镍（II）与[（Prop-2-en(yn)-1-yl）氧]乙胺硫代酸盐配合物及其应用

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI:10.1134/S1070363225600833

A. Z. Zalov, K. A. Kuliev, G. M. Talybov, U. B. Abasguliyeva, N. A. Novruzova

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引用次数: 0

摘要

采用萃取光度法研究了镍（II）与(S)-[（丙-2-炔-1-基）氧]乙酰亚硫酸盐（PENT）和(S)-[（丙-2-炔-1-基）氧]乙酰亚硫酸盐（PINT）的反应。用红外光谱和核磁共振光谱对配体进行了表征。研究了水相pH对Ni(II)L2配合物形成和热分解的影响。将所建立的萃取光度法应用于废水和植物样品中镍的测定。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Complexes of Nickel(II) with [(Prop-2-en(yn)-1-yl)oxy]ethanimidothioate and Their Applications

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Complexes of Nickel(II) with [(Prop-2-en(yn)-1-yl)oxy]ethanimidothioate and Their Applications

The reactions of nickel(II) with (S)-[(prop-2-en-1-yl)oxy]ethanimidothioate (PENT) and (S)-[(prop-2-yn-1-yl)oxy]ethanimidothioate (PINT) was studied by the extraction-photometric method. The ligands were characterized with IR and NMR spectroscopy. The influence of aqueous phase pH on the formation of Ni(II)L₂ complexes and thermal decomposition were studied. The developed extraction-photometric method was applied to determine nickel in wastewater and plant samples.

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.