Fundamental concepts, design rules and potentials in radiative cooling.

Amidst the escalating environmental concerns driven by global warming and the detrimental impacts of extreme climates, energy consumption and greenhouse gas emissions associated with refrigeration have reached unprecedented levels. Radiative cooling, as an emerging renewable cooling technology, has been positioned as a pivotal strategy in the fight against global warming. This review examines the theoretical model of radiative cooling emitters and complex practical environment. We first investigate the thermodynamic interactions between environmental factors and the cooling surface, followed by an examination of innovative modulation techniques such as asymmetric/non-reciprocal radiative heat transfer mechanisms. Additionally, we summarize the latest advancements in structural design and simulation methodologies for radiative cooling materials at the device level. We then delve into potential applications of radiative cooling materials in various scenarios including energy-efficient construction, personal thermal management, photovoltaic cooling, and dynamic PDRC materials with seasonal adaptability. In conclusion, we provide a comprehensive overview of this technology's strengths and current challenges to inspire further research and application development in radiative cooling technology with a focus on contributing towards energy conservation objectives and promoting a sustainable society.