{"title":"柔性聚偏氟乙烯/多壁碳纳米管热电复合薄膜具有优异的环境稳定性和增强的铁电极化功率因数","authors":"Qinghui Jiang \n (, ), Zhenxiang Yu \n (, ), Xinyue Zhang \n (, ), Shanliang Chen \n (, ), Jitao Yi \n (, ), Yong Liu \n (, )","doi":"10.1007/s40843-024-3240-9","DOIUrl":null,"url":null,"abstract":"<div><p>Flexible thermoelectric (TE) films and devices have potential applications in wearable technology and the Internet of Things. One of the main challenges is how to simultaneously achieve good TE performance and high chemical/thermal stability in air with low cost and large-scale production. To address this, we utilized tape casting to fabricate composite films of polyvinylidene fluoride (PVDF) and multi-walled carbon nanotubes (MWCNTs). In the composite, polar β-PVDF introduced by hot pressing can decouple the electrical conductivity and Seebeck coefficient and significantly lead to enhanced power factor of MWCNTs/PVDF composite film. As a result, the MWCNTs (60 wt%)/PVDF film has a power factor of 1.1–1.4 µW m<sup>−1</sup> K<sup>−2</sup> near room temperature. The film also has excellent flexibility and stability in the air. Its power factor is decreased by only 9% after 1000 bends and can keep stable in air for above 6 months, which is much longer than that (15 days) of Bi<sub>2</sub>Te<sub>3</sub>/PEDOT: PSS film. A demo TE device with 10 p-type legs has an output voltage of 11.5 mV and output power of 47.53 nW at a temperature difference of 60°C. The above descriptions make the MWCNTs/PVDF films have a significant advantage in the commercial application of flexible TE devices.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1240 - 1248"},"PeriodicalIF":6.8000,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Flexible polyvinylidene fluoride/multiwall carbon nanotube-based thermoelectric composite films with excellent environmental stability and enhanced power factor from ferroelectric polarization\",\"authors\":\"Qinghui Jiang \\n (, ), Zhenxiang Yu \\n (, ), Xinyue Zhang \\n (, ), Shanliang Chen \\n (, ), Jitao Yi \\n (, ), Yong Liu \\n (, )\",\"doi\":\"10.1007/s40843-024-3240-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Flexible thermoelectric (TE) films and devices have potential applications in wearable technology and the Internet of Things. One of the main challenges is how to simultaneously achieve good TE performance and high chemical/thermal stability in air with low cost and large-scale production. To address this, we utilized tape casting to fabricate composite films of polyvinylidene fluoride (PVDF) and multi-walled carbon nanotubes (MWCNTs). In the composite, polar β-PVDF introduced by hot pressing can decouple the electrical conductivity and Seebeck coefficient and significantly lead to enhanced power factor of MWCNTs/PVDF composite film. As a result, the MWCNTs (60 wt%)/PVDF film has a power factor of 1.1–1.4 µW m<sup>−1</sup> K<sup>−2</sup> near room temperature. The film also has excellent flexibility and stability in the air. Its power factor is decreased by only 9% after 1000 bends and can keep stable in air for above 6 months, which is much longer than that (15 days) of Bi<sub>2</sub>Te<sub>3</sub>/PEDOT: PSS film. A demo TE device with 10 p-type legs has an output voltage of 11.5 mV and output power of 47.53 nW at a temperature difference of 60°C. The above descriptions make the MWCNTs/PVDF films have a significant advantage in the commercial application of flexible TE devices.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":773,\"journal\":{\"name\":\"Science China Materials\",\"volume\":\"68 4\",\"pages\":\"1240 - 1248\"},\"PeriodicalIF\":6.8000,\"publicationDate\":\"2025-03-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science China Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s40843-024-3240-9\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science China Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s40843-024-3240-9","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Flexible polyvinylidene fluoride/multiwall carbon nanotube-based thermoelectric composite films with excellent environmental stability and enhanced power factor from ferroelectric polarization
Flexible thermoelectric (TE) films and devices have potential applications in wearable technology and the Internet of Things. One of the main challenges is how to simultaneously achieve good TE performance and high chemical/thermal stability in air with low cost and large-scale production. To address this, we utilized tape casting to fabricate composite films of polyvinylidene fluoride (PVDF) and multi-walled carbon nanotubes (MWCNTs). In the composite, polar β-PVDF introduced by hot pressing can decouple the electrical conductivity and Seebeck coefficient and significantly lead to enhanced power factor of MWCNTs/PVDF composite film. As a result, the MWCNTs (60 wt%)/PVDF film has a power factor of 1.1–1.4 µW m−1 K−2 near room temperature. The film also has excellent flexibility and stability in the air. Its power factor is decreased by only 9% after 1000 bends and can keep stable in air for above 6 months, which is much longer than that (15 days) of Bi2Te3/PEDOT: PSS film. A demo TE device with 10 p-type legs has an output voltage of 11.5 mV and output power of 47.53 nW at a temperature difference of 60°C. The above descriptions make the MWCNTs/PVDF films have a significant advantage in the commercial application of flexible TE devices.
期刊介绍：
Science China Materials (SCM) is a globally peer-reviewed journal that covers all facets of materials science. It is supervised by the Chinese Academy of Sciences and co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China. The journal is jointly published monthly in both printed and electronic forms by Science China Press and Springer. The aim of SCM is to encourage communication of high-quality, innovative research results at the cutting-edge interface of materials science with chemistry, physics, biology, and engineering. It focuses on breakthroughs from around the world and aims to become a world-leading academic journal for materials science.
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