{"title":"The effect of carbon monoxide on the detonation ability of the hydrogen-air mixture during shock wave focusing","authors":"S.V. Khomik , S.P. Medvedev , L.I. Stamov , N.N. Smirnov","doi":"10.1016/j.ijhydene.2025.03.371","DOIUrl":null,"url":null,"abstract":"<div><div>In this paper, the results of a research of the effect of carbon monoxide on the detonation ability of a hydrogen-air mixture were presented. Experiments on focusing shock waves on various conical reflectors in mixtures containing 15 % and 20 % of the total volume fraction of fuel were carried out. It was found that for the same amount of fuel, an increase in the proportion of CO when diluting the hydrogen-air mixture leads to a nonlinear decrease in the detonation ability of the mixture. The results of three-dimensional computational modeling of shock wave focusing processes in the considered hydrogen-air mixtures diluted with CO were also presented. The computational model was refined by comparing the simulation results with experimental data. Good agreement with experiment was obtained.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"122 ","pages":"Pages 35-43"},"PeriodicalIF":8.1000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Hydrogen Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S036031992501523X","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
本文介绍了一氧化碳对氢气-空气混合物引爆能力影响的研究结果。在燃料总体积分数分别为 15% 和 20% 的混合物中,对各种锥形反射器进行了冲击波聚焦实验。实验发现,对于相同数量的燃料,稀释氢气-空气混合物时 CO 比例的增加会导致混合物引爆能力的非线性下降。此外,还介绍了所考虑的氢气-空气混合物在稀释 CO 后的冲击波聚焦过程的三维计算模型结果。通过将模拟结果与实验数据进行比较,对计算模型进行了改进。结果与实验结果吻合。
The effect of carbon monoxide on the detonation ability of the hydrogen-air mixture during shock wave focusing
In this paper, the results of a research of the effect of carbon monoxide on the detonation ability of a hydrogen-air mixture were presented. Experiments on focusing shock waves on various conical reflectors in mixtures containing 15 % and 20 % of the total volume fraction of fuel were carried out. It was found that for the same amount of fuel, an increase in the proportion of CO when diluting the hydrogen-air mixture leads to a nonlinear decrease in the detonation ability of the mixture. The results of three-dimensional computational modeling of shock wave focusing processes in the considered hydrogen-air mixtures diluted with CO were also presented. The computational model was refined by comparing the simulation results with experimental data. Good agreement with experiment was obtained.
期刊介绍:
The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc.
The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.