提高ZSM-5材料水态控制的表面电荷调节，以促进水蒸发发电

IF 4.8 3区材料科学 Q1 CHEMISTRY, APPLIED

Microporous and Mesoporous Materials Pub Date : 2025-03-19 DOI:10.1016/j.micromeso.2025.113606

Jiangying Qu, Qian Yin, Zhe Jiao, Jiawei Ge, Feng Gao, Yunhao Zang

{"title":"提高ZSM-5材料水态控制的表面电荷调节，以促进水蒸发发电","authors":"Jiangying Qu, Qian Yin, Zhe Jiao, Jiawei Ge, Feng Gao, Yunhao Zang","doi":"10.1016/j.micromeso.2025.113606","DOIUrl":null,"url":null,"abstract":"<div><div>Water evaporation power generation (WEPG) is recognized as a novel and pollution-free energy technology. However, the regulation of water states in generating materials and their impact on power generation performance remain under-explored. In this study, a series of samples denoted as ZSM-5/Tx (where x = 0–7.00), with varying surface charges, are prepared by tailoring their Si/Al ratio. It is found that a lower Si/Al ratio results in a higher surface charge of the material. Consequently, a positive correlation between surface charge and WEPG performances is observed, with ZSM-5/Tx samples that have higher surface charges showing increased open-circuit voltage (Voc) and short-circuit current (Isc). Among all the samples, the typical ZSM-5/T3.55 sample, which has the highest surface charge, demonstrates the highest Voc of 1.35 V and Isc of 223 nA. Theoretical calculations indicate that charge accumulation between ZSM-5/Tx and water molecules increases with surface charge, i.e., 0.00038 e− for ZSM-5/T1.50, 0.0005 e− for ZSM-5/T3.55, and 0.00035 e− for ZSM-5/T7.00. The study further reveals that surface charge influences the water states of intermediate water (IW) and free water (FW) within the microchannels of ZSM-5/Tx. As the surface charge of ZSM-5/Tx increases, the IW/FW ratio follows the order of 0.72 (ZSM-5/T3.55) > 0.59 (ZSM-5/T1.50) > 0.48 (ZSM-5/T7.00) > 0.36 (ZSM-5/T0). The increase in the IW/FW ratio reduces energy consumption and enhances water evaporation, and IW is more likely to detach from ZSM-5/Tx at higher surface charges, thus improving power generation efficiency.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113606"},"PeriodicalIF":4.8000,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Surface charge regulation for enhanced control of water states in ZSM-5 materials to boost water evaporation power generation\",\"authors\":\"Jiangying Qu, Qian Yin, Zhe Jiao, Jiawei Ge, Feng Gao, Yunhao Zang\",\"doi\":\"10.1016/j.micromeso.2025.113606\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Water evaporation power generation (WEPG) is recognized as a novel and pollution-free energy technology. However, the regulation of water states in generating materials and their impact on power generation performance remain under-explored. In this study, a series of samples denoted as ZSM-5/Tx (where x = 0–7.00), with varying surface charges, are prepared by tailoring their Si/Al ratio. It is found that a lower Si/Al ratio results in a higher surface charge of the material. Consequently, a positive correlation between surface charge and WEPG performances is observed, with ZSM-5/Tx samples that have higher surface charges showing increased open-circuit voltage (Voc) and short-circuit current (Isc). Among all the samples, the typical ZSM-5/T3.55 sample, which has the highest surface charge, demonstrates the highest Voc of 1.35 V and Isc of 223 nA. Theoretical calculations indicate that charge accumulation between ZSM-5/Tx and water molecules increases with surface charge, i.e., 0.00038 e− for ZSM-5/T1.50, 0.0005 e− for ZSM-5/T3.55, and 0.00035 e− for ZSM-5/T7.00. The study further reveals that surface charge influences the water states of intermediate water (IW) and free water (FW) within the microchannels of ZSM-5/Tx. As the surface charge of ZSM-5/Tx increases, the IW/FW ratio follows the order of 0.72 (ZSM-5/T3.55) > 0.59 (ZSM-5/T1.50) > 0.48 (ZSM-5/T7.00) > 0.36 (ZSM-5/T0). The increase in the IW/FW ratio reduces energy consumption and enhances water evaporation, and IW is more likely to detach from ZSM-5/Tx at higher surface charges, thus improving power generation efficiency.</div></div>\",\"PeriodicalId\":392,\"journal\":{\"name\":\"Microporous and Mesoporous Materials\",\"volume\":\"391 \",\"pages\":\"Article 113606\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-03-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Microporous and Mesoporous Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387181125001209\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous and Mesoporous Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387181125001209","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}

