{"title":"热处理聚甲醛红外反射光谱的倾斜或阶梯特征。","authors":"Naoto Nagai, Yuko Amaki","doi":"10.1177/00037028251328049","DOIUrl":null,"url":null,"abstract":"<p><p>When injection-molded polyoxymethylene is heat-treated below its melting point, it shows increased polarized reflection along the injection direction, as confirmed through micro-infrared spectroscopy. A characteristic dip or step-like structure appears around 940 cm<sup>-1</sup>. Previously, the origin of this structure was unclear. However, we have found that it can be explained by refining the calculation model to account for the relative permittivity perpendicular to the sample surface.</p>","PeriodicalId":8253,"journal":{"name":"Applied Spectroscopy","volume":" ","pages":"37028251328049"},"PeriodicalIF":2.2000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dip or Step-Like Features in the Infrared Reflection Spectra of Heat-Treated Polyoxymethylene.\",\"authors\":\"Naoto Nagai, Yuko Amaki\",\"doi\":\"10.1177/00037028251328049\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>When injection-molded polyoxymethylene is heat-treated below its melting point, it shows increased polarized reflection along the injection direction, as confirmed through micro-infrared spectroscopy. A characteristic dip or step-like structure appears around 940 cm<sup>-1</sup>. Previously, the origin of this structure was unclear. However, we have found that it can be explained by refining the calculation model to account for the relative permittivity perpendicular to the sample surface.</p>\",\"PeriodicalId\":8253,\"journal\":{\"name\":\"Applied Spectroscopy\",\"volume\":\" \",\"pages\":\"37028251328049\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2025-03-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1177/00037028251328049\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"INSTRUMENTS & INSTRUMENTATION\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/00037028251328049","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"INSTRUMENTS & INSTRUMENTATION","Score":null,"Total":0}
Dip or Step-Like Features in the Infrared Reflection Spectra of Heat-Treated Polyoxymethylene.
When injection-molded polyoxymethylene is heat-treated below its melting point, it shows increased polarized reflection along the injection direction, as confirmed through micro-infrared spectroscopy. A characteristic dip or step-like structure appears around 940 cm-1. Previously, the origin of this structure was unclear. However, we have found that it can be explained by refining the calculation model to account for the relative permittivity perpendicular to the sample surface.
期刊介绍:
Applied Spectroscopy is one of the world''s leading spectroscopy journals, publishing high-quality peer-reviewed articles, both fundamental and applied, covering all aspects of spectroscopy. Established in 1951, the journal is owned by the Society for Applied Spectroscopy and is published monthly. The journal is dedicated to fulfilling the mission of the Society to “…advance and disseminate knowledge and information concerning the art and science of spectroscopy and other allied sciences.”