Kaito Kitagawa , Chika Kanda , Taku Iwamoto , Ryohei Yasuda , Jota Kanaya , Shunta Uno , Daigo Shimada , Ai Maruhashi , Mongkol Bumrungpon , Kazuhiro Hasezaki
{"title":"室温下n型碲化铋热电材料变材料、散射参数及约化费米能的实证分析方法","authors":"Kaito Kitagawa , Chika Kanda , Taku Iwamoto , Ryohei Yasuda , Jota Kanaya , Shunta Uno , Daigo Shimada , Ai Maruhashi , Mongkol Bumrungpon , Kazuhiro Hasezaki","doi":"10.1016/j.materresbull.2025.113440","DOIUrl":null,"url":null,"abstract":"<div><div>The variable materials parameter <em>β</em>, scattering parameter <em>γ</em>, and reduced Fermi energy <em>η</em> in <em>n</em>-type bismuth telluride produced by mechanical grinding followed by hot pressing were evaluated using the Fermi-Dirac statistics and a one-electron parabolic model at room temperature. The thermal conductivity <em>κ</em> was assumed to be a quadratic function of the electrical conductivity <em>σ</em> under a constant phonon thermal conductivity <em>κ</em><sub>ph</sub> and temperature. The <em>γ</em> and <em>η</em> were estimated using <em>L</em> and the measured Seebeck coefficient <em>α</em> composed of <em>γ</em> and <em>η</em>. The variational trend of <em>L</em> with <em>γ</em> was similar to that of non-degenerate semiconductors. The analytical <em>ZT<sub>βγη</sub></em> composed of <em>β, γ</em>, and <em>η</em> obtained based on the relationship between the dimensionless figure of merit <em>ZT</em> and <em>η</em> is consistent with the measured <em>ZT<sub>ασκ</sub></em> composed of <em>α, σ</em>, and <em>κ</em>. The obtained <em>β, γ</em>, and <em>η</em> indicate fundamental physical properties of thermoelectric materials alongside <em>α, σ</em>, and <em>κ</em>.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"189 ","pages":"Article 113440"},"PeriodicalIF":5.3000,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Empirical analysis method for evaluating variable materials and scattering parameters and reduced Fermi energy of n-type bismuth telluride thermoelectric materials at room temperature\",\"authors\":\"Kaito Kitagawa , Chika Kanda , Taku Iwamoto , Ryohei Yasuda , Jota Kanaya , Shunta Uno , Daigo Shimada , Ai Maruhashi , Mongkol Bumrungpon , Kazuhiro Hasezaki\",\"doi\":\"10.1016/j.materresbull.2025.113440\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The variable materials parameter <em>β</em>, scattering parameter <em>γ</em>, and reduced Fermi energy <em>η</em> in <em>n</em>-type bismuth telluride produced by mechanical grinding followed by hot pressing were evaluated using the Fermi-Dirac statistics and a one-electron parabolic model at room temperature. The thermal conductivity <em>κ</em> was assumed to be a quadratic function of the electrical conductivity <em>σ</em> under a constant phonon thermal conductivity <em>κ</em><sub>ph</sub> and temperature. The <em>γ</em> and <em>η</em> were estimated using <em>L</em> and the measured Seebeck coefficient <em>α</em> composed of <em>γ</em> and <em>η</em>. The variational trend of <em>L</em> with <em>γ</em> was similar to that of non-degenerate semiconductors. The analytical <em>ZT<sub>βγη</sub></em> composed of <em>β, γ</em>, and <em>η</em> obtained based on the relationship between the dimensionless figure of merit <em>ZT</em> and <em>η</em> is consistent with the measured <em>ZT<sub>ασκ</sub></em> composed of <em>α, σ</em>, and <em>κ</em>. The obtained <em>β, γ</em>, and <em>η</em> indicate fundamental physical properties of thermoelectric materials alongside <em>α, σ</em>, and <em>κ</em>.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"189 \",\"pages\":\"Article 113440\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2025-03-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540825001485\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825001485","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Empirical analysis method for evaluating variable materials and scattering parameters and reduced Fermi energy of n-type bismuth telluride thermoelectric materials at room temperature
The variable materials parameter β, scattering parameter γ, and reduced Fermi energy η in n-type bismuth telluride produced by mechanical grinding followed by hot pressing were evaluated using the Fermi-Dirac statistics and a one-electron parabolic model at room temperature. The thermal conductivity κ was assumed to be a quadratic function of the electrical conductivity σ under a constant phonon thermal conductivity κph and temperature. The γ and η were estimated using L and the measured Seebeck coefficient α composed of γ and η. The variational trend of L with γ was similar to that of non-degenerate semiconductors. The analytical ZTβγη composed of β, γ, and η obtained based on the relationship between the dimensionless figure of merit ZT and η is consistent with the measured ZTασκ composed of α, σ, and κ. The obtained β, γ, and η indicate fundamental physical properties of thermoelectric materials alongside α, σ, and κ.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.