引用次数: 0

摘要

水蒸发发电（WEPG）是公认的一种新型、无污染的能源技术。然而，发电材料中水态的调节及其对发电性能的影响仍未得到充分探讨。在本研究中，通过调整其Si/Al比制备了一系列具有不同表面电荷的样品，标记为ZSM-5/Tx（其中x = 0-7.00）。结果表明，硅铝比越低，材料的表面电荷越高。因此，表面电荷与WEPG性能之间存在正相关关系，具有较高表面电荷的ZSM-5/Tx样品显示出更高的开路电压（Voc）和短路电流（Isc）。在所有样品中，典型的ZSM-5/T3.55样品具有最高的表面电荷，其Voc最高为1.35 V， Isc最高为223 nA。理论计算表明，ZSM-5/Tx与水分子之间的电荷积累随着表面电荷的增加而增加，即ZSM-5/T1.50的电荷积累为0.00038 e−,ZSM-5/T3.55的电荷积累为0.0005 e−,ZSM-5/T7.00的电荷积累为0.00035 e−。研究进一步揭示了表面电荷影响ZSM-5/Tx微通道内中间水（IW）和自由水（FW）的水态。随着ZSM-5/Tx表面电荷量的增加，IW/FW比约为0.72 (ZSM-5/T3.55) >；0.59 (ZSM-5/T1.50) >；0.48 (ZSM-5/T7.00) >；0.36 (ZSM-5 / T0)。IW/FW比的提高降低了能耗，促进了水分蒸发，并且在较高的表面电荷下，IW更容易从ZSM-5/Tx中分离出来，从而提高了发电效率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Surface charge regulation for enhanced control of water states in ZSM-5 materials to boost water evaporation power generation

查看原文本刊更多论文

Surface charge regulation for enhanced control of water states in ZSM-5 materials to boost water evaporation power generation

Water evaporation power generation (WEPG) is recognized as a novel and pollution-free energy technology. However, the regulation of water states in generating materials and their impact on power generation performance remain under-explored. In this study, a series of samples denoted as ZSM-5/Tx (where x = 0–7.00), with varying surface charges, are prepared by tailoring their Si/Al ratio. It is found that a lower Si/Al ratio results in a higher surface charge of the material. Consequently, a positive correlation between surface charge and WEPG performances is observed, with ZSM-5/Tx samples that have higher surface charges showing increased open-circuit voltage (V_oc) and short-circuit current (I_sc). Among all the samples, the typical ZSM-5/T3.55 sample, which has the highest surface charge, demonstrates the highest V_oc of 1.35 V and I_sc of 223 nA. Theoretical calculations indicate that charge accumulation between ZSM-5/Tx and water molecules increases with surface charge, i.e., 0.00038 e⁻ for ZSM-5/T1.50, 0.0005 e⁻ for ZSM-5/T3.55, and 0.00035 e⁻ for ZSM-5/T7.00. The study further reveals that surface charge influences the water states of intermediate water (IW) and free water (FW) within the microchannels of ZSM-5/Tx. As the surface charge of ZSM-5/Tx increases, the IW/FW ratio follows the order of 0.72 (ZSM-5/T3.55) > 0.59 (ZSM-5/T1.50) > 0.48 (ZSM-5/T7.00) > 0.36 (ZSM-5/T0). The increase in the IW/FW ratio reduces energy consumption and enhances water evaporation, and IW is more likely to detach from ZSM-5/Tx at higher surface charges, thus improving power generation efficiency.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Microporous and Mesoporous Materials 化学-材料科学：综合

CiteScore

10.70

自引率

5.80%

发文量

649

审稿时长

26 days

期刊介绍： Microporous and Mesoporous Materials covers novel and significant aspects of porous solids classified as either microporous (pore size up to 2 nm) or mesoporous (pore size 2 to 50 nm). The porosity should have a specific impact on the material properties or application. Typical examples are zeolites and zeolite-like materials, pillared materials, clathrasils and clathrates, carbon molecular sieves, ordered mesoporous materials, organic/inorganic porous hybrid materials, or porous metal oxides. Both natural and synthetic porous materials are within the scope of the journal. Topics which are particularly of interest include: All aspects of natural microporous and mesoporous solids The synthesis of crystalline or amorphous porous materials The physico-chemical characterization of microporous and mesoporous solids, especially spectroscopic and microscopic The modification of microporous and mesoporous solids, for example by ion exchange or solid-state reactions All topics related to diffusion of mobile species in the pores of microporous and mesoporous materials Adsorption (and other separation techniques) using microporous or mesoporous adsorbents Catalysis by microporous and mesoporous materials Host/guest interactions Theoretical chemistry and modelling of host/guest interactions All topics related to the application of microporous and mesoporous materials in industrial catalysis, separation technology, environmental protection, electrochemistry, membranes, sensors, optical devices, etc.