链导电合成含5元氮杂环和13元碳环的双环[60]富勒烯衍生物

IF 3.6 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-03-14 DOI:10.1021/acs.joc.5c0005210.1021/acs.joc.5c00052

Zheng-Chun Yin*, Qian-Wen Zhang, Wen-Rui Liu, Chuang Niu, Muqing Chen and Guan-Wu Wang*,

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引用次数: 0

摘要

首次出人意料地实现了与5元氮杂环和13元碳环（即双环1,4,9,12-和1,2,4,15-加合物）融合的[60]富勒烯衍生物的电定向合成。新的双环[60]富勒烯衍生物是通过电化学还原[60]富勒烯-融合吲哚或内酰胺，然后与2,2″-双（溴甲基）-1,1 ':3 '，1″-terphenyl进行区域选择性环化得到的。通过光谱数据和单晶x射线分析对产物结构进行了表征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Tether-Directed Electrosynthesis of Bicyclic [60]Fullerene Derivatives Fused with 5-Membered Azacycle and 13-Membered Carbocycle

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Tether-Directed Electrosynthesis of Bicyclic [60]Fullerene Derivatives Fused with 5-Membered Azacycle and 13-Membered Carbocycle

Tether-directed electrosynthesis of [60]fullerene derivatives fused with 5-membered azacycle and 13-membered carbocycle, that is, bicyclic 1,4,9,12- and 1,2,4,15-adducts, has been achieved unexpectedly for the first time. The novel bicyclic [60]fullerene derivatives are obtained by the electrochemical reduction of [60]fullerene-fused indolines or lactams and subsequent regioselective cyclization with 2,2″-bis(bromomethyl)-1,1′:3′,1″-terphenyl. The product structures have been characterized by spectroscopic data and single-crystal X-ray analysis.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.