co2促进光氧化还原催化烯烃与亚硫酸盐的氢磺化反应†

IF 9.2 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2025-01-30 DOI:10.1039/d5gc00057b

Wanhui Huang , Ge Liu , Fangyuanhang Yang , Yuxi Ren , Yuzhen Gao , Weiping Su

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引用次数: 0

摘要

在此，我们报告了在金属、酸和外源试剂无条件下，二氧化碳促进的光氧化还原催化烯烃与亚硫酸盐的氢磺酰化策略。该方法与广泛的官能团兼容，包括复杂的药物衍生物，使其成为合成有价值的磺酰基化合物的通用和直接的方法。值得注意的是，二氧化碳作为一种环境友好型添加剂，在产品的实现中发挥了至关重要的作用，证明了二氧化碳在磺化反应中的新作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

CO2-Promoted photoredox-catalyzed hydrosulfonylation of alkenes with sulfinates†

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CO2-Promoted photoredox-catalyzed hydrosulfonylation of alkenes with sulfinates†

Herein, we report a CO₂-promoted strategy for the photoredox-catalyzed hydrosulfonylation of alkenes with sulfinates under metal-, acid-, and exogenous reagent-free conditions. This method was compatible with a wide range of functional groups, including complex drug derivatives, making it a versatile and straightforward approach for synthesizing valuable sulfonyl compounds. Notably, CO₂, which is an environmentally friendly additive, played an essential role in achieving the products, demonstrating a novel role of CO₂ in sulfonylation reactions.

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.