Zen Suzuki, Yuichiro Kawamoto, Toyoharu Kobayashi, Hisanaka Ito
{"title":"(±)-苏门答腊素C的全合成","authors":"Zen Suzuki, Yuichiro Kawamoto, Toyoharu Kobayashi, Hisanaka Ito","doi":"10.1016/j.tetlet.2025.155561","DOIUrl":null,"url":null,"abstract":"<div><div>The first total synthesis of (±)-sumatranin C was accomplished. The synthesis features an intermolecular aldol reaction to connect two parts of the molecule and an acid-induced acetal cyclization to form the tricyclic framework. The present strategy would be applicable to synthesize other related natural products.</div></div>","PeriodicalId":438,"journal":{"name":"Tetrahedron Letters","volume":"161 ","pages":"Article 155561"},"PeriodicalIF":1.5000,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Total synthesis of (±)-sumatranin C\",\"authors\":\"Zen Suzuki, Yuichiro Kawamoto, Toyoharu Kobayashi, Hisanaka Ito\",\"doi\":\"10.1016/j.tetlet.2025.155561\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The first total synthesis of (±)-sumatranin C was accomplished. The synthesis features an intermolecular aldol reaction to connect two parts of the molecule and an acid-induced acetal cyclization to form the tricyclic framework. The present strategy would be applicable to synthesize other related natural products.</div></div>\",\"PeriodicalId\":438,\"journal\":{\"name\":\"Tetrahedron Letters\",\"volume\":\"161 \",\"pages\":\"Article 155561\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-03-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0040403925001108\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040403925001108","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
The first total synthesis of (±)-sumatranin C was accomplished. The synthesis features an intermolecular aldol reaction to connect two parts of the molecule and an acid-induced acetal cyclization to form the tricyclic framework. The present strategy would be applicable to synthesize other related natural products.
期刊介绍:
Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.