Ming Gao , Rui Bao , Jianhong Yi , Caiju Li , Jingmei Tao , Yan Ren , Linjiang Du , Yuanchun Zhao , Chao Wu , Liang Liu
{"title":"通过粉末冶金方法提高了Ti3SiC2 MAX相增强Cu-Ni-Si复合材料的强度和耐磨性","authors":"Ming Gao , Rui Bao , Jianhong Yi , Caiju Li , Jingmei Tao , Yan Ren , Linjiang Du , Yuanchun Zhao , Chao Wu , Liang Liu","doi":"10.1016/j.jallcom.2025.180168","DOIUrl":null,"url":null,"abstract":"<div><div>Compositional segregation, microstructural inhomogeneity and insufficient wear-resistant are the primary challenges associated with the traditional smelting and casting of Cu-Ni-Si alloys. This study presented a powder metallurgy technique for preparing Ti<sub>3</sub>SiC<sub>2</sub> MAX phase reinforced Cu-3.8Ni-1Si alloy with homogeneous composition and good comprehensive performance. The manipulation of solution and precipitation as well as the morphology modulation of δ-Ni₂Si phases were achieved via Ti<sub>3</sub>SiC<sub>2</sub> MAX phase and in-situ formed SiC whiskers. Nano-sized Ni₂Si phase showed a coherent interface relationship with the alloy matrix, which hindered the climbing and sliding of dislocations. A mechanically mixed layer (MML) composed of Ti<sub>3</sub>SiC<sub>2</sub> MAX phase, SiC whisker, and δ-Ni₂Si phase were formed on the surface of tribological layer. Meanwhile, the synergistic effects among Ti<sub>3</sub>SiC<sub>2</sub> MAX phase, SiC whisker, and δ-Ni₂Si phase significantly improved the mechanical properties. Therefore, Ti<sub>3</sub>SiC<sub>2</sub>/Cu-Ni-Si composite has provided a promising candidate for applications requiring high strength and wear resistance in copper alloys.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1023 ","pages":"Article 180168"},"PeriodicalIF":6.3000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Simultaneously enhanced strength and wear-resistance of Ti3SiC2 MAX phase reinforced Cu-Ni-Si composite via powder metallurgy method\",\"authors\":\"Ming Gao , Rui Bao , Jianhong Yi , Caiju Li , Jingmei Tao , Yan Ren , Linjiang Du , Yuanchun Zhao , Chao Wu , Liang Liu\",\"doi\":\"10.1016/j.jallcom.2025.180168\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Compositional segregation, microstructural inhomogeneity and insufficient wear-resistant are the primary challenges associated with the traditional smelting and casting of Cu-Ni-Si alloys. This study presented a powder metallurgy technique for preparing Ti<sub>3</sub>SiC<sub>2</sub> MAX phase reinforced Cu-3.8Ni-1Si alloy with homogeneous composition and good comprehensive performance. The manipulation of solution and precipitation as well as the morphology modulation of δ-Ni₂Si phases were achieved via Ti<sub>3</sub>SiC<sub>2</sub> MAX phase and in-situ formed SiC whiskers. Nano-sized Ni₂Si phase showed a coherent interface relationship with the alloy matrix, which hindered the climbing and sliding of dislocations. A mechanically mixed layer (MML) composed of Ti<sub>3</sub>SiC<sub>2</sub> MAX phase, SiC whisker, and δ-Ni₂Si phase were formed on the surface of tribological layer. Meanwhile, the synergistic effects among Ti<sub>3</sub>SiC<sub>2</sub> MAX phase, SiC whisker, and δ-Ni₂Si phase significantly improved the mechanical properties. Therefore, Ti<sub>3</sub>SiC<sub>2</sub>/Cu-Ni-Si composite has provided a promising candidate for applications requiring high strength and wear resistance in copper alloys.</div></div>\",\"PeriodicalId\":344,\"journal\":{\"name\":\"Journal of Alloys and Compounds\",\"volume\":\"1023 \",\"pages\":\"Article 180168\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Compounds\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925838825017268\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925838825017268","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Simultaneously enhanced strength and wear-resistance of Ti3SiC2 MAX phase reinforced Cu-Ni-Si composite via powder metallurgy method
Compositional segregation, microstructural inhomogeneity and insufficient wear-resistant are the primary challenges associated with the traditional smelting and casting of Cu-Ni-Si alloys. This study presented a powder metallurgy technique for preparing Ti3SiC2 MAX phase reinforced Cu-3.8Ni-1Si alloy with homogeneous composition and good comprehensive performance. The manipulation of solution and precipitation as well as the morphology modulation of δ-Ni₂Si phases were achieved via Ti3SiC2 MAX phase and in-situ formed SiC whiskers. Nano-sized Ni₂Si phase showed a coherent interface relationship with the alloy matrix, which hindered the climbing and sliding of dislocations. A mechanically mixed layer (MML) composed of Ti3SiC2 MAX phase, SiC whisker, and δ-Ni₂Si phase were formed on the surface of tribological layer. Meanwhile, the synergistic effects among Ti3SiC2 MAX phase, SiC whisker, and δ-Ni₂Si phase significantly improved the mechanical properties. Therefore, Ti3SiC2/Cu-Ni-Si composite has provided a promising candidate for applications requiring high strength and wear resistance in copper alloys.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.