Eu³+ /Li +共掺杂YBa₃（BO₃）₃led荧光粉的可调发光和结构修饰

IF 5.3 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Research Bulletin Pub Date : 2025-03-27 DOI:10.1016/j.materresbull.2025.113453

Dhowah A.E. Somaily , Abeer S. Altowyan , U.H. Kaynar , H. Aydin , Jabir Hakami , M.B. Coban , T. Zelai , N. Can

{"title":"Eu³+ /Li +共掺杂YBa₃（BO₃）₃led荧光粉的可调发光和结构修饰","authors":"Dhowah A.E. Somaily , Abeer S. Altowyan , U.H. Kaynar , H. Aydin , Jabir Hakami , M.B. Coban , T. Zelai , N. Can","doi":"10.1016/j.materresbull.2025.113453","DOIUrl":null,"url":null,"abstract":"<div><div>Eu³⁺-doped and Eu³⁺/Li⁺ co-doped YBa₃(BO₃)₃ (YBBO) phosphors were synthesized via a microwave-assisted sol-gel combustion method for warm white LED applications. Li⁺ co-doping improved crystallinity and luminescence efficiency. XRD with Rietveld refinement confirmed single-phase YBBO with lattice modifications due to doping. SEM-EDS analysis revealed improved particle densification and uniformity, while FTIR and Raman spectra confirmed alterations in the borate network. Photoluminescence studies showed a dominant red emission at 611 nm. The intensity corresponding to 0.05 mol Eu³⁺ doping was approximately 8.38-fold higher than that of the 0.005 mol Eu³⁺ sample, indicating enhanced luminescence efficiency before the onset of concentration quenching. The phosphor exhibited high color purity (88.3 %) based on CIE coordinates, making it suitable for color evaluation over CCT. Time-resolved PL measurements showed prolonged lifetimes and decreased non-radiative decay. These results demonstrate the potential of YBBO:Eu³⁺/Li⁺ as a highly efficient red-emitting phosphor for next-generation optoelectronic and solid-state lighting applications.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"189 ","pages":"Article 113453"},"PeriodicalIF":5.3000,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Tunable luminescence and structural modifications in Eu³⁺/Li⁺ Co-doped YBa₃(BO₃)₃ phosphors for LEDs\",\"authors\":\"Dhowah A.E. Somaily , Abeer S. Altowyan , U.H. Kaynar , H. Aydin , Jabir Hakami , M.B. Coban , T. Zelai , N. Can\",\"doi\":\"10.1016/j.materresbull.2025.113453\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Eu³⁺-doped and Eu³⁺/Li⁺ co-doped YBa₃(BO₃)₃ (YBBO) phosphors were synthesized via a microwave-assisted sol-gel combustion method for warm white LED applications. Li⁺ co-doping improved crystallinity and luminescence efficiency. XRD with Rietveld refinement confirmed single-phase YBBO with lattice modifications due to doping. SEM-EDS analysis revealed improved particle densification and uniformity, while FTIR and Raman spectra confirmed alterations in the borate network. Photoluminescence studies showed a dominant red emission at 611 nm. The intensity corresponding to 0.05 mol Eu³⁺ doping was approximately 8.38-fold higher than that of the 0.005 mol Eu³⁺ sample, indicating enhanced luminescence efficiency before the onset of concentration quenching. The phosphor exhibited high color purity (88.3 %) based on CIE coordinates, making it suitable for color evaluation over CCT. Time-resolved PL measurements showed prolonged lifetimes and decreased non-radiative decay. These results demonstrate the potential of YBBO:Eu³⁺/Li⁺ as a highly efficient red-emitting phosphor for next-generation optoelectronic and solid-state lighting applications.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"189 \",\"pages\":\"Article 113453\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2025-03-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540825001618\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825001618","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

采用微波辅助溶胶-凝胶燃烧法合成了Eu³+掺杂和Eu³+ /Li +共掺杂的YBa₃（BO₃）₃（YBBO）荧光粉，用于暖白光LED的应用。Li +共掺杂提高了结晶度和发光效率。采用Rietveld细化的XRD证实了掺杂引起的晶格修饰的单相YBBO。SEM-EDS分析显示颗粒致密性和均匀性得到改善，而FTIR和拉曼光谱证实了硼酸盐网络的改变。光致发光研究表明，在611 nm处主要有红色发射。0.05 mol Eu³+掺杂后的发光强度比0.005 mol Eu³+的发光强度高约8.38倍，表明在浓度猝灭发生之前，发光效率得到了提高。根据CIE坐标，该荧光粉显示出高的颜色纯度（88.3%），适合在CCT上进行颜色评价。时间分辨PL测量显示延长寿命和减少非辐射衰变。这些结果证明了YBBO:Eu³+ /Li +作为下一代光电和固态照明应用的高效发红荧光粉的潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Tunable luminescence and structural modifications in Eu³⁺/Li⁺ Co-doped YBa₃(BO₃)₃ phosphors for LEDs

查看原文本刊更多论文

Tunable luminescence and structural modifications in Eu³⁺/Li⁺ Co-doped YBa₃(BO₃)₃ phosphors for LEDs

Eu³⁺-doped and Eu³⁺/Li⁺ co-doped YBa₃(BO₃)₃ (YBBO) phosphors were synthesized via a microwave-assisted sol-gel combustion method for warm white LED applications. Li⁺ co-doping improved crystallinity and luminescence efficiency. XRD with Rietveld refinement confirmed single-phase YBBO with lattice modifications due to doping. SEM-EDS analysis revealed improved particle densification and uniformity, while FTIR and Raman spectra confirmed alterations in the borate network. Photoluminescence studies showed a dominant red emission at 611 nm. The intensity corresponding to 0.05 mol Eu³⁺ doping was approximately 8.38-fold higher than that of the 0.005 mol Eu³⁺ sample, indicating enhanced luminescence efficiency before the onset of concentration quenching. The phosphor exhibited high color purity (88.3 %) based on CIE coordinates, making it suitable for color evaluation over CCT. Time-resolved PL measurements showed prolonged lifetimes and decreased non-radiative decay. These results demonstrate the potential of YBBO:Eu³⁺/Li⁺ as a highly efficient red-emitting phosphor for next-generation optoelectronic and solid-state lighting applications.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Materials Research Bulletin 工程技术-材料科学：综合

CiteScore

9.80

自引率

5.60%

发文量

372

审稿时长

42 days

期刊介绍： Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.