{"title":"含锰AFA合金在550℃、氧浓度为10-6 wt的LBE中的耐蚀性","authors":"Menghe Tu, Yajie He, Zihui Liu, Xiaogang Fu, Lingzhi Chen","doi":"10.3390/ma18061328","DOIUrl":null,"url":null,"abstract":"<p><p>Alumina-forming austenitic steels (AFA steels) exhibit excellent creep resistance and oxidation capabilities, making them a strong candidate for cladding materials in lead-cooled fast reactors. This study investigates the corrosion resistance of Mn-containing AFA steels in lead-bismuth eutectic (LBE) at 550 °C with a controlled oxygen concentration of 10<sup>-6</sup> wt.%. The results demonstrate that under these experimental conditions, the addition of Al enhances the material's resistance to lead-bismuth corrosion. Moreover, Mn incorporation significantly improves corrosion resistance, with the optimal composition being an AFA alloy containing 16 wt.% Ni, 12 wt.% Cr, 3 wt.% Al, and 4 wt.% Mn. Mn addition alters the type of oxide product formed on the alloy surface, shifting from Fe<sub>3</sub>O<sub>4</sub> or (Fe, Cr)<sub>x</sub>O<sub>y</sub> to (Cr, Mn)<sub>x</sub>O<sub>y</sub>.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 6","pages":""},"PeriodicalIF":3.1000,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11943494/pdf/","citationCount":"0","resultStr":"{\"title\":\"Corrosion Resistance of Mn-Containing AFA Alloys in LBE at 550 °C with Controlled Oxygen Concentration of 10<sup>-6</sup> wt.\",\"authors\":\"Menghe Tu, Yajie He, Zihui Liu, Xiaogang Fu, Lingzhi Chen\",\"doi\":\"10.3390/ma18061328\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Alumina-forming austenitic steels (AFA steels) exhibit excellent creep resistance and oxidation capabilities, making them a strong candidate for cladding materials in lead-cooled fast reactors. This study investigates the corrosion resistance of Mn-containing AFA steels in lead-bismuth eutectic (LBE) at 550 °C with a controlled oxygen concentration of 10<sup>-6</sup> wt.%. The results demonstrate that under these experimental conditions, the addition of Al enhances the material's resistance to lead-bismuth corrosion. Moreover, Mn incorporation significantly improves corrosion resistance, with the optimal composition being an AFA alloy containing 16 wt.% Ni, 12 wt.% Cr, 3 wt.% Al, and 4 wt.% Mn. Mn addition alters the type of oxide product formed on the alloy surface, shifting from Fe<sub>3</sub>O<sub>4</sub> or (Fe, Cr)<sub>x</sub>O<sub>y</sub> to (Cr, Mn)<sub>x</sub>O<sub>y</sub>.</p>\",\"PeriodicalId\":18281,\"journal\":{\"name\":\"Materials\",\"volume\":\"18 6\",\"pages\":\"\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2025-03-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11943494/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.3390/ma18061328\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.3390/ma18061328","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Corrosion Resistance of Mn-Containing AFA Alloys in LBE at 550 °C with Controlled Oxygen Concentration of 10-6 wt.
Alumina-forming austenitic steels (AFA steels) exhibit excellent creep resistance and oxidation capabilities, making them a strong candidate for cladding materials in lead-cooled fast reactors. This study investigates the corrosion resistance of Mn-containing AFA steels in lead-bismuth eutectic (LBE) at 550 °C with a controlled oxygen concentration of 10-6 wt.%. The results demonstrate that under these experimental conditions, the addition of Al enhances the material's resistance to lead-bismuth corrosion. Moreover, Mn incorporation significantly improves corrosion resistance, with the optimal composition being an AFA alloy containing 16 wt.% Ni, 12 wt.% Cr, 3 wt.% Al, and 4 wt.% Mn. Mn addition alters the type of oxide product formed on the alloy surface, shifting from Fe3O4 or (Fe, Cr)xOy to (Cr, Mn)xOy.
期刊介绍：
Materials (ISSN 1996-1944) is an open access journal of related scientific research and technology development. It publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Materials provides a forum for publishing papers which advance the in-depth understanding of the relationship between the structure, the properties or the functions of all kinds of materials. Chemical syntheses, chemical structures and mechanical, chemical, electronic, magnetic and optical properties and various applications will be considered.
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