的积极影响。为实现这些目标而做出的不懈努力无疑将标志着向更加可持续和水资源安全的未来迈出关键的一步。
Advanced nanofibers for water treatment: Unveiling the potential of electrospun polyacrylonitrile membranes
The challenges pertaining to the potable water scarcity and pollution motivates us to envision innovative strategies. Industrial wastewater containing hazardous heavy metals, synthetic dyes, and oil exacerbates the pursuit of clean drinking water. Among the array of available technologies, electrospun nanofiber membranes have garnered attention due to their efficiency, high surface-to-volume ratio, cost-effectiveness, scalability, and multifunctionality. These membranes possess distinct physical and chemical attributes that position them as ideal solutions to water purification challenges. Their versatility enables effective contaminant removal through filtration, adsorption, and chemical interactions. Polyacrylonitrile (PAN) emerges as a frontrunner among electrospun polymers due to its affordability, remarkable physical and chemical characteristics, and the ease of production. Research efforts have been dedicated to the study of electrospun PAN membranes, exploring modifications in terms of the functionalization of PAN molecular chain, incorporation of appropriate nanoparticles, and composition with other functional polymers. Parameters such as functional groups, hydrophilicity, mechanical properties, porosity, pore structure, reusability, sustainability, zeta potential, and operational conditions significantly influence the performance of electrospun PAN membranes in treating the contaminated water. Despite progress, challenges surrounding fouling, toxicity, scalability, selectivity, and production costs ought to be addressed strategically to enhance their practicality and real-world viability. This review comprehensively scrutinizes the current landscape of available electrospun PAN membranes in water treatment encompassing diverse range of synthesized entities and experimental outcomes. Additionally, the review delves into various approaches undertaken to optimize the performance of electrospun PAN membranes while proposing potential strategies to overcome the existing hindrances. By carefully analyzing the parameters that impact the performance of these membranes, this overview offers invaluable guidelines for researchers and engineers, thus empowering them to design tailored electrospun nanofiber membranes for specific water purification applications. As the innovative research continues and strategic efforts address the current challenges, these membranes can play a pivotal role in enhancing water quality, mitigating water scarcity, and contributing to environmental sustainability. The widespread application of electrospun nanofiber membranes in water treatment has the potential to create a lasting positive impact on global water resources and the environment. A dedicated effort towards their implementation will undoubtedly mark a crucial step towards a more sustainable and water-secure future.
期刊介绍:
The Environmental Research journal presents a broad range of interdisciplinary research, focused on addressing worldwide environmental concerns and featuring innovative findings. Our publication strives to explore relevant anthropogenic issues across various environmental sectors, showcasing practical applications in real-life settings.