羟基甲基-1,3-二氧环烷丙二酸酯的合成与反应

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-03-27 DOI:10.1007/s11172-025-4534-5

Yu. G. Borisova, R. M. Sultanova, S. S. Zlotsky

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引用次数: 0

摘要

合成了含1,3-二氧环己烷的丙二酸盐，并在常规加热和微波辐照条件下进行了部分反应。新丙二酸酯可以成功地用作烷基化反应中的C-H酸，也可以用于叔胺和烯烃的合成。研究了微波活化定量合成目标产物的条件。

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Synthesis and reactions of malonic esters based on hydroxymethyl-1,3-dioxacycloalkanes

Malonates bearing 1,3-dioxacycloakane moiety were synthesized and some of their reactions were carried out under conditions of conventional heating and microwave irradiation. New malonates can be successfully used as C—H acids in the alkylation reaction as well as for the synthesis of tertiary amines and olefins. The conditions for synthesizing target products in quantitative yields using microwave activation were developed.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.